全文获取类型
收费全文 | 3599篇 |
免费 | 450篇 |
国内免费 | 248篇 |
专业分类
化学 | 2419篇 |
晶体学 | 14篇 |
力学 | 161篇 |
综合类 | 22篇 |
数学 | 507篇 |
物理学 | 1174篇 |
出版年
2024年 | 13篇 |
2023年 | 66篇 |
2022年 | 87篇 |
2021年 | 92篇 |
2020年 | 100篇 |
2019年 | 92篇 |
2018年 | 75篇 |
2017年 | 62篇 |
2016年 | 140篇 |
2015年 | 117篇 |
2014年 | 167篇 |
2013年 | 251篇 |
2012年 | 321篇 |
2011年 | 305篇 |
2010年 | 218篇 |
2009年 | 178篇 |
2008年 | 245篇 |
2007年 | 192篇 |
2006年 | 183篇 |
2005年 | 169篇 |
2004年 | 143篇 |
2003年 | 149篇 |
2002年 | 122篇 |
2001年 | 97篇 |
2000年 | 71篇 |
1999年 | 66篇 |
1998年 | 47篇 |
1997年 | 58篇 |
1996年 | 62篇 |
1995年 | 48篇 |
1994年 | 44篇 |
1993年 | 37篇 |
1992年 | 26篇 |
1991年 | 19篇 |
1990年 | 25篇 |
1989年 | 16篇 |
1988年 | 15篇 |
1987年 | 14篇 |
1986年 | 14篇 |
1985年 | 18篇 |
1984年 | 23篇 |
1983年 | 13篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 14篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1974年 | 5篇 |
排序方式: 共有4297条查询结果,搜索用时 15 毫秒
21.
Hang-Chin Lai 《Journal of Mathematical Analysis and Applications》2004,294(2):644-654
Consider a two-person zero-sum game constructed by a dynamic fractional form. We establish the upper value as well as the lower value of a dynamic fractional game, and prove that the dual gap is equal to zero under certain conditions. It is also established that the saddle point function exists in the fractional game system under certain conditions so that the equilibrium point exists in this game system. 相似文献
22.
Supramolecular side chain liquid crystalline polymers (SCLCPs) based on poly(3-carboxypropylmethylsiloxane-co-dimethylsiloxane) (PSIX, X=100, 76, 60, 41 or 23, denoting the mole percentage of 3-carboxypropylmethylsiloxane unit in the polymer) and stilbazole derivatives have been obtained through intermolecular hydrogen bonding (H-bonding) interactions between the carboxylic acid and the pyridyl moieties. The formation of H-bonding and self-assembly results in the formation of new mesogenic units, in which H-bonds function as molecular connectors. FTIR shows the existence of H-bonding in the complexes. The polymeric complexes behave as single component liquid crystalline polymers and exhibit stable and enantiotropic mesophases. The liquid crystalline properties of the supramolecular SCLCPs were studied using differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction, and were found to exhibit smectic A phases with focal-conic textures. The thermal stability of the SCLCP increases on increasing the carboxylic acid content in the polysiloxane and the concentration of the stilbazole derivative in the complex. However, the thermal stability decreases on increasing the chain length of the stilbazole derivative. The crystal phase was not formed even on cooling to the glass transition temperature of the polymeric complex. 相似文献
23.
本文将t(t是大于2的整数)元整系数多项式看成为系数为t-2元整系数多项式的二元多项式,建立了多元整系数多项式因式分解的一种新理论,进而得到了分解多元整系数多项式的一个有力的算法。 相似文献
24.
25.
26.
27.
Baijun Liu Gilles P. Robertson Michael D. Guiver Yi‐Ming Sun Yin‐Ling Liu Juin‐Yih Lai Serguei Mikhailenko Serge Kaliaguine 《Journal of Polymer Science.Polymer Physics》2006,44(16):2299-2310
A series of sulfonated poly(aryl ether ether ketone ketone)s statistical copolymers with high molecular weights were synthesized via an aromatic nucleophilic substitution polymerization. The sulfonation content (SC), defined as the number of sulfonic acid groups contained in an average repeat unit, could be controlled by the feed ratios of monomers. Flexible and strong membranes in sodium sulfonate form could be prepared by the solution casting method, and readily transformed to their proton forms by treating them in 2 N sulfuric acid. The polymers showed high Tgs, which increased with an increase in SC. Membranes prepared from the present sulfonated poly(ether ether ketone ketone) copolymers containing the hexafluoroisopropylidene moiety (SPEEKK‐6F) and copolymers containing the pendant 3,5‐ditrifluoromethylphenyl moiety (SPEEKK‐6FP) had lower water uptakes and lower swelling ratios in comparison with previously prepared copolymers containing 6F units. All of the polymers possessed proton conductivities higher than 1 × 10?2 S/cm at room temperature, and proton conductivity values of several polymers were comparable to that of Nafion at high relative humidity. Their thermal stability, oxidative stability, and mechanical properties were also evaluated. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2299–2310, 2006 相似文献
28.
Trivariate Cr macroelements defined in terms of polynomials of degree 8r + 1 on tetrahedra are analyzed. For r = 1,2, these spaces reduce
to well-known macroelement spaces used in data fitting and in the finite-element method.
We determine the dimension of these spaces, and describe stable local minimal determining sets and nodal minimal determining
sets. We also show that the spaces approximate smooth functions to optimal order. 相似文献
29.
Ternary Ti-Si-N refractory barrier films of 15 nm thick was prepared by low frequency, high density, inductively coupled plasma implantation of N into TixSiy substrate. This leads to the formation of Ti-N and Si-N compounds in the ternary film. Diffusion of copper in the barrier layer after annealing treatment at various temperatures was investigated using time-of-flight secondary ion mass spectrometer (ToF-SIMS) depth profiling, X-ray diffractometer (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) and sheet resistance measurement. The current study found that barrier failure did not occur until 650 °C annealing for 30 min. The failure occurs by the diffusion of copper into the Ti-Si-N film to form Cu-Ti and Cu-N compounds. FESEM surface morphology and EDX show that copper compounds were formed on the ridge areas of the Ti-Si-N film. The sheet resistance verifies the diffusion of Cu into the Ti-Si-N film; there is a sudden drop in the resistance with Cu compound formation. This finding provides a simple and effective method of monitoring Cu diffusion in TiN-based diffusion barriers. 相似文献
30.