全文获取类型
收费全文 | 47311篇 |
免费 | 9331篇 |
国内免费 | 18128篇 |
专业分类
化学 | 35475篇 |
晶体学 | 2083篇 |
力学 | 3723篇 |
综合类 | 1818篇 |
数学 | 7704篇 |
物理学 | 23967篇 |
出版年
2024年 | 124篇 |
2023年 | 484篇 |
2022年 | 1765篇 |
2021年 | 1783篇 |
2020年 | 1722篇 |
2019年 | 1658篇 |
2018年 | 1577篇 |
2017年 | 2400篇 |
2016年 | 1685篇 |
2015年 | 2437篇 |
2014年 | 3034篇 |
2013年 | 3855篇 |
2012年 | 3746篇 |
2011年 | 4096篇 |
2010年 | 4268篇 |
2009年 | 4426篇 |
2008年 | 4948篇 |
2007年 | 4533篇 |
2006年 | 4338篇 |
2005年 | 3754篇 |
2004年 | 2911篇 |
2003年 | 2007篇 |
2002年 | 2044篇 |
2001年 | 2117篇 |
2000年 | 2264篇 |
1999年 | 1236篇 |
1998年 | 672篇 |
1997年 | 483篇 |
1996年 | 452篇 |
1995年 | 457篇 |
1994年 | 428篇 |
1993年 | 439篇 |
1992年 | 391篇 |
1991年 | 272篇 |
1990年 | 291篇 |
1989年 | 295篇 |
1988年 | 195篇 |
1987年 | 192篇 |
1986年 | 143篇 |
1985年 | 121篇 |
1984年 | 138篇 |
1983年 | 91篇 |
1982年 | 83篇 |
1981年 | 93篇 |
1980年 | 64篇 |
1979年 | 81篇 |
1978年 | 26篇 |
1977年 | 21篇 |
1965年 | 19篇 |
1959年 | 22篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Four new derivatives of podophyllotoxin, N'-podophyllic acid-N-[3-(2, 2, 5, 5-te-tramethyl-pyrrolinenyloxy)] semicarbazide(GP-11, 6), podophyllic acid [3-(2,2,5,5-te-tramethyl-pyrrolinenyloxy)]hydrazone (GP-12, 7), podophyllic acid-[4-(2, 2, 6, 6-tetramethyl-1-hydroxy piperidine)]hydrazone(GP-1-OH, 8) and podophyllic acid[4-(2,2, 6, 6-tetramethyl piperidine)]hydrazone(GP-1-H, 9) were synthesized. The inhibition effect of the four new compounds on L-1210 cells were determined. The antitumor activity and toxicity of GP-1(2), GP-1-OH(8), GP-1-H(9) and VP-16-213(1) were discussed. 相似文献
992.
The photophysical properties of a series of sulfonated micromolecule(paratoluenesulfonic acid,HPTS) and macromolecules (linear and crosslinked poiys.tvrene) have been studied by steady-state fluorescence spectra. The results indicate that the ground sulfonated ring associations can form in both the micromolecules and the macromolecules. The fluorescence spectra of the sulfonated crosslinked copolymers appear a red-shift when the copolymers change from hydrogen-type to sodium-t~pe, and some new emission bands appear in the long-wavelength region.These results are explained in terms of synergetic effect of hydrogen bond, π-π interaction and crosslinking effect. 相似文献
993.
ZiYunLI XinSUN QiangXIAO ShouHeXIANG 《中国化学快报》2005,16(1):115-118
Catalytic properties of ZSM-5 zeolite samples pretreated with NaOH solution have been investigated. The samples are characterized by XRD, SEM, chemical analysis, and N2 adsorption.The results indicate that mesopores are created in ZSM-5 crystals under alkali treatment without change the microporous structure and acidic strength of the zeolite, but the crystallinity is greatly decreased under severe treatment. IR indicates that the concentration of silanol is greatly enriched by alkali treatment. The etherification activities of ZSM-5 zeolites are greatly increased byalkali-treatment. The noticeably improved catalytic activity of treated samples is ascribed to the formation of mesopores and greatly enriched silanol group. 相似文献
994.
采用物理涂附法将单链DNA固定到金表面得到ssDNA/Au修饰电极。研究表明,该电极在pH 5,0.2 mol/L NaAc-HAc缓冲底液中,可用于测定水中痕量Pb2 。Pb2 以Pb-DNA络合物的形式吸附在电极上,以示差脉冲伏安法测定Pb2 ,在0.15 V(vsSCE)处有灵敏的氧化峰,其峰电流与Pb2 浓度在5.0×10-8~1.0×10-6mol/L范围内呈良好的线性关系,此法的检测限为2.0×10-8mol/L,该修饰电极的稳定性和抗干扰性都较好。用该电极对饮用水中的Pb进行检测,得到了满意的结果。 相似文献
995.
The solvothermal reaction (D2O) of 2,6-dideuterium-4-cyanopyridine with ZnCl2 in the presence of NaN3 offers a novel complex Zn(OD)(C6H2D2N4) (1) in which Zn has a distorted tetrahedron composed of two N atoms from one tetrazoyl group and pyridyl group and two O atoms from two deuteratohydroxy OD groups. Crystal data for 1: Pbcn, a=1.456 8(5) nm, b=0.659 2(2) nm, c=1.645 3(5) nm, α=90°, β=90°, γ=90°, V=1.580 0(9) nm3, Z=8, M=231.54, Dc=2.236 Mg·m-3, μ=3.070 mm-1, R1=0.043 4, wR2=0.120 6, S=1.029. CCDC: 660629. 相似文献
996.
神木煤显微组分加氢热解特性的研究 总被引:2,自引:5,他引:2
在加压热天平上终温900℃,升温速率20℃/min,0.1MPa-3MPa的条件下考察了神木煤显微组分加氢热解的热失重行为、半焦元素分布、脱硫脱氮率及半焦的燃烧反应特性。结果表明:镜质组和丝质组的加氢热解失重行为相似,在378℃-718℃出现明显失重峰,但镜质组加氢热解失重峰温低,失重速率大,在实验压力范围(0.1MPa-3MPa)内,随热解压力升高,半焦中C含量增加,H、O含量下降,脱硫脱氮率增加,在压力为3MPa时,镜质组的脱硫率显著高于丝质组,镜质组加氢热解半焦的燃烧反应性高于丝质组半焦,随加氢热解压力的增加,半焦的燃烧反应性表现出先下降后增加的趋势。 相似文献
997.
The morphology of shear-oriented films of a thermotropic liquid crystalline polyester containing a triad ester mesogenic unit and a flexible spacer has been investigated in details. The formation conditions and process, the fine structures and the relaxation process of mat structure in the oriented films have been observed and discussed. 相似文献
998.
999.
Novel macrocyclic monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a were synthesized by the reaction of calix[4]arene dibromides 1-5 with the disodium salt of bis(2-selenylethyl)ether in the yields between 28% and 64%. Their structures were characterized by proton and carbon NMR spectra. X-Ray structure analysis of la further confirmed the cone conformation of compounds 1a-5a. An interesting host-guest complex of la with dichloromethane via CH/π and C1/π interactions was elucidated. Extraction experiments showed that these novel monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a had strong extraction ability towards mercury ion. The interaction of Hg^2+with the calix ligand has also been investigated by 1^H NMR titration. 相似文献
1000.