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91.
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93.
Giuseppe Palleschi Mohammad H. Faridnia Glenn J. Lubrano George G. Guilbault 《Analytica chimica acta》1991
Electrochemical biosensors for lactate were assembled and used for the determination of lactic acid in saliva. Saliva was collected from healthy subjects and immediately screened for its lactate content. The electrochemical and biological interferences from saliva were discriminated by using a dual platinum electrode and blocking membranes. The stability, reproducibility and lifetime of the probe were studied. Lactate was measured in eight subjects in fasting conditions and after eating, showing an increase in lactate for each subject after meals. Correlation with a spectrophotometric lactate measurement is reported. Subjects before, during and after physical exercise showed consistent variations of lactate in saliva. 相似文献
94.
A. E. Hughes C. MacRae N. Wilson A. Torpy T. H. Muster A. M. Glenn 《Surface and interface analysis : SIA》2010,42(4):334-338
Sheet AA2024‐T3 is probably one of the most studied aluminium alloys in the corrosion field, because, with copper as an alloying addition, it is one of the most corrosion‐prone aluminium alloys. This paper reports new findings on the composition and distribution of intermetallic (IM) particles in AA2024‐T3 through the examination of over 80 000 compositional domains in nearly 18 000 IM particles. This work was achieved by using an electron microprobe to map out 2 × 2 mm2 at a step size of 400 nm. This study revealed that the composition of individual particles can vary considerably from ‘accepted’ compositions. Domains within particles were extensive across the surface. Because such a large area was mapped, it was possible to subdivide this area and to look at the variation of particle statistics from region to region, providing some information on the statistical variation for small electrodes. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
95.
Chen MZ McLaughlin M Takahashi M Tarselli MA Yang D Umemura S Micalizio GC 《The Journal of organic chemistry》2010,75(23):8048-8059
Regio-, diastereo-, and enantioselective coupling reactions between imines and allylic alcohols have been developed. These coupling reactions deliver complex homoallylic amine products through a convergent C-C bond forming process that does not proceed through intermediate allylic organometallic reagents. In general, convergent coupling, by exposure of an allylic alkoxide to a preformed Ti-imine complex, occurs with allylic transposition in a predictable and stereocontrolled manner. While simple diastereoselection in these reactions is high, delivering anti-products with ≥20:1 selectivity, the organometallic transformation described is compatible with a diverse range of functionality and substrates (including aliphatic and aromatic imines, allylic silanes, trisubstituted alkenes, vinyl- and aryl halides, trifluoromethyl groups, thioethers, and aromatic heterocycles). Alkene geometry of the products is a complex function of the allylic alcohol structure and is consistent with a mechanistic proposal based on syn-carbometalation followed by syn-elimination by way of a boat-like transition state geometry. Single asymmetric coupling reactions provide a means to translate the stereochemical information of the allylic alcohol to the homoallylic amine or to control diastereoselection in the coupling reactions of achiral allylic alcohols with chiral imines. Double asymmetric coupling reactions are also described that afford a unique means to control stereoselection in these complex convergent coupling processes. Finally, empirical models are proposed that are consistent with the observed stereochemical course of these coupling reactions en route to chiral homoallylic amines possessing di- or trisubstituted alkenes and anti- or syn- relative stereochemistry at the allylic and homoallylic positions. 相似文献
96.
