Charged-particle reaction studies for nuclear astrophysics

The TUDA and TACTIC facilities at TRIUMF provide versatile experimental capabilities for the study of astrophysically important reactions using both direct and indirect techniques. The present work will outline the research programme to date, describe the experimental facilities and discuss recent developments.     

REACTIONS OF ARYLSULPHONYL FLUORIDES

Abstract

Substituent effects have been investigated for both nucleophili -ic and reduction reactions of arylsulphonyl fluorides in aqueous media. The significance of the results will be discussed in relation to the reactions of arylsulphonyl chlorides.     

2.3 Geologisches material

Referate2 Spezielle Produkte und Anwendungsgebiete

2.3 Geologisches material     

Transport properties of CO2-expanded acetonitrile from molecular dynamics simulations

Carbon-dioxide-expanded liquids, which are mixtures of organic liquids and compressed CO2, are novel media used in chemical processing. The authors present a molecular simulation study of the transport properties of liquid mixtures formed by acetonitrile and carbon dioxide, in which the CO2 mole fraction is adjusted by changing the pressure, at a constant temperature of 298 K. They report values of translational diffusion coefficients, rotational correlation times, and shear viscosities of the liquids as function of CO2 mole fraction. The simulation results are in good agreement with the available experimental data for the pure components and provide interesting insights into the largely unknown properties of the mixtures, which are being recognized as important novel materials in chemical operations. We find that the calculated quantities exhibit smooth variation with composition that may be represented by simple model equations. The translational and rotational diffusion rates increase with CO2 mole fraction for both the acetonitrile and carbon dioxide components. The shear viscosity decreases with increasing amount of CO2, varying smoothly between the values of pure acetonitrile and pure carbon dioxide. Our results show that adjusting the amount of CO2 in the mixture allows the variation of transport rates by a factor of 3-4 and liquid viscosity by a factor of 8. Thus, the physical properties of the mixture may be tailored to the desired range by changes in the operating conditions of temperature and pressure.