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981.
Xiu‐Ying Wang Long Xu Rui‐Bin Liu Shu‐Qin Liu Wen‐Bo Yang Prof. Dr. Jian‐Jun Zhang 《无机化学与普通化学杂志》2012,638(6):1006-1011
A rigid imidazolate/sulfonate functionalized ligand, 6‐(4‐sulfonatopheny)imidazo[4, 5‐f]isoindole‐5, 7‐dione (SPID) was designed and used for assembling reactions with Mn2+ and Cu2+ ions. Two 2D frameworks compounds, [Mn(H‐1SPID)2(DMAC)2] ( 1 ) and [Cu(H‐2SPID)(H2O)2] · 0.7DMAC · 0.3H2O ( 2 ) (DMAC = N,N‐dimethylacetamide) were obtained. Single crystal X‐ray analyses show that 1 has a 2D (4, 4)‐net based on 4‐connected Mn2+ nodes and μ2‐coordinated H‐1SPID spacers, whereas compound 2 has a 2D (6, 3)‐net built of 3‐connected Cu2+ nodes and μ3‐coordinated H‐2SPID spacers. Additionally, the thermal behavior of 1 and 2 is presented. 相似文献
982.
983.
We investigate the activation of living monocytic U937 cells induced by interleukin-6 (IL-6) at the single cell level. We employ home-built Raman tweezers to measure the Raman spectra of living U937 cells with and without IL-6 at the single cell level. Raman peaks of amide III, amide I, DNA backbone, as well as guanine and adenine in U937 cells, change at 1312, 1652, 1090, and 1576 cm ?1 , respectively, shortly after IL-6 is added in the medium. The change is a dynamic temporal process. In the activation process of U937 cells induced by IL-6, the protein signals recover in 20 min, while the nucleic acid signals continue to increase for 20 min. The results reveal that the biochemical cascades of activation in signal transduction induced by IL-6 can be investigated in situ at the single cell level. 相似文献
984.
The experimental one-, three-, and five-quasiparticle bands in ~(177)Lu are analyzed by the particle-number conserving (PNC) method for treating the cranked shell model with pairing interaction, in which the blocking effects are taken into account exactly. The experimental moments of inertia are reproduced very well by PNC calculations with us free parameter. 相似文献
985.
Yang Wu Qing Ma Xiangrong Song Yu Zheng Wen Ren Jinkun Zhang Liang Ouyang Fengbo Wu Gu He 《Journal of polymer science. Part A, Polymer chemistry》2012,50(21):4532-4537
A novel amphiphilic poly(ethylene glycol)‐block‐poly(γ‐cholesterol‐L ‐glutamate) (mPEG–PCHLG) diblock copolymer has been synthesized. The mPEG–PCHLG copolymer has good biocompatibility and low toxicity. The mPEG–PCHLG copolymers could aggregate into nanoparticles with PCHLG blocks as the hydrophobic core and PEG blocks as the hydrophilic shell through emulsion solvent evaporation method. The copolymers were characterized by nuclear magnetic resonance spectroscopy, mass spectrum, Fourier transform infrared spectroscopy, and gel permeation chromatography. The particle sizes, size distributions, and zeta potentials of nanoparticles can also be determined by dynamic light scattering and transmission electron microscopy. This work provides a new and facile approach to prepare amphiphilic block copolymer nanoparticles with controllable performances. This novel copolymer may have potential applications in drug delivery and bioimaging applications.© 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
986.
Dr. Qi Wei Jia‐Jia Wang Dr. Chao He Prof. Dr. Jian‐Wen Cheng Prof. Dr. Guo‐Yu Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(31):10759-10762
A new borate LiBa3(OH)[B9O16][B(OH)4], which combines the uniform porosity of open‐frameworks with the extraordinary NLO properties of borates, has been obtained under hydrothermal conditions by using mixed lithium and barium ions as templates. The framework displays an acs‐type net with large 21‐ring channels. The second harmonic generation (SHG) measurement shows that it is a type I phase‐matchable material with a strong SHG signal intensity about 3.1 times that of KDP (KH2PO4). UV/Vis–NIR diffuse reflectance analysis indicates that the compound has a wide transparency range with the short‐wavelength absorption edge below 200 nm. These characteristics reveal that the compound is a promising deep‐UV nonlinear optical material. 相似文献
987.
988.
This paper proposes a circular threshold quantum secret sharing (TQSS) scheme with polarized single photons. A polarized single photon sequence runs circularly among any t or more of n parties and any t or more of n parties can reconstruct the secret key when they collaborate. It shows that entanglement is not necessary for quantum secret sharing. Moreover, the theoretic efficiency is improved to approach 100% as the single photons carrying the secret key are deterministically forwarded among any t or more of n parties, and each photon can carry one bit of information without quantum storage. This protocol is feasible with current technology. 相似文献
989.
X. M. Wen L. V. Dao P. Hannaford S. Mokkapati H. H. Tan C. Jagadish 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(1):65-70
We investigate the electron dynamics of p-type modulation doped and undoped
InGaAs/GaAs quantum dots using up-conversion photoluminescence at low
temperature and room temperature. The rise time of the p-doped sample is
significantly shorter than that of the undoped at low temperature. With
increasing to room temperature the undoped sample exhibits a decreased rise
time whilst that of the doped sample does not change. A relaxation mechanism
of electron-hole scattering is proposed in which the doped quantum dots
exhibit an enhanced and temperature independent relaxation due to excess
built-in holes in the valence band of the quantum dots. In contrast, the
rise time of the undoped quantum dots decreases significantly at room
temperature due to the large availability of holes in the ground state of
the valence band. Furthermore, modulation p-doping results in a shorter
lifetime due to the presence of excess defects. 相似文献
990.
Performance of gain-switched all-solid-state quasi-continuous-wave tunable Ti:sapphire laser system
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We have made a gain-switched all-solid-state quasi-continuous-wave (QCW) tunable Ti:sapphire laser system, which is pumped by a 532 nm intracavity frequency-doubled Nd:YAG laser. Based on the theory of gain-switching and the study on the influencing factors of the output pulse width, an effective method for obtaining high power and narrow pulse width output is proposed. Through deliberately designing the pump source and the resonator of the Ti:sapphire laser, when the repetition rate is 6 kHz and the length of the cavity is 220 mm, at an incident pump power of 22 W, the tunable Ti:sapphire laser from 700 to 950nm can be achieved. It has a maximum average output power of 5.6W at 800nm and the pulse width of 13.2 ns, giving an optical conversion efficiency of 25.5% from the 532 mn pump laser to the Ti:sapphire laser. 相似文献