全文获取类型
收费全文 | 13220篇 |
免费 | 573篇 |
国内免费 | 7篇 |
专业分类
化学 | 9843篇 |
晶体学 | 74篇 |
力学 | 221篇 |
数学 | 1799篇 |
物理学 | 1863篇 |
出版年
2023年 | 130篇 |
2022年 | 79篇 |
2021年 | 135篇 |
2020年 | 228篇 |
2019年 | 229篇 |
2018年 | 149篇 |
2017年 | 136篇 |
2016年 | 457篇 |
2015年 | 487篇 |
2014年 | 507篇 |
2013年 | 940篇 |
2012年 | 1075篇 |
2011年 | 989篇 |
2010年 | 587篇 |
2009年 | 442篇 |
2008年 | 912篇 |
2007年 | 860篇 |
2006年 | 851篇 |
2005年 | 768篇 |
2004年 | 635篇 |
2003年 | 533篇 |
2002年 | 473篇 |
2001年 | 189篇 |
2000年 | 187篇 |
1999年 | 105篇 |
1998年 | 85篇 |
1997年 | 85篇 |
1996年 | 118篇 |
1995年 | 87篇 |
1994年 | 64篇 |
1993年 | 90篇 |
1992年 | 67篇 |
1991年 | 52篇 |
1990年 | 50篇 |
1989年 | 41篇 |
1988年 | 39篇 |
1987年 | 38篇 |
1986年 | 60篇 |
1985年 | 88篇 |
1984年 | 70篇 |
1983年 | 41篇 |
1982年 | 59篇 |
1981年 | 62篇 |
1980年 | 62篇 |
1979年 | 53篇 |
1978年 | 54篇 |
1977年 | 39篇 |
1976年 | 48篇 |
1975年 | 28篇 |
1974年 | 28篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Abstract. We propose a general approach to deal with nonlinear, nonconvex variational problems based on a reformulation of the problem
resulting in an optimization problem with linear cost functional and convex constraints. As a first step we explicitly explore
these ideas to some one-dimensional variational problems and obtain specific conclusions of an analytical and numerical nature. 相似文献
2.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
3.
Monika Goikoetxea María J. Barandiaran José M. Asua 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5838-5846
The mechanisms involved in the formation of n‐butanol during the synthesis of butyl acrylate containing latices were investigated. The experimental results showed that neither the hydrolysis of butyl acrylate nor of the ester bond in the butyl acrylate segments of the polymer played a major role in the formation of n‐butanol, which was mainly generated from the polymer backbone, by transfer reactions to polymer chain followed by cyclization. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5838–5846, 2007 相似文献
4.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
5.
Simple expressions are given for the mean delay, mean waiting time, and mean busy period length in a multiplexer. Data streams with active periods having a general distribution are permitted, and the data rate during the active periods can be random. Data can also arrive in batches. The key restrictions of the model are that the sources are independent, idle periods are exponentially distributed, and a source generates at least enough data during an active period to keep the server busy throughout the period. The exact formulas allow evaluation of the error in approximations such as a heavy traffic diffusion approximation.Both continuous and discrete time models are considered. The discrete-time model includes that studied by Viterbi and subsequently generalized by Neuts. The Pollaczek-Khinchine formula for the mean amount of work in anM/GI/1 queue is retrieved as a limiting case.Preliminary version presented at IEEE INFOCOM, San Francisco, April 1993. 相似文献
6.
We analyze the well-posedness of the initial value problem for the dissipative quasi-geostrophic equations in the subcritical
case. Mild solutions are obtained in several spaces with the right homogeneity to allow the existence of self-similar solutions.
While the only small self-similar solution in the strong
Lp{\cal L}^{p}
space is the null solution, infinitely many self-similar solutions do exist in weak-
Lp{\cal L}^{p}
spaces and in a recently introduced [7] space of tempered distributions. The asymptotic stability of solutions is obtained
in both spaces, and as a consequence, a criterion of self-similarity persistence at large times is obtained. 相似文献
7.
Eu3+ in ca. 10 wt% europium-exchanged Y-zeolite is partially reduced by treatment in hydrogen at 600°C to Eu2+. The reduction of Eu3+ is more readily achieved in Y-zeolite than in europium(III) oxide. The discrepancy in the extent of reduction as revealed by151Eu Mössbauer spectroscopy and near edge X-ray absorption fine structure (XANES) is associated with any difference in the recoil free fractions of Eu2+ and Eu3+ which may exist at 298 K and the enhanced sensitivity of the XANES to changes in the europium oxidation state. 相似文献
8.
José Trashorras 《Comptes Rendus Mathematique》2003,336(1):69-74
We improve the Large Deviations Principle satisfied by a Coarse Grained process already analyzed by Boucher, Ellis and Turkington [Ann. Probab. 27 (1999) 297–324]. To cite this article: J. Trashorras, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
9.
José Natário 《General Relativity and Gravitation》2006,38(3):475-484
We find a class of warp drive spacetimes possessing Newtonian limits, which we then determine. The same method is used to
compute Newtonian limits of the Schwarzschild solution and spatially flat Friedmann-Robertson-Walker cosmological models.
This work was partially supported by FCT/POCTI/FEDER. 相似文献
10.
We prove the vanishing of the Koszul homology group H
μ(Kos(M)μ), where μ is the minimal number of generators of M. We give a counterexample that the Koszul complex of a module is not always
acyclic and show its relationship with the homology of commutative rings. 相似文献