全文获取类型
收费全文 | 24793篇 |
免费 | 3969篇 |
国内免费 | 3007篇 |
专业分类
化学 | 17498篇 |
晶体学 | 280篇 |
力学 | 1664篇 |
综合类 | 235篇 |
数学 | 2801篇 |
物理学 | 9291篇 |
出版年
2024年 | 80篇 |
2023年 | 464篇 |
2022年 | 844篇 |
2021年 | 915篇 |
2020年 | 973篇 |
2019年 | 951篇 |
2018年 | 818篇 |
2017年 | 715篇 |
2016年 | 1125篇 |
2015年 | 1181篇 |
2014年 | 1379篇 |
2013年 | 1798篇 |
2012年 | 2117篇 |
2011年 | 2326篇 |
2010年 | 1516篇 |
2009年 | 1488篇 |
2008年 | 1517篇 |
2007年 | 1392篇 |
2006年 | 1358篇 |
2005年 | 1116篇 |
2004年 | 969篇 |
2003年 | 731篇 |
2002年 | 700篇 |
2001年 | 604篇 |
2000年 | 566篇 |
1999年 | 511篇 |
1998年 | 431篇 |
1997年 | 364篇 |
1996年 | 381篇 |
1995年 | 358篇 |
1994年 | 350篇 |
1993年 | 270篇 |
1992年 | 285篇 |
1991年 | 226篇 |
1990年 | 198篇 |
1989年 | 161篇 |
1988年 | 97篇 |
1987年 | 93篇 |
1986年 | 81篇 |
1985年 | 79篇 |
1984年 | 46篇 |
1983年 | 49篇 |
1982年 | 39篇 |
1981年 | 24篇 |
1980年 | 15篇 |
1979年 | 9篇 |
1977年 | 7篇 |
1975年 | 7篇 |
1969年 | 4篇 |
1957年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Heng-You Lan 《Journal of Mathematical Analysis and Applications》2007,327(1):481-493
In this paper, we introduce and study a new system of nonlinear A-monotone multivalued variational inclusions in Hilbert spaces. By using the concept and properties of A-monotone mappings, and the resolvent operator technique associated with A-monotone mappings due to Verma, we construct a new iterative algorithm for solving this system of nonlinear multivalued variational inclusions associated with A-monotone mappings in Hilbert spaces. We also prove the existence of solutions for the nonlinear multivalued variational inclusions and the convergence of iterative sequences generated by the algorithm. Our results improve and generalize many known corresponding results. 相似文献
82.
利用微扰展开技术推导出变参数波振器的小信号增益两个近似求积表达式并将其计算结果与数值模拟结果进行了比较,二者吻合很好。利用近似解析式对小信号增益进行了初步探讨,得到了电子入射能量可低于初始谐振能,能散度允许范围受波振器设计影响以及降低锥度改变率可提高小信号增益等新结论。 相似文献
83.
针对90t RH精炼装置,以水力学模拟研究了吹气孔直径对真空循环精炼过程中钢液流动和混合特性的影响.模型和原型的相似比为15.模型吹气孔直径分别为0.8 mm和1.2 mm.结果表明,1.2 mm孔径下环流量和主要工艺参数间的关系为Ql Q80.26Du0.69Dd0.80;在给定的吹气量和插入管内径下,增大吹气孔直径并不显著改变精炼过程中钢液流动特征,环流量随吹气孔直径的增大而略有增大,其关系式为Ql=2.40Q 0.23gD0.72u D0.88d d0.13in;相应地,混合时间稍有缩短;0.8和1.2 mm孔径下,τm与搅拌能密度的关系分别为τm ε5和τm ε0.49. 相似文献
84.
