全文获取类型
收费全文 | 1043篇 |
免费 | 35篇 |
国内免费 | 6篇 |
专业分类
化学 | 821篇 |
晶体学 | 36篇 |
力学 | 24篇 |
数学 | 33篇 |
物理学 | 170篇 |
出版年
2024年 | 2篇 |
2023年 | 8篇 |
2022年 | 24篇 |
2021年 | 33篇 |
2020年 | 16篇 |
2019年 | 36篇 |
2018年 | 32篇 |
2017年 | 37篇 |
2016年 | 44篇 |
2015年 | 25篇 |
2014年 | 45篇 |
2013年 | 103篇 |
2012年 | 81篇 |
2011年 | 84篇 |
2010年 | 48篇 |
2009年 | 48篇 |
2008年 | 69篇 |
2007年 | 60篇 |
2006年 | 72篇 |
2005年 | 48篇 |
2004年 | 39篇 |
2003年 | 25篇 |
2002年 | 23篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1969年 | 1篇 |
1967年 | 2篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1084条查询结果,搜索用时 15 毫秒
11.
Application of sodium metaperiodate for the determination of ribavirin in pharmaceutical formulations 总被引:1,自引:0,他引:1
Three simple and sensitive visible spectrophotometric methods (A-C) have been described for the assay of ribavirin either in pure form or in pharmaceutical formulations. They are based on the oxidation of ribavirin with excess sodium metaperiodate and estimating either the products formed (dialdehyde with MBTH, method A; iodate with metol-sulphanilamide, in the presence of Mo(VI) and iodide, method B) or the amount of periodate consumed (celestine blue in the presence of telurium (IV), method C). All of the variables have been optimized and the reaction mechanisms presented. The concentration measurements are reproducible within a R.S.D. of 1.0%. Recoveries are 99.2-101.2%. 相似文献
12.
alpha-Fluoroamino acids were targeted in our ongoing efforts to design novel fluoropeptidomimetics (1) as potential protease inhibitors. alpha-Fluoroglycine derivative (2) and alpha-fluoro-beta-aminoethanethiol derivatives (3-9) were synthesized for the first time en route to obtain the peptidomimetic moiety 1. The stability of 2-9 was investigated under organic as well as aqueous conditions. The stability of 3-9 under acidic and basic conditions, the effect of substitution at C-2 position, and potential biological activities are discussed. 相似文献
13.
The solubility of the nucleic acid bases, adenine and thymine, in aqueous erythritol, xylose, glucose, and sucrose solutions has been studied. The solubility of adenine increases linearly with glucose and sucrose concentration, whereas with the other reagents a nonlinear increase is observed. Below 1.5M reagent concentration, the solubility of adenine increases in the order erythritol < robose, xylose < glucose < sucrose. The solubility of thymine in these solutions, on the other hand, decreases, increases, or does not change depending upon the reagent. The effect of temperature on the solubility of adenine and thymine in sugar solution indicates that the transfer of these molecules from water to sugar solution is exothermic.Presented in part at the VIIth All-India Symposium in Biophysics held at Visva Bharati University during October 1976. 相似文献
14.
A highly convergent and efficient synthesis of (−)-microcarpalide, a 10-membered lactone displaying remarkable microfilament disrupting activity is described. Ring-closing metathesis and Sharpless asymmetric dihydroxylations are the key steps. Our strategy highlights the application of novel hydroxy lactone precursors for the stereoselective synthesis of (−)-microcarpalide. 相似文献
15.
Conductive films of gold were assembled on flexible polymer substrates such as Kapton and polyethylene using a solution-based process. The polymer substrates were modified by using argon plasma and subsequent coupling of silanes with amino- or mercapto- terminal groups. These modified surfaces were examined by X-ray photoelectron spectroscopy and contact angle measurements. Colloidal gold was assembled onto the silane-modified surface from solution. The gold particles are attached to the surface by covalent interactions with the thiol or amine group. Formation of a conductive film is achieved by increasing the coverage of gold by using a "seeding" method to increase the size of the attached gold particles. Field emission scanning electron microscopy was used to follow the growth of the film. The surface resistance of the films, measured using a four-point probe, was about 1 Omega/sq. 相似文献
16.
Patrick Koch Carl Djerassi Vijai Lakshmi Francis J. Schmitz 《Helvetica chimica acta》1983,66(8):2431-2436
Thirty-two sterols are identified in the sponge Hyrtios sp. In addition to fourteen monohydroxylated compounds, the sterol fraction contains eight functionalized sidechain sterols, three of them new: 3 β-hydroxy-24-norchol-5-en-23-al (19) , (22-trans)-3 β-hydroxycholest-5, 22-dien-24-one (20) and (22R, 23R, 24S) or (22S, 23S, 24S)- 22,23-epoxy-24-methylchoest-5-en-3 β-ol (24). The probable biological origin, rather than artifact production, of these undescribed components is discussed. 相似文献
17.
M. Lakshmi Kantam B. KavitaV. Neeraja Y. HarithaM.K. Chaudhuri S.K. Dehury 《Tetrahedron letters》2003,44(50):9029-9032
Microencapsulated copper(II) acetylacetonate was prepared and used in the aziridination of alkenes employing [N-(p-tolylsulfonyl)imino]phenyliodinane (PhINTs) as the nitrogen source. Microencapsulated copper(II) acetylacetonate [MC-Cu(acac)2] catalyst was reused for several cycles with consistent activity. 相似文献
18.
Parupalli J. Lakshmi Kamatala C. Rajanna Pondichery K. Saiprakash 《Transition Metal Chemistry》1996,21(2):135-141
Summary Oxidation of the FeII chelates [FeL] (L = phen or bipy) by CrVI and MnVII in H2SO4 medium was found to proceed through the formation of a bimetallic insertion complex which decomposes in the slow step, followed by electron transfer from [FeL] to the oxidant. The reactions are catalysed by both anionic and non-ionic micelles [SDS and triton-x (Tx), respectively]. A mechanism is suggested involving electrostatic stabilization of the cationic forms of the FeII chelates by anionic SDS and the partial anionic character of polyoxyethylene moiety of Tx, respectively. The marginal catalysis of cationic micelles (CTAB) is attributed to co-anion-micellar interactions. 相似文献
19.
A new chelating polymeric sorbent has been developed using Merrifield chloromethylated resin anchored with quinoline-8-ol (HQ). The modified polymeric resin was characterized by FT-IR spectroscopy and elemental analysis. The HQ anchored resin showed superior binding affinity for U(VI) over Th(IV) and La(III). The influence of various physicochemical parameters on the recovery of U(VI) were optimized by both static and dynamic methods. The phase exchange kinetic studies performed for U(VI) revealed that <5 min was sufficient for reaching equilibrium metal ion sorption. The maximum sorption capacity of HQ anchored resin for U(VI) was found to be 120.30 mg g−1 of resin which is higher than other solid phase extraction sorbents reported so far excepting N,N-dibutyl, N′-benzoyl thiourea sorbed Amberlite XAD-16. The developed HQ anchored polymeric resin is highly selective as none of the extraneous species were found to have any deleterious effect. Solid phase extraction (SPE) studies performed using HQ anchored polymeric resin offered enrichment factor of 100 and the lowest concentration below which recoveries become non-quantitative is 5 μg l−1. The accuracy of the developed SPE method in conjunction with Arsenazo III procedure was tested by analyzing marine sediment (MESS-3) and soil (IAEA–Soil 7) reference materials. Furthermore, the above procedure has been successfully employed for the analysis of real soil and sediment samples. 相似文献