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101.
Laurent Aubry Thierry Sayd Claude Ferreira Christophe Chambon Annie Vnien Sylvie Blinet Marie Bourin Anglique Travel Maeva Halgrain Vronique Sant-Lhoutellier Laetitia Thron 《Molecules (Basel, Switzerland)》2021,26(12)
The marketing of poultry livers is only authorized as fresh, frozen, or deep-frozen. The higher consumer demand for these products for a short period of time may lead to the marketing of frozen–thawed poultry livers: this constitutes fraud. The aim of this study was to design a method for distinguishing frozen–thawed livers from fresh livers. For this, the spectral fingerprint of liver proteins was acquired using Matrix-Assisted Laser Dissociation Ionization-Time-Of-Flight mass spectrometry. The spectra were analyzed using the chemometrics approach. First, principal component analysis studied the expected variability of commercial conditions before and after freezing–thawing. Then, the discriminant power of spectral fingerprint of liver proteins was assessed using supervised model generation. The combined approach of mass spectrometry and chemometrics successfully described the evolution of protein profile during storage time, before and after freezing-thawing, and successfully discriminated the fresh and frozen–thawed livers. These results are promising in terms of fraud detection, providing an opportunity for implementation of a reference method for agencies to fight fraud. 相似文献
102.
103.
Himatkumar V. Patel Kavita A. Vyas Sudhanshu P. Pandey Peter S. Fernandes 《合成通讯》2013,43(21):3081-3087
A novel one-step synthesis of 4-arylazo-1H-1, 3, 5-trimethylpyrazoles is accomplished by reaction of N, N-dimethylhydrazine with 2, 3, 4-pentantrione-3-arylhydrazones via an unusual demethylation. 相似文献
104.
D. G. Beasley A. Alghamdi M. C. Freitas A. Fernandes Z. Révay 《Journal of Radioanalytical and Nuclear Chemistry》2009,281(2):307-311
The epithermal beamline at the Portuguese Research Reactor is being optimized for Prompt Gamma Neutron Activation Analysis
(PGNAA). One of the major changes is to thermalise the beam by the introduction of a sapphire crystal into the beamline. Placing
the sapphire at the exit of the beamline would greatly reduce the alterations and work necessary to the port and make the
crystal easily removable. However, the scattered neutrons from the sapphire would increase both the neutron-induced detector
damage and the background radiation. MCNPX was used to simulate the crystal in the beam port and at the exit of the port. 相似文献
105.
106.
Th. R. Cunningham R. J. Price St. G. Simpson W. C. Schumb P. Klinger O. Schliessmann D. R. Nijk H. Bart G. v. Hevesy R. Hobbie A. Asmanow P. H. M. P. Brinton R. B. Ellestad G. Scagliarini P. Pratesi I. M. Kolthoff J. J. Lingane J. Volmar Mathis J. Perrin E. Bayle R. Fabre H. George H. Gräven G. Canneri und L. Fernandes 《Fresenius' Journal of Analytical Chemistry》1934,99(3-4):113-129
Ohne Zusammenfassung 相似文献
107.
Ohne Zusammenfassung 相似文献
108.
The flow activation free energy ( ΔG *) is the minimum energy necessary to induce a flow in a system that is at rest. It can be calculated from the system viscosity using the Andrade--Eyring theory. In the present work the flow activation free energy of cholesteric lyotropic liquid crystals was studied as a function of D-(+)-mannose concentration added to a nematic mesophase. The results obtained showed that all the systems can be characterized as Newtonian, but a smooth time-dependent effect can be observed mainly in systems with a lower chiral inductor concentration. It has also been observed that an increase of cholestericity leads to a decrease of ΔH * values until a limit is reached at 1 mol % of inductor. From a positive ΔS * variation it was possible to verify the existence of a locally less organized transient state during the process of micellar diffusion. When the cholesterization process was considered, the increase of the inductor concentration leads to a decrease of ΔS * and consequently to a system, as a whole, more orderly, possibly as a result of the restriction of movement caused by the presence of chiral interactions. 相似文献
109.
Paula Amaral Luís M. Fernandes Joaquim Júdice Hanif D. Sherali 《Journal of Global Optimization》2009,45(4):645-666
This paper addresses the problem of finding an optimal correction of an inconsistent linear system, where only the nonzero
coefficients of the constraint matrix are allowed to be perturbed for reconstructing a consistent system. Using the Frobenius
norm as a measure of the distance to feasibility, a nonconvex minimization problem is formulated, whose objective function
is a sum of fractional functions. A branch-and-bound algorithm for solving this nonconvex program is proposed, based on suitably
overestimating the denominator function for computing lower bounds. Computational experience is presented to demonstrate the
efficacy of this approach. 相似文献
110.
Elvis J. De França Elisabete A. De Nadai Fernandes Márcio A. Bacchi Peter Bode Rob T. M. van Soldt 《Journal of Radioanalytical and Nuclear Chemistry》2009,282(1):125-132
For environmental quality assessment, INAA has been applied for determining chemical elements in small (200 mg) and large
(200 g) samples of leaves from 200 trees. By applying the Ingamells’ constant, the expected percent standard deviation was
estimated in 0.9–2.2% for 200 mg samples. Otherwise, for composite samples (200 g), expected standard deviation varied from
0.5 to 10% in spite of analytical uncertainties ranging from 2 to 30%. Results thereby suggested the expression of the degree
of representativeness as a source of uncertainty, contributing for increasing of the reliability of environmental studies
mainly in the case of composite samples. 相似文献