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51.
Low-pump-power,short-fiber copropagating dual-pumped (800 and 1050 nm) thulium-doped fiber amplifier
Gomes AS Carvalho MT Sundheimer ML Bastos-Filho CJ Martins-Filho JF Von der Weid JP Margulis W 《Optics letters》2003,28(5):334-336
Using optical frequency-domain reflectometry to reveal the gain distribution and allow us to optimize a thulium-doped fiber amplifier, we have demonstrated 18-dB gain by employing only 5 m of a 2000-parts-in-10(6)-Tm-doped fiber pumped with 145 mW of power at dual wavelengths of 800 and 1050 nm. The role of the 800-nm pump, which by itself does not permit population inversion, was clearly observed experimentally. 相似文献
52.
The Bootstrap Methodology in Statistics of Extremes—Choice of the Optimal Sample Fraction 总被引:2,自引:0,他引:2
The main objective of statistics of extremes is the prediction of rare events, and its primary problem has been the estimation of the tail index , usually performed on the basis of the largest k order statistics in the sample or on the excesses over a high level u. The question that has been often addressed in practical applications of extreme value theory is the choice of either k or u, and an adaptive estimation of . We shall be here mainly interested in the use of the bootstrap methodology to estimate adaptively, and although the methods provided may be applied, with adequate modifications, to the general domain of attraction of G, , we shall here illustrate the methods for heavy right tails, i.e. for > 0. Special relevance will be given to the use of an auxiliary statistic that is merely the difference of two estimators with the same functional form as the estimator under study, computed at two different levels. We shall also compare, through Monte Carlo simulation, these bootstrap methodologies with other data-driven choices of the optimal sample fraction available in the literature. 相似文献
53.
van Der Voort M Rella CW van Der Meer LF Akimov AV Dijkhuis JI 《Physical review letters》2000,84(6):1236-1239
We present results of the first vibrational photon-echo, transient-grating, and temperature dependent transient-bleaching experiments on a-Si:H. Using these techniques, and the infrared light of a free electron laser, the vibrational population decay and phase relaxation of the Si-H stretching mode were investigated. Careful analysis of the data indicates that the vibrational energy relaxes directly into Si-H bending modes and Si phonons, with a distribution of rates determined by the amorphous host. Conversely, the pure dephasing appears to be single exponential, and can be modeled by dephasing via two-phonon interactions. 相似文献
54.
José R. B. Gomes Emanuel A. Sousa Jorge M. Gonçalves Luís Gales Ana M. Damas Paula Gomes Siddharth Pandey William E. Acree Jr Maria D. M. C. Ribeiro da Silva 《Journal of Physical Organic Chemistry》2007,20(7):491-498
The gaseous standard molar enthalpies of formation of two 2‐R‐3‐methylquinoxaline‐1,4‐dioxides (R = benzoyl or tert‐butoxycarbonyl), at T = 298.15 K, were derived using the values for the enthalpies of formation of the compounds in the condensed phase, measured by static bomb combustion calorimetry, and for the enthalpies of sublimation, measured by Knudsen effusion, using a quartz crystal oscillator. The three dimensional structure of 2‐tert‐butoxycarbonyl‐3‐methylquinoxaline‐1,4‐dioxide has been obtained by X‐ray crystallography showing that the two N? O bond lengths in this compound are identical. The experimentally determined geometry in the crystal is similar to that obtained in the gas‐phase after computations performed at the B3LYP/6‐311 + G(2d,2p) level of theory. The experimental and computational results reported allow to extend the discussion about the influence of the molecular structure on the dissociation enthalpy of the N? O bonds for quinoxaline 1,4‐dioxide derivatives. As found previously, similar N? O bond lengths in quinoxaline‐1,4‐dioxide compounds are not linked with N? O bonds having the same strength. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
55.
