Химическая сенсиБил изация фотографичес кой эмульсии

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Chemical sensiblilisation of photographic emulsion

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, 7. V. 1953 .     

The surface layer on a ferromagnetic. The energy of some periodic domain structures

Explicit solutions are found for a number of special cases of the potential problem of periodic charge distribution. The effect of uneven distribution of the charges of a Bloch wall on the magnetostatic energy is studied, the effective width of the Bloch wall is determined, an analytical expression is found for this distribution of poles and finally the effective height of the surface layer is also determined. An expression is derived for the orientation of the vectors of magnetization in the surface layer with respect to the easy directions of magnetization. The stability of the basic domain structure up to an inclination of 6°of the plane under observation to the direction of easy magnetization and the dimensions of the domains in periodic closure structures follow from the calculations.

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Radical-scavenging activity of glutathione,chitin derivatives and their combination

Since chitosan and its amino-, cinnamo- or cinnamo-amino- derivatives are acid-soluble, the effect of acetic acid on hyaluronan (HA) macromolecules degraded by Cu(II) ions and ascorbate was examined to produce reactive oxygen species (ROS). Further, the effects of glutathione (GSH), chitosan and its derivatives, added individually or in combination, on the quenching of ROS and ABTS^˙+ cation radical were examined using rotational viscometry and ABTS assay, respectively. The results of the rotational viscometry indicated a rapid degradation of HA by ROS after the addition of acetic acid. Chitosan and its derivatives moderately decreased the rate of HA degradation, while GSH decreased the rate of HA degradation more significantly. Moreover, GSH enhanced the protection of HA macromolecules against their degradation in the presence of chitosan or its derivatives. The results of the ABTS assay confirmed the results of the rotational viscometry. The GSH in the combination with chitosan and its derivatives reduced ABTS^˙+ more intensively than when added individually.     

Dithiols as more effective than monothiols in protecting biomacromolecules from free-radical-mediated damage: in vitro oxidative degradation of high-molar-mass hyaluronan

Oxidative stress and the resulting damage to cellular and extracellular components has been observed in a variety of degenerative processes, including degenerative joint disorders, where high-molar-mass hyaluronan (HA) is often found to be massively degraded. The present study sought to test the hypothesis that dithiols are more effective in protecting biomacromolecules from free-radicalmediated damage than monothiols. The materials/thiols tested included bucillamine (BUC), dithioerythritol (DTE), dithiothreitol (DTT) and glutathione (GSH), as a reference, for their effectiveness in protecting HA from oxidative degradation induced in vitro. Since HA degradation results in a decrease in its dynamic viscosity, rotational viscometry was applied to follow HA oxidative degradation. The free-radical-scavenging activities of the thiols tested were determined by 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) and di(phenyl)-(2,4,6-trinitrophenyl)iminoazanium (DPPH) assays. It was found that all the dithiols in the concentration range tested protected HA from the oxidative degradation. On the other hand, monothiol GSH exerted protection only at high concentrations (10 μmol L^?1 and 100 μmol L^?1) and 1 μmol L^?1 of GSH even exhibited a prodegradative effect. The ABTS assay revealed free-radical scavenging activities in the following order: BUC, DTT, DTE, GSH, and that of the DPPH assay: BUC, DTE, DTT, GSH. In conclusion, it was demonstrated that dithiols may be more effective than monothiols in affording biomacromolecule protection from oxidative degradation.     

Lithium insertion into TiO2 (anatase): electrochemistry,Raman spectroscopy,and isotope labeling

This article presents a critical discussion of selected structural aspects of electrochemical Li-insertion into TiO₂ (anatase). Recent works are reviewed (almost half of the cited works is from 2010+) with a special attention to the crystal-face-specific phenomena, Raman spectroscopy, and single-crystal and nanocrystalline electrodes. The benefits of isotopic labeling are highlighted for the in-depth understanding of Raman spectra and the Raman spectroelectrochemistry of Li-insertion. The persisting open questions and contradictory issues in the field are discussed too.     

Special isomorphisms of F[x 1,..., x n ] preserving GCD and their use

On the ring R = F[x ₁,..., x _n ] of polynomials in n variables over a field F special isomorphisms A’s of R into R are defined which preserve the greatest common divisor of two polynomials. The ring R is extended to the ring S: = F[[x ₁,..., x _n ]]⁺ and the ring T: = F[[x ₁,..., x _n ]] of generalized polynomials in such a way that the exponents of the variables are non-negative rational numbers and rational numbers, respectively. The isomorphisms A’s are extended to automorphisms B’s of the ring S. Using the property that the isomorphisms A’s preserve GCD it is shown that any pair of generalized polynomials from S has the greatest common divisor and the automorphisms B’s preserve GCD. On the basis of this Theorem it is proved that any pair of generalized polynomials from the ring T = F[[x ₁,..., x _n ]] has a greatest common divisor.     

Travel groupoids

In this paper, by a travel groupoid is meant an ordered pair (V, *) such that V is a nonempty set and * is a binary operation on V satisfying the following two conditions for all u, v ∈ V: