C_nP_4~4(n=1～7)团簇结构与能量的密度泛函研究

使用分子图形软件设计出多种CnP-4(n =1～ 7)的结构模型 ,并进行B3LYP密度泛函几何构型优化和振动频率计算 .最稳定的CP-4和C2 P-3 都是平面环状结构 .最稳定的CnP-4(n =3 ,5 ,7)结构在直碳链的一端连接 1个磷原子且另一端是P3 C的四元环的平面结构 .最稳定的CnP-4(n =4,6)结构在直碳链的一端连接 1个磷原子且另一端是P3 的三元环的锄状结构 .直碳链可与平面环的磷原子生成大π键 .大多数构型是由C2 ,C3 ,C4子结构以环状或链状方式组成的 .碳原子与磷原子以交替方式排列的结构数量少、能量高 .     

Radiative lifetimes of Rydberg states of BeⅠ and BeⅢ

By using the multichannel quantum defect theory(MQDT),we have evaluated the energy levels and lifetimes of 2sns ^3 S1,2snd ^3D(n=3-25)of BeI and 1 sns ^3s1,1snd ^3D(n=3-25)of BeⅢ,These energies and lifetimes that we have calculated not only agree with the recent measurements and theoretical calculation of Ref.4 and Ref.3, but also predict the lifetimes of 66 other highly excited states.     

Stationary Intensity Distribution of Single-Mode Laser Driven by Additive and Multiplicative Colored Noises with Colored Cross-Correlation

Applying the approximate Fokker-Planck equation we derived, we obtain the analytic expression of thestationary laser intensity distribution Pst(Ⅰ) by studying the single-mode laser cubic model subject to colored cross-correlation additive and multiplicative noise, each of which is colored. Based on it, we discuss the effects on the stationarylaser intensity distribution Pst(Ⅰ) by cross-correlation between noises and “color“ of noises (non-Markovian effect) whenthe laser system is above the threshold. In detail, we analyze two cases: One is that the three correlation-times (i.e.the self-correlation and cross-correlation times of the additive and multiplicative noise) are chosen to be the same value(τ1 = τ2 = τ3 = τ). For this case, the effect of noise cross-correlation is investigated emphatically, and we detect thatonly when λ≠ 0 can the noise-induced transition occur in the Pst(Ⅰ) curve, and only when τ≠ 0 and λ≠ 0, can the“reentrant noise-induced transition“ occur. The other case is that the three correlation times are not the same value,τ1 ≠τ2 ≠τ3. For this case, we find that the noise-induced transition occurring in the Pst (Ⅰ) curve is entirely differentwhen the values of τ1, τ2, and τ3 are changed respectively. In particular, when τ2 (self-correlation time of additivenoise) is changing, the ratio of the two maximums of the Pst(Ⅰ) curve R exhibits an interesting phenomenon, “reentrantnoise-induced transition“, which demonstrates the effect of noise “color“ (non-Markovian effect).     

电感耦合等离子体发射光谱法同时测定涂料中的Pb、Cd、Cr和Hg

研究了电感耦合等离子体发射光谱法测定涂料中的重金属Pb，Cd，Cr和Hg，确定了测定涂料中的重金属Pb，Cd，Cr和Hg的最佳条件。加标回收试验和实际样品测定结果表明，方法的回收率和精密度分别在99.5％-110．0％和0．95％-1．98％范围，该方法快速、准确、可靠，各元素的检出限能满足涂料安全标准，适用于涂料的日常检验。     

一类广义长短波方程的整体适定性

In the present paper,we investigate the well-posedness of the global solution for the Cauchy problem of generalized long-short wave equations.Applying Kato's method for abstract quasi-linear evolution equations and a priori estimates of solution,we get the existence of globally smooth solution.     

管肋式辐射器排热特性的数值分析与优化设计

为得到按单面辐射方式布置的管肋式空间辐射器的排热特性，建立了相应的数学模型．采用数值模拟方法分析了管内流体温度、肋片几何尺寸和等效热沉温度对辐射器排热特性的影响，得到了不同参数值下辐射器单位面积排热量以及特定参数范围内的辐射器肋片最佳宽度和肋片效率．数值模拟结果对辐射器的工程结构设计以及空间站热管理方案的优化分析具有一定的参考价值．     

类氢及碱金属原子激发态寿命的半经典计算公式

根据对应原理,得到了类氢原子能态平均寿命半经典的计算公式τ(n,l),然后利用相对论单通道量子数亏损理论进行推广,得到用来计算考虑总角动量J的激发态寿命公式τ(n,l,l+1/2)和τ(n,l,l-1/2),利用单通道量子数亏损理论得到了碱金属原子n、l远大于1时激发态寿命的半经典公式τ(n.l)=τ0(m+M/nm/v/+M)2v7l(l+1/2)/n4,其计算结果和实验数据符合的很好.     

HER磁镜上硬X射线和热电子测量

一、引言 磁镜运行中,为了要知道它在电子回旋共振加热(ECRH)下形成热电子的参数,我们测量了硬X射线能谱、硬X射线发射的时间特性、不同磁场强度下形成热电子环的位置、以及热电子的脉冲幅度分布等。 HER是中国科学院等离子体物理研究所简单型磁镜装置,它的几何尺寸是,真空室长     

Cu(Ⅱ)与N-(2-羟苄基)-DL-丙氨酸、4，4′-联吡啶三元配合物的合成与晶体结构

近年来，基于金属和有机配体间的配位键合作用来设计和构筑具有多孔结构的超分子体系已成为现代化学、材料科学领域内非常活跃和充满前景的研究主题之一。为实现这目标，探求决定配合物配位几何构型的因素及通过配体的设计来控制配合物的结构已引起化学家们广泛的兴趣。     

铜(Ⅱ)-黄原酸配合物微粒体系的光谱研究及其在废水分析中的应用

采用分光光度法和共振散射光谱法研究了Cu(Ⅱ)-黄原酸配合物微粒体系。该配合物微粒体系在410nm处有一吸收峰,其吸光度与黄原酸浓度在1.0～40×10-5mol/L范围成良好线性关系,检出限(3σ)为0.5×10-5mol/L。据此建立了一个测定废水中黄原酸含量的分光光度法.该法灵敏、简便、快速、准确、重复性好,平均回收率为98%～100%,相对标准偏差RSD为0.9%～1.9%.共振散射光谱研究结果表明,该体系存在Cu(Ⅱ)-黄原酸配合物微粒,该微粒在360nm处存在共振散射效应.