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11.
Gamma-irradiation was found to affect the physicochemical properties of dry red kidney beans. The highest dose used (8 kGy) significantly (P0.05) modified the extent of deamidation, the number of sulfhydryl groups, as well as the solubility and the hydrophobicity of the protein. Deamidation, protein solubility and hydrophobicity all increased with the irradiation dose while the number of sulfhydryl groups was reduced by the treatment. Furthermore, irradiation also affected the outgrowth of natural filamentous fungi contaminants present on the dry beans. A dose of 1.5 kGy reduced the number of filamentous fungi by 2 log cycles immediately after treatment. However, the highest dose used (3 kGy) did not eliminate the filamentous fungi completely. Moreover, the filamentous fungi population was a lot less diversified on the irradiated samples. Species of Aspergillus sp. and Penicillium sp. were more abundant on the unirradiated beans while the beans irradiated at 3 kGy contained were predominantly infected by species of Rhizopus sp. , Cladosporium sp. and Alternaria sp. 相似文献
12.
Jalal Ghilane Olivier Fontaine Pascal Martin Jean-Christophe Lacroix Hyacinthe Randriamahazaka 《Electrochemistry communications》2008,10(8):1205-1209
The electrochemical reduction of noble metal electrodes in the presence of redox ionic liquid, 1-ferrocenylethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [FcEMIM][TFSI], was investigated by cyclic voltammetry. Our experiments suggest the formation of metal with negative oxidation states, in the cases of platinum and gold electrodes [Mn−, FcEMIM+]. By analogy with the previous work, the formation of these phases is concomitant with the insertion of the supporting electrolyte; which correspond in our experimental condition to the redox cation of the ionic liquid. As an exciting result, the electrochemical investigations of the reduced electrode in electrolytic solution, containing solvent and supporting electrolyte, evidence the presence of the ferrocene groups at the electrode surface. Moreover, the reduced electrode exhibits the presence of the ferrocene even after, contact with air, after ultrasound, and after physical polishing, highlighting the large stability of this organo-metallic phases formed in this media. The AFM investigations demonstrate the morphological change of the platinum surface after the reduction process. Finally, our works bring a formal electrochemical proof of the presence of the ionic liquid cation inside the electrode material after the cathodic treatment in this media. 相似文献
13.
Ekaterina P. Nesterenko Pavel N. Nesterenko Damian Connolly Flavie Lacroix Brett Paull 《Journal of chromatography. A》2010,1217(14):2138-2146
A new method for the fixation of polymethacrylate monoliths within titanium tubing of up to 0.8 mm I.D. for use as a chromatographic column under elevated temperatures and pressures is described. The preparation of butyl methacrylate–ethylene dimethacrylate-based monolithic stationary phases with desired porous structures was achieved within titanium tubing with pre-oxidised internal walls. The oxidised titanium surface was subsequently silanised with 3-trimethoxysilylpropyl methacrylate resulting in tight bonding of butyl methacrylate porous monolith to the internal walls, providing stationary phase stability at column temperatures up to 110 °C and at operating column pressure drops of >28 MPa. The titanium housed monoliths exhibited a uniform and dense porous structure, which provided peak efficiencies of up to 59,000 theoretical plates per meter when evaluated for the separation of small molecules in reversed-phase mode, under optimal conditions (achieved at 15 μL/min and temperature of 110 °C for naphthalene with a retention factor, k = 0.58). The developed column was applied to the reversed-phase isocratic separation of a text mixture of pesticides. 相似文献
14.
Heterogeneous photocatalysis is a recent discipline particularly well adapted to environmental problems since it operates
at room temperature by replacing catalyst’s thermo-activation by photo-activation (or replacing phonons by photons). In fine
chemistry, high initial selectivities (100%) are obtained in dry organic media in selective mild oxidation of gaseous or liquid
hydrocarbons. Similarly, 100% selectivities were obtained in sulfur-involving photocatalytic reactions, noted as “thio-photocatalysis”.
Environmental photocatalysis is active in water and air decontamination and can advantageously use the UV-A solar spectrum
for outside applications. 相似文献
15.