该文用顺磁离子对其近邻~(13)C核的NMR吸收增宽效应,系统地研究了抗坏血酸在不同溶剂中对金属离子Mn~(2+)、Gd~(3+)的配合行为.在水溶液中,抗坏血酸可通过两种配合方式与Mn~(2+)作用,但与Gd~(3+)的作用只有一种稳定的结构.在水中抗坏血酸对金属的配位活性部位分别是1位羟基氧,3位离解的羟基氧和6位羟基氧.在DMSO中,3位羟基由于H~+对该基团的静电遮蔽而变得对金属离子Mn~(2+)表现为配位惰性,同时6位羟基配位活性较大增强.对Gd~(3+)来说,此时没有优势配位活性部位存在.文章还讨论了抗坏血酸在H_2O-DMSO混合溶剂中的~(13)C NMR谱及在DMSO中NaOH对其~(13)C NMR谱及其与金属络合结构的影响. 相似文献
85.
Suoyuan Lian Lei Gao Zhenhui Kang Di Wu Yang Lan Lin Xu 《Solid State Communications》2004,132(6):375-378
Single-crystal magnetite nanowires with average diameter of ca. 20 nm and length of up to several micrometers were prepared by a simple alkaline surfactant-free hydrothermal process. The crystallinity, purity, morphology, and structural features of the as-prepared magnetite nanowires were investigated by powder X-ray diffraction, transmission electron microscopy (TEM) and selected area electron diffraction. The composition and length of nanowires depends on the pH, with higher pH favoring longer nanowires composed entirely of Fe3O4. A mechanism for nanowire growth is proposed. 相似文献
86.
玻色—爱因斯坦凝聚和兰姆位移 总被引:1,自引:0,他引:1
扼要地介绍了BEC研究的近况和研究方向,同时报道了我们在BEC的光散射和兰姆位移方面的研究工作 相似文献
87.
89.
Toshiki Kono Toshikazo Sakaguchi Yanming Hu Masashi Shiotsuki Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5943-5953
Phenylacetylene (PA) derivatives having two polar groups (ester, 2a – d ; amide, 4) or one cyclic polar group (imide, 5a – c ) were polymerized using (nbd)Rh+[(η6‐C6H5)B?(C6H5)3] catalyst to afford high molecular weight polymers (~1 × 106 – 4 × 106). The hydrolysis of ester‐containing poly(PA), poly( 2a) , provided poly(3,4‐dicarboxyPA) [poly ( 3 )], which could not be obtained directly by the polymerization of the corresponding monomer. The solubility properties of the present polymers were different from those of poly(PA) having no polar group; that is, poly( 2a )–poly( 2d ) dissolved in ethyl acetate and poly( 4 ) dissolved in N,N‐dimethylformamide, while poly(PA) was insoluble in such solvents. Ester‐group‐containing polymers [poly( 2a )–poly( 2d )] afforded free‐standing membranes by casting from THF solutions. The membrane of poly( 2a ) showed high carbon dioxide permselectivity against nitrogen (PCO2/PN2 = 62). © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5943–5953, 2006 相似文献
90.
Mikaru Ikedo Masanobu Mori Kazumasa Kurachi Wenzhi Hu Kazuhiko Tanaka 《Analytical sciences》2006,22(1):117-121
The selective and simultaneous ion-exclusion chromatography (IEC) with UV-detection on a weakly acidic cation-exchange resin column in the H+ -form (TSKgel Super IC-A/C) was developed and applied for the simultaneous determination of phosphate and silicate ions as the water quality parameters required for optimizing the water-leaching process for ceramics glaze raw materials of natural origin including feldspar, woods-ash, and straw-ash. Phosphate and silicate ions in these water-leaching process water samples were separated selectively from the coexisting anions such as sulfate, chloride, nitrate and carbonate ions, based on the ion-exclusion separation mechanism. They were detected selectively and simultaneously by a postcolumn derivatization with molybdenum-yellow using the UV-detector. Under the optimized separation and detection conditions (eluent, 0-1 mM sulfuric acid; reactant, 10 mM sodium molybdate-25 mM sulfuric acid; detector, UV at 370 nm; temperature, 45 degrees C), the linearity of calibration was in the range 0.1 - 10 ppm for both phosphate and silicate ions, and the detection limits at S/N = 3 were 2.58 ppb for silicate ions and 4.75 ppb for phosphate ions. The effectiveness of this method was demonstrated in practical applications to the water-leaching process for some ceramics glaze raw materials. 相似文献