Gas phase A-band short time photodissociation dynamics of trans and gauche conformations of 1-iodopropane and comparison with the solution phase short time photodissociation dynamics

A-band resonance Raman spectra are reported for gas phase 1-iodopropane. The gas phase absorption spectrum and resonance Raman intensities were simulated using time-dependent wavepacket calculations and a simple model in order to extract the A-band short time photo-dissociation dynamics for the trans and gauche conformers of 1-iodopropane. The gas phase short time dynamics for trans and gauche are very similar to the results obtained from a reanalysis of corresponding solution phase spectra. This indicates that solvation has little effect on the A-band short time photodissociation dynamics. However, the electronic dephasing parameters for the gauche conformer increase significantly upon solvation while the trans conformer parameters are almost the same in the gas and solution phases. This suggests that the gauche conformer in the A-band excited electronic state undergoes stronger interaction with the solvent than the trans conformer to give rise to faster electronic dephasing upon solvation for the gauche conformer.     

中能重离子碰撞中同位旋相关核子-核子碰撞截面和同位旋相关平均场的探针

在最近几年我们通过使用同位旋相关的量子分子动力学模型（IQMD）系统的研究了同位旋相关的平均场和介质中核子－核子（N－N）碰撞截面对中能重离子碰撞（HIC）中碎裂和耗散的同位旋效应。我们发现原子核阻R和Qzz，中等质量碎片多重性Nimf和质子（中子）发射数Np(Nn）敏感的依赖于介质中N－N碰撞截面的同位旋效应，而弱的依赖于同位旋相关的平均场（对称势），这些物理量作为提取相对高能范围缺中子系统的同位旋相关介质中N－N碰撞截面的探针。我们也可以通过相对低能区到150MeV/u的前平衡核子发射中质比来提取关于对称势的知识和讨论它的同位旋依赖性。     

FREE VIBRATION ANALYSIS OF BAFFLED LIQUID-STORAGE TANKS BY THE STRUCTURAL-ACOUSTIC FINITE ELEMENT FORMULATION

In fluid-structure interaction systems, baffles as a dynamic damping device are being widely used to suppress the fluid sloshing motion. Meanwhile, natural and dynamic behaviors of such systems are significantly influenced by the baffle parameters, such as the baffle number, the installation location, the inner-hole diameter and the liquid fill height. This paper intends to numerically investigate the parametric eigen characteristics, by the coupled structural-acoustic finite element method (FEM), of baffled cylindrical liquid-storage tank. According to the symmetric two-field formulation, a test FEM program is developed, in which the reduced integration for avoiding the shear and membrane locking and the modified shear correction factor as well as degenerated 8- and 6-node shell elements and 3-D trilinear acoustic elements are used. Through the comparison with the available analytic solutions of no-baffled axisymmetric tank, the validity of the test program and theoretical work is verified. Next, with the verified test FEM program, various combinations of major baffle parameters are intensively examined, in order for the parametric baffle effects on the natural frequency of baffled tanks.     

A global multiplicity result for two-point boundary value problems of p-Laplacian systems

In this paper,we consider the existence,nonexistence and multiplicity of positive solutions for two-point boundary value problems of p-Laplacian systems which have a singular indefinite weight and real multiparameters.For proofs,we mainly make use of the upper and lower solution method and the fixed point index theorem.To obtain a global multiplicity result,we construct a weighted space to benefit richer topology of the solution space than C 0-space.     

THE δ^－－PROBLEM FOR HOLOMORPHIC （0,2）－FORMS ON PSEUDOCONVEX DOMAINS IN SEPARABLE HILBERT SPACES AND D.F.N. SPACES

This paper shows that the δ^--problem for holomorphic (0, 2)-forms on Hilbert spaces is solv-able on pseudoconvex open subsets. By using this result, the authors investigate the existence ofthe solution of the δ^--equation for holomorphic(0, 2)-forms on pseudoconvex domains in D.F.N.spaces.     

ChemInform Abstract: Vibrational Spectroscopy of the Hydrated Hydronium Cluster Ions H3O+·(H2O)n (n = 1, 2, 3).

Using a new spectroscopic method, the gas phase IR spectra of the title cluster ions, produced in a high pressure corona discharge source, are observed between 3550 and 3800 cm^-1.     

ChemInform Abstract: Vibrational Spectroscopy of the Ammoniated Ammonium Ions NH+ 4(NH3)n ( n = 1-10)

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

ChemInform Abstract: C61 Clusters: AM1 Computations.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

ChemInform Abstract: Si60 Clusters: AM1 Computed Ih/C2v Relative Populations

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

ChemInform Abstract: Quantitative Photoabsorption and Fluorescence Study of HCl in Vacuum Ultraviolet.

The oscillator strengths for the discrete structures are determined from the measured absorption cross sections; the values are comparable to theoretical results.