Electrical Characterization of Metal-Insulator-Metal Capacitors with Atomic-Layer-Deposited HfO2 Dielectrics for Radio Frequency Integrated Circuit Application

Metal-insulator-metal （MIM） capacitors with atomic-layer-deposited HfO2 dielectric and TaN electrodes are investigated for rf integrated circuit applications. For 12nm HfO2, the fabricated capacitor exhibits a high capacitance density of 15.5fF/μm2 at 100kHz, a small leakage current density of 6.4 × 10^-9 A/cm^2 at 1.8V and 125℃, a breakdown electric field of 2.6 MV//cm as well as voltage coefficients of capacitance （VCCs） of 2110ppm/V^2 and -824 ppm/V at 100kHz. Further, it is deduced that the conduction mechanism in the high field range is dominated by the Poole-Frenkel emission, and the conduction mechanism in the low field range is possibly related to trap-assisted tunnelling. Finally, comparison of various HfO2 MIM capacitors is present, suggesting that the present MIM capacitor is a promising candidate for future rf integrated circuit application.     

XAD树脂分组水稻土富里酸组分的脂肪族特性

为准确把握由多种物质组成的富里酸的化学性质及结构,将富里酸按一定的性质及构造相似的特征进行细划分,从而减小富里酸的复杂性。该研究以通用缓冲液(pH 2)平衡后的XAD-8树脂能吸附H+型富里酸,利用pH 4.8,pH 7.0,pH 11.0的该通用缓冲液,可将富里酸中亲水性物质按解离程度分离为三种组分,再用水、乙醇将富里酸中的疏水性物质划分为的强、弱两部分。分析各组分的元素组成,红外光谱和核磁共振(1HNMR)的特征,认为在低pH缓冲液溶出的组分中含氧量、羧基含量高于水和乙醇溶出的组分,而脂肪性成分含量则低于水和乙醇溶出的组分,并且脂肪族侧链较短。     

共振瑞利散射法测定环境水样中痕量砷(Ⅲ)

建立了一种测定环境水中痕量砷(Ⅲ)的共振瑞利散射(RRS)新方法.在pH=6.6 KH2PO4-Na2HPO4(PBS)缓冲溶液中和聚乙烯醇(PVA)存在时,I-3与结晶紫(CV)能生成稳定的离子缔合物,导致共振瑞利散射增强.当加入微量As(Ⅲ)时,碘能定量氧化As(Ⅲ),导致共振瑞利散射减弱.在0.1-3.0 μg/25mL浓度范围内,体系的共振瑞利散射改变值△IRRS与As(Ⅲ)浓度呈线性关系,方法检出限为1.0μg/L.已用于环境水样中痕量As(Ⅲ)的测定,结果令人满意.     

大气激光通信系统建模及关键技术研究

对光通信系统的关键技术进行了研究分析，通过在不同天气条件下的场外测量建立出典型天气条件下的信道模型，制定了信源编码及信道编码方式及相关参量，并用MATLAB对其进行了半实物仿真，仿真结果表明，引入256-PPM信源编码及RS（255，223）信道编码对系统通信性能的提高是行之有效的．     

一种新的六氢喹啉衍生物的NMR研究

应用¹H NMR,¹³C NMR,DEPT,¹H-¹H COSY,HSQC,HMBC等多种NMR实验测试分析方法,确证了一种新的六氢喹啉衍生物2,7,7-三甲基-4-(4-羟基-3-甲氧基）苯基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸甲酯的结构,并对它的¹H、¹³C信号进行了归属.     

