首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   169篇
  免费   11篇
  国内免费   2篇
化学   137篇
力学   5篇
数学   12篇
物理学   28篇
  2023年   2篇
  2022年   2篇
  2021年   1篇
  2020年   4篇
  2019年   6篇
  2018年   12篇
  2017年   6篇
  2016年   15篇
  2015年   12篇
  2014年   14篇
  2013年   28篇
  2012年   20篇
  2011年   15篇
  2010年   15篇
  2009年   8篇
  2008年   6篇
  2007年   1篇
  2006年   6篇
  2005年   2篇
  2003年   1篇
  2002年   2篇
  2000年   1篇
  1989年   2篇
  1986年   1篇
排序方式: 共有182条查询结果,搜索用时 15 毫秒
111.
The replacement of indicator functions by integrated beta kernels in the definition of the empirical tail dependence function is shown to produce a smoothed version of the latter estimator with the same asymptotic distribution but superior finite-sample performance. The link of the new estimator with the empirical beta copula enables a simple but effective resampling scheme.  相似文献   
112.
In order to explore the capability of a solid–liquid phase change material (PCM) for cooling electronic or heat storage applications, melting of a PCM in a vertical rectangular enclosure was studied. Three protruding generating heat sources are attached on one of the vertical walls of the enclosure, and generating heat at a constant and uniform volumetric rate. The horizontal walls are adiabatic. The power generated in heat sources is dissipated in PCM (n-eicosane with the melting temperature, Tm = 36 °C) that filled the rectangular enclosure. The advantage of using PCM is that it is able to absorb high amount of heat generated by heat sources due to its relatively high energy density. To investigate the thermal behaviour and thermal performance of the proposed system, a mathematical model based on the mass, momentum and energy conservation equations was developed. The governing equations are next discretised using a control volume approach in a staggered mesh and a pressure correction equation method is employed for the pressure–velocity coupling. The PCM energy equation is solved using the enthalpy method. The solid regions (wall and heat sources) are treated as fluid regions with infinite viscosity and the thermal coupling between solid and fluid regions is taken into account using the harmonic mean of the thermal conductivity method. The dimensionless independent parameters that govern the thermal behaviour of the system were next identified. After validating the proposed mathematical model against experimental data, a numerical investigation was next conducted in order to examine the thermal behaviour of the system by analyzing the flow structure and the heat transfer during the melting process, for a given values of governing parameters.  相似文献   
113.
114.

Stilbenophanes 1c and 2c were synthesized in good yields. Among alkali ions, both isomers only formed 1:1 complexes with lithium selectively. An X-ray structure of 1c shows a statistical disorder which leads to two refined positions for the ethylene moiety. The existence of a weak intramolecular C-H > O hydrogen bond in its structure was confirmed by both X-ray analysis and theoretical calculation.  相似文献   
115.
116.
117.
The Fe3O4 magnetic particles were modified with 1,10‐phenanthroline‐5,6‐diol (Phen) and the related Mn complex (Fe3O4@Phen@Mn) synthesized as a heterogeneous catalyst to be used for the one‐pot three‐component synthesis of various tetrazoles. The catalysts were characterized by several methods, such as the elemental analysis, FT‐IR, X‐ray powder diffraction, dispersive X‐ray spectroscopy, scanning electron microscopy, transmission electron microscopy, dynamic light scattering, thermogravimetric‐differential thermal analysis, vibrating sample magnetometer and X‐ray photoelectron spectroscopy. In addition, the antioxidant and antibacterial activities of the catalyst and its Phen ligand were in vitro screened with 2,2‐diphenyl‐1‐picrylhydrazyl by free radical scavenging methods. Results showed that the synthesized compounds possess strong antioxidant activity (IC50; 0.172  ±  0.005 mg ml?1) as well as a good antibacterial potential in comparison to standards.  相似文献   
118.
119.
120.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号