色氨酸与稀土元素Eu(Ⅲ)配合物的合成及配位位置的研究

氨基酸是生命系统中蛋白质的基本结构单位.本文通过共沉淀法合成了色氨酸与稀土元素Eu(Ⅲ)的固体配合物,并对其进行了光谱及波谱研究,确定了配合物的配位机理及配位点.     

Magnetization of a Gapped Spin 1/2 Antiferromagnetic Ising Chain near the Critical External Field

We study the magnetization of gapped spin 1/2 XXZ Heisenberg Ising chains and calculate the scattering length among massive spinons. We obtain the magnetization close to the critical external magnetic field. The leading correction term determined by the scattering length among massive spinons is given. Our results are in agreement with exact results and with experimental results. We show that the deviation from the massive free hard core boson picture can be accounted very well by the leading correction term due to the spinon-spinon interaction. We show that the deviation increases along with the increasing of the Ising term.     

High—Dimensional Integrable Models with Infinitely Dimensional Virasoro—Type Symmetry Algebra

Using every realization of the Virasoro-type symmetry algebra[σ(f1),σ(f2)]=σ(f1f2-f2f1),we can obtain various high-dimensional integrable models under the meaning that they possess infinitely many symmetries,By means of a concrete realization ,many(3 1)-dimensional equations which possess Kac-Moody-Virasoro-type infinite dimensional symmetry algebras are obtained.     

自适应零限波束形成语音增强算法鲁棒性分析

分析了双传声器自适应零限波束形成语音增强算法对传声器不一致和本底噪声的鲁棒性。结果表明:信干比越高,算法对传声器不一致的鲁棒性越差;当信干比很低时,算法对相位不一致是鲁棒的。幅度不一致会降低算法对干扰的抑制能力,但引起的目标信号失真很小。相对于传声器不一致,本底噪声对算法性能的影响较小。对自适应滤波器权值加约束和对传声器做校准可以提高算法性能。     

均质旋转面绕旋转轴转动的转动惯量

根据转动惯量的定义推得任意形状均质旋转面对旋转轴的转动惯量的计算公式,文中讨论了鼓形面、花瓶形面、圆台面、圆锥面、圆柱面等特殊形状均质旋转面对旋转轴的转动惯量.     

基于反应谱值分析的爆破震动破坏评估研究

采用反应谱方法研究了爆破震动信号的振动速度和频率特征,提出了采用反应谱曲线积分值来评估爆破震动破坏效应。通过对289组爆破地震波数据的统计表明,在反应谱曲线的积分值小于5时,爆破地震动不会对所研究的普通民房结构物产生震动破坏效应。     

铁镧复合氧化物纳米米微粒的制备及其光催化性能

以溶胶-凝胶法制备了纳米铁镧复合氧化物.通过了XRD、TG-DTA等手段,对该氧化物进行了分析.研究了焙烧温度、光催化剂的用量、光照等因素对催化剂光催化降解活性染料的影响.并用红外光谱分析方法验证光催化降解效果.结果表明在适当的用量和700C焙烧并在紫外光照射下铁镧复合氧化物对活性翠蓝KGL和活性B-GFF黑有较强的光催化降解活性.     

内积在溶液浓度测定中的应用

提出内积的溶液浓度测定方法。该方法计算已知浓度溶液透光率曲线与0号溶液（浓度最低的溶液）透光率曲线的内积ρ,确定溶液的ρ-C曲线,然后测定未知溶液的透光率曲线,计算其与0号溶液透光率曲线的内积,并利用已建立好的ρ-C曲线进行插值以估计溶液浓度。由于该方法利用了透光率曲线的全部信息,因此对溶液浓度的估计精度较高。对K2Cr2O7溶液浓度的测定实验结果表明,该方法对溶液浓度的估计相对误差小于1.00%。     

关于自由射流计算的两点考虑

本文用Multi-Block算法和标准的κ-ε模型计算轴对称自由射流,计算中发现:(1)不同的纵向网格宽度比(疏密度比)会导致不同的扩张速率的计算结果。(2)在相同的网格疏密度比下,由于不同喷管长度L带来的射流上游进口的湍流结构的变化与下游射流扩张速率有清晰的关联。     

Effect of Ionic Liquids on Catalytic Characteristics of Horse Liver Alcohol Dehydrogenase

The catalytic characteristics of horse liver alcohol dehydrogenase （HLADH） in the systems involving ionic liquids （ILs） （BMIm·Cl, BMIm·Br, BMIm·PF6, BMIm·BF4 BMIm·OTf and EMIm·Cl） were examined. HLADH displayed higher oxidation activity towards ethanol in the systems containing BMIm·Cl, BMIm·Br, EMIm·Cl or BMIm·PF6 with proper content than that in the IL-free buffer. An excessive amount of these ILs in the reaction systems resulted in an obvious decline in enzymatic activity. BMIm·BF4 and BMIm·OTf of any content investigated could considerably inhibit the enzyme. The anions of ILs showed significant effect on the activity, kinetic parameters and activation energy of HLADH-mediated ethanol oxidation. Additionally, BMIm·Cl, BMIm·Br, EMIm·Cl and BMIm·PF6 boosted markedly the thermostability of HLADH, while the enzyme was less thermostable in BMIm·BF4 or BMIm·OTf-containing systems. The associated conformational changes in HLADH caused by ILs were examined by UV technique.