表面活性剂及水溶性功能高分子的NMR研究

核磁共振（NMR）技术是研究表面活性剂在溶液中聚集状态的一种非常有用的工具,本文运用多种NMR技术研究了几种不同类型表面活性剂及水溶性功能高分子在水溶液中的聚集行为： 1. 季铵盐型双子表面活性剂16-4-16的聚集行为季铵盐型双子表面活性剂N,N′-双(十六烷基二甲基)-α,ω-丁烷溴化铵(16-4-16)分子中联接基团及靠近离子头的质子位于胶束的壳层, 运动受到一定限制. 而距离离子头较远的烷烃链位于胶束的内部,运动相对自由. 与对应的单链表面活性剂十六烷基三甲基溴化铵(CTAB)相比,16-4-16形成的胶束堆积更为紧密. 通过NOESY谱中交叉峰强度的定量计算,认为16-4-16在胶束中分子以上下交错排列的方式形成球形聚集体.  2. 脱氧胆酸钠与十六烷基三甲基溴化铵的相互作用在脱氧胆酸钠(NaDC)溶液中,NaDC质子H3与其他质子不同,其横向弛豫时间(T₂)表现为双指数衰减,表明此质子可能存在两种不同的状态. 实验证明,其它胆酸盐的H3的横向弛豫也呈现双指数衰减. 因此推测在胆酸盐的稀溶液中,3-OH质子和羰基氧之间有可能存在氢键作用,形成了头尾相连的分子对结构.  在NaDC和CTAB的混合溶液中,两者形成1∶1的混合胶束. 用NOESY和ROESY研究混合胶束的结构,显示CTAB的离子头位于NaDC的羧酸基团附近. 这可能是正负离子之间的静电性相互作用的结果.  3. 丙烯酰胺/丙烯酸模板共聚物的微结构研究了不同pH值条件下,丙烯酰胺和丙烯酸共聚物分子在水溶液中的聚集形态. 在酸性溶液中,分子内的氢键致使聚集体形成较为紧密的堆积,侧链的苯氧基团运动受阻;随着溶液pH值的增大,丙烯酸电离产生的阴离子使得分子间的静电斥力增大,分子链变得伸展,分子间的氢键作用导致了聚集体体积变大. 当溶液呈强碱性,丙烯酸完全电离,氢键作用力被破坏,分子呈现自由伸展的状态,侧链的苯氧基团运动相对自由.     

Sensitivity of Exponents of Three-Power Laws to Hybrid Ratio in Weighted HUHPM

The sensitivity of exponents of three-power laws for node degree, node strength and edged weight to hybrid ratio are studied analytically and numerically in the weighted harmonious unifying hybrid preferential model （HUHPM）, which is extended from an-weighted hybrid preferential attachment model we proposed previously [Chin. Phys. Lett. 22 （2005）719]. Our weighted HUHPMs plus the Barrat-Barthelemy-Vespignani model and the traffic-driven evolution model, respectively, are taken as two typical examples for demonstration and application of the HUHPM.     

Transmission Frequency Properties of Elastic Waves along a Hetero-Phononic Crystal Waveguide

We investigate the propagation properties of hetero-phononic crystal waveguides by the improved eigen-mode matching theory, which can be used at same time to calculate both the transmission （reflection） coefficient and band structure. The numerical results show that the transmission frequency range is the same as the common range for two uniform waveguides composing the hereto-system, and the gap of any composite waveguide is also the gap of the hetero-phononic crystals waveguide.     

Isotope Dependence of Superheavy Nucleus Formation Cross Section

The dynamical process in the superheavy nucleus synthesis is studied on the basis of the two-dimensional Smoluchowski equation. Special attention is paid to the isotope dependence of the cross section for the superheavy nucleus formation by means of making a comparison among the reaction systems of ^54Re＋204pb, ^56Re ＋206Pb, and ^58Fe＋^208Pb. It is found by this comparison that the formation cross section is very sensitive to the conditional saddle-point height and the neutron separation energy of the compound nucleus. Reaction systems with lower height of conditional saddle-point and smaller neutron separation energy are more favourable for the synthesis of the superheavy nucleus.     

Magnetic Properties of Melted ThMn12-Type Carbides and Their Nitrides

The carbides of NdDy0.2Fe12-yMoyC0.6 （y = 1.5, 2） crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongly enhanced with the addition of carbon. Upon the carbonation the saturation magnetization Ms is increased by about 20emu/g and the Curie temperature Tc is enhanced by 40-70K. The spin reorientation （SR） temperature decreases from 125 K for NdDy0.2Fe10Mo2 to 55 K for NdDy0.2Fe10MO2C0.6 indicating the change of magnetocrystalline anisotropy in the Nd sublattice. It is found that the intrinsic magnetic properties of the carbides can be improved by further nitrogenation, The composite carbon-nitrogen compounds show a Tc - 560K, M8 - 105 emu/g and Ha （anisotropy field） - 86kOe for NdDy0.2Fe10Mo2Co.6Nz and a Tc- 628K, M8 - 119 emu/g and Ha - 115kOe for NdDy0.2Fe10.5Mo1.5C0.6Nz. These magnetic properties are even better than those of simple nitrides, suggesting that these compounds can be considered as a good candidate for permanent magnet applications.