Mitsushiro Nomura Shigemi Kondo Eriko Suzuki Glenn V. Alea Chikako Fujita-Takayama Masatsugu Kajitani 《Journal of organometallic chemistry》2010,695(21):2366-2895
Eight new sulfur-rich [CpCo(dithiolene)] complexes were synthesized from [Zn(dmit)2]2− as a starting material. The structures, electrochemical behavior and electronic absorption spectra of the sulfur-rich [CpCo(S2C2S2Y)] complexes could be compared with the early data of analogous Ni complexes. [CpCo(pddt)] (Y = -(CH2)3-), [CpCo(dpdt)] (Y = -CH2C(CH2)CH2-), [CpCo(bddt)] (Y = -(CH2)4-), [CpCo(dtdt)] (Y = -CH2SCH2-) and [CpCo(poddt)] (Y = -CH2C(O)CH2-) crystallized in all isostructural with the corresponding paramagnetic [CpNi(dithiolene)] complexes, but [CpCo(dmid)] (Y = CO), [CpCo(dddt)] (Y = -(CH2)2-) and [CpCo(F2pddt)] (Y = -CH2CF2CH2-) crystallized in non-isostructural with them. These molecules are associated with intermolecular short S?S contacts in the crystals. [CpCo(F2pddt)] did not show any remarkable S?S contacts but indicated interesting fluorine segregation and Cp?Cp face-to-face interactions. Redox potentials of [CpCo(dithiolene)] complexes were obtained with the cyclic voltammetry measurements and dimerized by electrochemical oxidations. Electronic absorption spectra of [CpCo(dithiolene)] complexes showed visible absorption in the range of 585-701 nm as lowest energy wavelengths (? = 9800-11,800 M−1 cm−1) in solutions, and they were higher energy than those of [CpNi(dithiolene)] complexes (near-IR). 相似文献
97.
The reference scan method is a simple yet powerful method for measuring spatial drift of the x-ray spot during a low-cone-angle μ-CT experiment. As long as the drift is smooth, and occurring on a time scale that is long compared to the acquisition time of each projection, this method provides a way to compensate for the drift by applying 2D in-plane translations to the radiographs. Here we show that this compensation may be extended to the regime of high-magnification, high-cone-angle CT experiments where source drift perpendicular to the detector plane can cause significant magnification changes throughout the acquisition. 相似文献
98.
Steiner quadruple systems are set systems in which every triple is contained in a unique quadruple. It is well known that Steiner quadruple systems of order v, or SQS(v), exist if and only if . Universal cycles, introduced by Chung, Diaconis, and Graham in 1992, are a type of cyclic Gray code. Overlap cycles are generalizations of universal cycles that were introduced in 2010 by Godbole, et al. Using Hanani's SQS constructions, we show that for every with there exists an SQS(v) that admits a 1‐overlap cycle. 相似文献
99.
Robert F. Allen Flavia Colonna Glenn R. Easley 《Mediterranean Journal of Mathematics》2014,11(1):97-108
The Lipschitz space ${\mathcal{L}}$ of an infinite tree T rooted at o is defined as the space consisting of the functions ${f : T \rightarrow \mathbb{C}}$ such that $$\beta_f = {\rm sup}\{|f(v) - f(v^-)| : v \in T\backslash\{o\}, \,v^- {\rm parent \, of \,} v\}$$ is finite. Under the norm ${\|f\|_\mathcal{L} = |f(o)|+\beta_f,\mathcal{L}}$ is a Banach space. In this article, the functions φ mapping T into itself whose induced composition operator ${C_{\varphi} : f \mapsto f \circ \varphi}$ on the Lipschitz space is bounded, compact, or an isometry, are characterized. Specifically, it is shown that the symbols of the bounded composition operators are the Lipschitz maps of T into itself viewed as a metric space under the edge-counting distance. The symbols inducing compact operators have finite range while those inducing isometries on ${\mathcal{L}}$ are precisely the onto maps fixing the root and whose images of neighboring vertices coincide or are themselves neighboring vertices. Finally, the spectrum of the operators ${C_\varphi}$ that are isometries is studied in detail. 相似文献
100.
Given a totally real field F and a prime integer p which is unramified in F, we construct p-adic families of overconvergent Hilbert modular forms (of non-necessarily parallel weight) as sections of, so called, overconvergent Hilbert modular sheaves. We prove that the classical Hilbert modular forms of integral weights are overconvergent in our sense. We compare our notion with Katz’s definition of p-adic Hilbert modular forms. For F = ?, we prove that our notion of (families of) overconvergent elliptic modular forms coincides with those of R. Coleman and V. Pilloni. 相似文献