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F. Lahoz P. Haro-Gonzalez F. Rivera-López S. González-Pérez I. R. Martín N. E. Capuj C. N. Afonso J. Gonzalo J. Fernández R. Balda 《Applied Physics A: Materials Science & Processing》2008,93(3):621-625
Thin films of Er3+-doped lead–niobium germanate have been produced by pulsed laser deposition from Er3+-doped 25PbO2–25Nb2O5–50GeO2 (mol%) transparent glasses with an Er content in the range 0.5–3 wt%. The room-temperature infrared to visible upconversion
properties of these thin films have been investigated under 800-nm laser excitation. An energy transfer upconversion mechanism
has been identified to be responsible for the population of the 4S3/2:2H11/2 excited level, from which an intense green emission occurs. A rate equation analysis supports the proposed mechanism. 相似文献
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Romero-Cano MS Martín-Rodríguez A de las Nieves FJ 《Journal of colloid and interface science》2000,227(2):329-333
An experimental desorption study of Triton X-100 from latices with different functionality is presented. Two different strategies to follow the desorption experiment have been used: first, a discontinuous method based on the wash step (centrifugation-removal-redispersion); and second, a continuous method based on the replacement of the disperse media. The desorption results show that in all cases a residual amount of Triton X-100 remains adsorbed, indicating irreversibility of the surfactant adsorption. Finally, the effect of desorption on the colloidal stability of one type of latex-surfactant complex has been analyzed. Copyright 2000 Academic Press. 相似文献
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A Combined Experimental–Computational Investigation to Uncover the Puzzling (Chiro‐)optical Response of Pyridocyclophanes: One‐ and Two‐Photon Spectra 下载免费PDF全文
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P. Haro-González I. R. Martín F. Lahoz N. E. Capuj 《Applied physics. B, Lasers and optics》2011,104(1):237-240
Evidence of positive optical gain is observed in Tm3+–Yb3+-codoped oxyfluoride glass ceramic in an upconversion pump and probe experiment. The 1G4 level of the Tm3+ ions is populated by an upconversion mechanism under excitation of the Yb3+ ions at 975 nm with a high-power pulsed laser and give rise to an intense emission from the 1G4 to the 3F4 levels. The 1G4→3F4 electronic transition is stimulated with a low signal at 650 nm as a probe. 相似文献
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Aitor Carretero Zacarías León Juan Carlos García-Cañaveras Ángela Zaragoza María José Gómez-Lechón María Teresa Donato Agustín Lahoz 《Analytical and bioanalytical chemistry》2014,406(22):5465-5476
Multiple analytical methods are required to comprehensively assess oxidative homeostasis and specific damage to macromolecules. Our aim was to develop a straightforward strategy for the fast assessment of global oxidative status and specific damage to DNA, proteins, and lipids. To this end, an analytical method, based on ultra-performance liquid chromatography coupled to mass spectrometry (UPLC-MS/MS), was developed and validated for the quantification of 16 oxidative stress (OS) biomarkers. Some of these markers were unstable; thus, an easy sample treatment procedure, including fractionation and derivatization, was set up. The method was validated according to Food and Drug Administration (FDA) guidelines, and it provided good results in terms of intra- and inter-day precision (≤17.2 and 16 %, respectively), accuracy (relative error measurement between ?16.6 and 19.8 %), and linearity (R 2?>?0.994). The approach was applied to determine the oxidative insult provoked to cultured rat hepatocytes by cumene hydroperoxide and to analyze the liver and serum samples from patients diagnosed with nonalcoholic steatohepatitis. In both studies, significant differences were found if compared to the corresponding control groups; interestingly, ophthalmic acid was shown as an OS biomarker in both models for the first time. A key advantage of the novel approach in comparison with former multi-method approaches is that now a single method is applied to assess the 16 OS biomarkers. Its comprehensive capacity to profile oxidative homeostasis and damage in both in vitro and clinical samples has been illustrated, which indicates that the proposed approach is a good choice to evaluate whether OS is involved in physiological signals, diseases, or toxic events and to what extent. 相似文献