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11.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
12.
It is shown that, if t is an integer ≥3 and not equal to 7 or 8, then there is a unique maximal graph having the path Pt as a star complement for the eigenvalue ?2. The maximal graph is the line graph of Km,m if t = 2m?1, and of Km,m+1 if t = 2m. This result yields a characterization of L(G ) when G is a (t + 1)‐vertex bipartite graph with a Hamiltonian path. The graphs with star complement PrPs or PrCs for ?2 are also determined. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 137–149, 2003  相似文献   
13.
The effect of space- and time-dependent random mass density, velocity, and pressure fields on frequencies and amplitudes of acoustic waves is considered by means of the analytical perturbative method. The analytical results, which are valid for weak fluctuations and long wavelength sound waves, reveal frequency and amplitude alteration, the effect of which depends on the type of random field. In particular, the effect of a random mass density field is to increase wave frequencies. Space-dependent random velocity and pressure fields reduce wave frequencies. While space-dependent random fields attenuate wave amplitudes, their time-dependent counterparts lead to wave amplification. In another example, sound waves that are trapped in the vertical direction but are free to propagate horizontally are affected by a space-dependent random mass density field. This effect depends on the direction along which the field is varying. A random field, which varies along the horizontal direction, does not couple vertically standing modes but increases their frequencies and attenuates amplitudes. These modes are coupled by a random field which depends on the vertical coordinate, but the dispersion relation remains the same as in the case of the deterministic medium.  相似文献   
14.
A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates.  相似文献   
15.
In this study, a novel stepwise extraction method has been examined. The guest molecules housed between the helices of the clathrate δ form of syndiotactic polystyrene can be removed completely with this method. A systematic study of the preparation of a solvent‐free mesophase (emptied clathrate) membrane, its helical and residual solvent contents, and its structural transformations has been performed. In this first attempt, an enhancement in the TTGG helical content has been observed in the extracted membrane, and a conceptual mechanism is proposed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 269–273, 2003  相似文献   
16.
Beloshapka  V. K. 《Mathematical Notes》2004,75(3-4):475-488
In previous papers by the present author, a machinery for calculating automorphisms, constructing invariants, and classifying real submanifolds of a complex manifold was developed. The main step in this machinery is the construction of a “nice” model surface. The nice model surface can be treated as an analog of the osculating paraboloid in classical differential geometry. Model surfaces suggested earlier possess a complete list of the desired properties only if some upper estimate for the codimension of the submanifold is satisfied. If this estimate fails, then the surfaces lose the universality property (that is, the ability to touch any germ in an appropriate way), which restricts their applicability. In the present paper, we get rid of this restriction: for an arbitrary type (n,K) (where n is the dimension of the complex tangent plane, and K is the real codimension), we construct a nice model surface. In particular, we solve the problem of constructing a nondegenerate germ of a real analytic submanifold of a complex manifold of arbitrary given type (n,K) with the richest possible group of holomorphic automorphisms in the given class.  相似文献   
17.
The title compound is a centrosymmetric dimer with each cadmium in a distorted CdS5 square pyramidal geometry. The Cd–S bond distances range from 2.5626(11) to 2.8459(11) Å. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
18.
The electro-optic and complex dielectric behaviour of an antiferroelectric liquid crystal 4-(1-methylheptyloxycarbonyl)phenyl 4'-(n-butanoyloxyprop-1-oxy)biphenyl-4-carboxylate, having chiral SmCA* and hexatic smectic phases, have been investigated. Complex dielectric permittivities were measured as a function of frequency, d.c. bias field and temperature. Spontaneous polarization was measured by the current reversal technique; tilt angle was measured under a polarizing microscope using a low frequency electric field. The electro-optic properties and dielectric behaviour of the material are compared with results obtained by DSC and polarizing optical microscopy. Dielectric relaxation processes in SmCA* and hexatic smectic phases were determined. The dielectric strength at the SmCA* to hexatic smectic phase transition is discussed in terms of coupling between the long range bond orientational order and smectic C director. It seems from the results of spontaneous polarization and dielectric relaxation spectroscopy that the material might possess an additional phase between the SmCA* and hexatic smectic I* phases.  相似文献   
19.
A new method was developed for studying voids and channels in crystal structures based on the Voronoi-Dirichlet partition of crystal space, and 822 structurally characterized ternary compounds Li p X q O r were analyzed for the first time. For these compounds, the dimensionality was determined and the migration patterns of channel systems capable of providing lithium-ion transport were constructed. The calculated coordinates of lithium atoms in the centers of the voids are consistent (within 0.4 ?) with the known structural data. Among these compounds, 113 compounds have infinite channel systems, 60 compounds (18 structural types, STs) have been described earlier in the literature as solid electrolytes, and 53 compounds (23 STs) can be considered as potential one-, two-, or three-dimensional ionic conductors (13, 3, and 7 STs, respectively). Original Russian Text ? N.A. Anurova, V.A. Blatov, G.D. Ilyushin, O.A. Blatova, A.K. Ivanov-Shitz, L.N. Dem’yanets, 2008, published in Kristallografiya, 2008, Vol. 53, No. 6, pp. 987–993.  相似文献   
20.
Our model for light-induced defect creation in hydrogenated amorphous silicon is applied to its kinetics, i.e., the growing curve of light-induced dangling bond density as a function of illumination time, which is fitted to a stretched exponential function. Two parameters β and τ involved in the function are estimated as functions of saturated dangling bond density in terms of our model. These are compared with two experimental results, i.e., our results obtained from ESR measurements and Shimakawa et al.’s results obtained from photoconductivity measurements. The saturated dangling bond density is also measured as a function of the generation rate of free carriers. The experimental results are compared with calculated results and discussed.  相似文献   
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