Cristina M. Gomes M. Helena Ado Benilde J. V. Saramago Anabela C. Fernandes 《Journal of Polymer Science.Polymer Physics》1997,35(3):407-414
Cellular polymers constitute an important field of investigation due to their unique properties as shock absorbers and thermal or acoustic insulators. The knowledge of the wetting properties of these materials is important in applications where adhesion or weathering behavior are an issue. In this study, cellular polyurethane polymers were used to investigate the effect of the cellular structure on the wetting properties. The polymeric substrates were analyzed by scanning electron microscopy and the wetting properties were studied by goniometry. The contact angles of water and diiodomethane were measured as a function of time and the surface tension of the expanded polymers was evaluated by the geometric and harmonic mean methods. It was found that the wettability and the surface energy of the cellular polymers increase as the density decreases. © 1997 John Wiley & Sons, Inc. 相似文献
56.
M. Ivette Gomes 《Annals of the Institute of Statistical Mathematics》1984,36(1):71-85
Summary Let {X
n}n≧1 be a sequence of independent, identically distributed random variables. If the distribution function (d.f.) ofM
n=max (X
1,…,X
n), suitably normalized with attraction coefficients {αn}n≧1(αn>0) and {b
n}n≧1, converges to a non-degenerate d.f.G(x), asn→∞, it is of interest to study the rate of convergence to that limit law and if the convergence is slow, to find other d.f.'s
which better approximate the d.f. of(M
n−bn)/an thanG(x), for moderaten. We thus consider differences of the formF
n(anx+bn)−G(x), whereG(x) is a type I d.f. of largest values, i.e.,G(x)≡Λ(x)=exp (-exp(−x)), and show that for a broad class of d.f.'sF in the domain of attraction of Λ, there is a penultimate form of approximation which is a type II [Ф
α(x)=exp (−x−α), x>0] or a type III [Ψ
α(x)= exp (−(−x)α), x<0] d.f. of largest values, much closer toF
n(anx+bn) than the ultimate itself. 相似文献
57.
Henriques ES Floriano WB Reuter N Melo A Brown D Gomes JA Maigret B Nascimento MA Ramos MJ 《Journal of computer-aided molecular design》2001,15(4):309-322
We present the search for a new model of -factor XIIa, a blood coagulation enzyme, with an unknown experimental 3D-structure. We decided to build not one but three different models using different homologous proteins as well as different techniques and different modellers. Additional studies, including extensive molecular dynamics simulations on the solvated state, allowed us to draw several conclusions concerning homology modelling, in general, and -factor XIIa, in particular. 相似文献
58.
59.
60.
Pensado AS Costa Gomes MF Canongia Lopes JN Malfreyt P Pádua AA 《Physical chemistry chemical physics : PCCP》2011,13(30):13518-13526
Properties of the surface of ionic liquids, such as surface tension, ordering, and charge and density profiles, were studied using molecular simulation. Two types of modification in the molecular structure of imidazolium cations were studied: the length of the alkyl side chain and the presence of a polar hydroxyl group at the end of the side chain. Four ionic liquids were considered: 1-ethyl-3-methylimidazolium tetrafluoroborate, [C(2)C(1)im][BF(4)]; 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate, [C(2)OHC(1)im][BF(4)]; 1-octyl-3-methylimidazolium tetrafluoroborate, [C(8)C(1)im][BF(4)] and 1-(8-hydroxyoctyl)-3-methylimidazolium tetrafluoroborate, [C(8)OHC(1)im][BF(4)]. The surface tension was calculated using both mechanical and thermodynamic definitions, with consistent treatment of the long-range corrections. The simulations reproduce the available experimental values of surface tension with a maximum deviation of ±10%. This energetic characterization of the interface is completed by microscopic structural analysis of orientational ordering at the interface and density profiles along the direction normal to the interface. The presence of the hydroxyl group modifies the local structure at the interface, leading to a less organized liquid phase. The results allow us to relate the surface tension to the structural ordering at the liquid-vacuum interface. 相似文献