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101.
Basak Anirban Sadhu Arindam Das Kunal Sharma Kapil K. 《International Journal of Theoretical Physics》2019,58(9):3158-3179
In this paper, an attempt is made to present a method of quantum cost minimization or optimization technique for quantum reversible circuits using proposed merger rules in Exclusive Sum of Product (ESOP) method. These modified ESOP methods are used to minimize the quantum circuits. We found that the quantum cost is drastically decreased than the previous ESOP method. It will be easy to find the quantum cost and quantum gate optimized quantum circuits implementation. It will also reduce quantum error while the quantum circuit is executed in real quantum processor.
相似文献102.
ABSTRACTWe study the structural, energetic and electronic properties of the structured water chain clusters within the density functional theory. We refer the structured water chains to those water clusters that have specific geometric patterns stretched along one direction. External electric field required to keep the structures open chain, thereby preventing them to form closed structures, is applied along the length of the chain. The structures are essentially periodic with basic repeating unit consisting of the corner- or edge-sharing 4-, 5- or 6-membered ring water clusters. Our calculations underscore the possible existence of such structured water clusters in the electrostatic environments, which we simulate in its simplicity employing a dipolar, uniform and static electric field. Analysis reveals that the 5-membered ring water chain clusters, i.e. the pentamer chain clusters have the lowest average dipole moment per water molecule while the threshold field, that marks the onset of the field-induced closure of the HOMO (highest occupied molecular orbital)-LUMO (lowest unoccupied molecular orbital) energy gap, is highest, followed by that for the tetramer and hexamer chains. The results suggest that the pentamer chains are the most stable clusters over a wide range of electric fields. 相似文献
103.
Over the last decade, the synthetic chemist's community has attracted attention towards aldo-x precursors due to their versatility to afforded variety of heterocyclic frameworks. The aldo-x bifunctional building blocks (AXB3s) contain two or more reactive sites with different reactivity, which may offer new opportunities for the introduction of diversity in core skeleton, which may be of great biological and medicinal relevance. In this context, pyrazole based AXB3s such as 4-iodopyrazole-3/5-carbaldehyde may be explored for achieving pyrazole fused/linked heterocyclic skeletons by employing different organic transformations. Specifically, iodo substituted pyrazoles provide a new platform for the installation of desired pattern via transition-metal catalyzed approaches. Herein, we have assembled the strategies towards the development of pyrazole substituted and fused molecular architectures by using 4-iodopyrazole-3/5-carbaldehydes and pyrazole C-3)/C5- carbaldehydes. The photophysical data of some fluorescent pyrazole derivatives have also been discussed. 相似文献
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Kirtikumar D. Bharwad Priyanka A. Shah Pranav S. Shrivastav Vinay S. Sharma Puran Singhal 《Biomedical chromatography : BMC》2020,34(1):e4708
A rapid, simple and sensitive ultra-performance liquid chromatography–tandem mass spectrometry (UHPLC–MS/MS) method has been developed to quantify fenoprofen, a nonsteroidal anti-inflammatory drug in human plasma for a pharmacokinetic study in healthy subjects. Owing to high levels of protein binding, protein precipitation followed by solid-phase extraction was employed for the extraction of fenoprofen and fenoprofen-d3 (used as internal standard) from 200 μL human plasma. Separation was performed on a BEH C18 (50 × 2.1 mm, 1.7 μm) column using methanol−0.2% acetic acid in water (75:25, v/v) under isocratic elution. Electrospray ionization was operated in the negative mode for sample ionization. Ion transitions used for quantification in the selected reaction monitoring mode were m/z 241/197 and m/z 244/200 for fenoprofen and fenoprofen-d3, respectively. Under the optimized conditions, fenoprofen showed excellent linearity in the concentration range 0.02–20 μg/mL (r2 ≥ 0.9996), adequate sensitivity, favorable accuracy (96.4–103.7%) and precision (percentage coefficient of variation ≤4.3) with negligible matrix effect. The validated method was successfully applied to a pharmacokinetic study of fenoprofen in healthy subjects. The significant features of the method include higher sensitivity, small plasma volume for processing and a short analysis time. 相似文献
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Crystallography Reports - The communication deals with the eco-friendly synthesis and X-ray crystal structure of an organic carbonitrile, namely... 相似文献
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The present article reports the heat transfer characteristics of a vertical stainless steel foil of 0.15 mm thickness (SS304) by circular impinging jets of various fluids such as pure water, nano-fluids (Al2O3-water, ф = 0.15%, 0.6%), and aqueous high-alcohol surfactant (HAS, i.e., 2-ethyl-hexanol, 100–400 ppm) studied using an infrared thermal imaging camera (A655sc, FLIR System). The enhancement in the heat transfer rates for Al2O3-water nano-fluids with ф = 0.15%, ф = 0.60%, and aqueous surfactant solution (150ppm) is found to be 140%, 207%, and 117% higher compared to pure water results, respectively. The surface characteristics of the foil after jet impingement by various fluids are also studied using scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), and surface wettability. 相似文献