Mélanie Turgis Mathieu Millette Stéphane Salmieri Monique Lacroix 《Radiation Physics and Chemistry》2012,81(8):1170-1172
A combined treatment of an edible coating composed of trans-cinnamaldehyde (TCN; 0.5% p/p) with γ-irradiation was investigated against Listeria inoculated in peeled mini-carrots. First, the D10 value (γ-irradiation dose required to eliminate 90% of the bacterial population) of TCN was evaluated under air. This treatment resulted in a 3.66-fold increase in relative bacterial radiosensitivity (RBR) as compared to the control without antimicrobial coating. Secondly, the shelf life of mini-carrots during 21 day of storage at 4 °C was studied. Antimicrobial coating containing TCN was assayed in combination with two irradiation doses (0.25 and 0.5 kGy). Results suggested that the inactive coating did not have any antimicrobial effect against Listeria while the coating containing TCN resulted in a 1.29 log reduction in carrots packed under air after 21 days of storage. Hence, these observations indicated that the combination of irradiation with antimicrobial coating played an important role in enhancing the radiosensitization of Listeria to γ-irradiation. 相似文献
16.
In order to enhance the shelf-life of edible mature mushrooms Agaricus bisporus, 2 kGy ionising treatments were applied at two different dose rates: 4.5 kGy/h (I−) and 32 kGy/h (I+). Both I+ and I− showed 2 and 4 days shelf-life enhancement compared to the control (C). Before day 9, no significant difference (p>0.05) in L* value was detected in irradiated mushrooms. However, after day 9, the highest observed L* value (whiteness) was obtained for the mushrooms irradiated in I−. Analyses of phenolic compounds revealed that mushrooms in I− contained more phenols than I+ and C, the latter containing the lower level of phenols. The polyphenol oxidase (PPO) activities of irradiated mushrooms, analysed via catechol oxidase and dopa oxidase substrates, resulted in being significantly lowered (p0.05) compared to C, with a further decrease in I+. Analyses of the enzymes indicated that PPO activity was lower in I+, contrasting with its lower phenol concentration. Ionising treatments also increased significantly (p0.05) the phenylalanine ammonia-lyase (PAL) activity. The observation of mushrooms cellular membranes, by electronic microscopy, revealed a better preserved integrity in I− than in I+. It is thus assumed that the browning effect observed in I+ was caused by both the decompartimentation of vacuolar phenol and by the entry of molecular oxygen into the cell cytoplasm. The synergetic effect of the residual active PPO and the molecular oxygen, in contact with the phenols, allowed an increased oxidation rate and, therefore, a more pronounced browning in I+ than in I−. 相似文献
17.
A simple collimating lens system was used to modify, at modest cost, a flame atomic absorption spectrophotometer for performing flameless atomic absorption spectrophotometry (f.a.a.s.) analysis with the Varian Model 63 Carbon Rod Atomizer. The source light was collimated into a 3-mm diameter beam which passed through the carbon tube and was focused by a second lens to work efficiently with the monochromator. The modified f.a.a.s. techniques extends the capability of the flame atomic absorption spectrophotometer to make possible analyses of trace elements. Good correlation of values for Zn, Fe, Cu, and Mn were obtained by use of the National Bureau of Standards Standard Reference Material Orchard Leaves. 相似文献
18.
19.
E.?Tomasi-GustafssonEmail author F.?Lacroix C.?Duterte G.?I.?Gakh 《The European Physical Journal A - Hadrons and Nuclei》2005,24(3):419-430
We perform a global analysis of the experimental data of the electromagnetic nucleon form factors, in space-like and time-like regions. We give the expressions of the observables in annihilation processes, such as p + ¯↦ℓ+ + ℓ-, ℓ = e or μ, in terms of form factors. We discuss some of the phenomenological models proposed in the literature for the space-like region, and consider their analytical continuation to the time-like region. After determining the parameters through a fit on the available data, we give predictions for the observables which will be experimentally accessible with large statistics, polarized annihilation reactions 相似文献
20.
Shevchenko A Carter J Fearick RW Förtsch SV Fujita H Fujita Y Kalmykov Y Lacroix D Lawrie JJ von Neumann-Cosel P Neveling R Ponomarev VY Richter A Sideras-Haddad E Smit FD Wambach J 《Physical review letters》2004,93(12):122501
Fine structure in the energy region of the isoscalar giant quadrupole resonance in nuclei is observed in high-resolution proton scattering experiments at iThemba LABS over a wide mass range. A novel method based on wavelet transforms is introduced for the extraction of scales characterizing the fine structure. A comparison with microscopic model calculations including two-particle two-hole (2p2h) degrees of freedom identifies the coupling to surface vibrations as the main source of the observed scales. A generic pattern is also found for the stochastic coupling to the background of the more complex states. 相似文献