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61.
Adsorption Mechanisms of Mesoporous Adsorbents in Solutions 总被引:1,自引:0,他引:1
WUZhi-jian LEEKangtaek 《高等学校化学研究》2004,20(2):185-187
Sieve effect, compiexation, ionic exchange, electrostatic interaction, hydrogen bonding, hydrophobic interaction, and molecular recognition based on molecular imprinting are comprehensively discussed. 相似文献
62.
用不同分子量的聚苯乙烯在乳液体系中进行过氧化氢基化反应,然后测定这些产品的特性粘数,HPO值(每1,000个苯乙烯结构单元中所合的过氧化氢基平均数目)等。在过氧化氢基聚苯乙烯的红外光谱里,可以在3,200—3,600厘米~(-1)吸收区里观察到过氧化氢基的吸收带,其吸收强度随着HPO值的增大而加强。最后用这些大分子过氧化物引发甲基丙烯酸甲酯及苯乙烯聚合,得到接枝聚合物。经过分离提纯后,用下列的方法: (1)浊度滴定; (2)热机械性能的测试; (3)水解后测定交换量; (4)红外吸收光谱;证明它们是接枝共聚物。 相似文献
63.
光纤近红外光谱法在中草药分析中的应用——甘草中甘草酸含量的测定 总被引:7,自引:0,他引:7
提出光纤近红外光谱技术在线和快速检测中药甘草中有效成分甘草酸含量的方法。对含甘草酸浓度在0.94%~3.06%内的甘草,根据其在10 000~4 000 cm-1的近红外吸收光谱, 采用偏最小二乘算法(PLS)和主成分回归算法(PCR)建立了校正模型,比较了光谱不同前处理方法对校正结果的影响,当采用数据标准化并求一阶导前处理时可较好提取中药复杂体系的信息。当采用PLS算法时,校正集相关系数为0.958,校正集标准偏差(SEC)为0.179,验证集标准偏差(SEP)为0.197,PLS算法优于PCR算法。该方法快速和简便,适合于中药有效成分在线监控。 相似文献
64.
PREDICTION OF NON-CAVITATING UNDERWATER PROPELLER NOISE 总被引:2,自引:0,他引:2
Non-cavitation noise of underwater propeller is numerically investigated. The main purpose is to analyze non-cavitation noise in various operating conditions with different configurations. The noise is predicted using time-domain acoustic analogy and boundary element method. The flow field is analyzed with potential-based panel method, and then the time-dependent pressure data are used as the input for Ffowcs Williams-Hawkings formulation to predict the farfield acoustics. Boundary integral equation method is also considered to investigate the effect of ducted propeller. Sound deflection and scattering effect on the duct is considered with the BEM. The governing equations are based on the assumption that all acoustic pressure is linear. A scattering approach is applied in which the acoustic pressure field is split into the known incident component and the unknown scattered component. Noise prediction results are presented for single propeller and ducted propeller in non-uniform flow conditions similar to real situation. The investigation reveals that the effect of a duct on the acoustic performance propeller is small in the far field under non-cavitating situations since the noise directivities of single and ducted propellers are almost the same. Only the high order BPFs are influenced by the existence of the duct. 相似文献
65.
M.H. YEOW.K. LEE 《Journal of sound and vibration》2002,257(4):653-665
An investigation into non-linear asymmetric vibrations of a clamped circular plate under a harmonic excitation is made. We re-examined a primary resonance studied by Sridhar, Mook and Nayfeh, in which the frequency of excitation is near the natural frequency of an asymmetric mode of the plate. We corrected their solvability conditions and found that in the absence of internal resonance, the steady state response can have not only the form of standing wave but also the form of travelling wave, which is a remarkable contrast to their conclusion. 相似文献
66.
67.
We present and demonstrate a polarization-insensitive mechanically induced long-period fiber grating (MLPG) for EDFA gain flattening. By forming a 90° fiber rotator in the middle of the MLPG the PDL of the MLPG was substantially reduced. The PDL-compensated MLPG was able to flatten the ASE spectrum of an EDFA successfully without deterioration of the polarization characteristics. 相似文献
68.
Pulsatile flows in the vicinity of mechanical ring-type constrictions in pipes were studied for transitional turbulent flow with a Reynolds number (Re) of the order of 104. The Womersley number (Nw) is in the range 30–50, with a corresponding Strouhal number (St) range of 0·0143–0·0398. The pulsatile flows considered are a pure sinusoidal flow, a physiological flow and an experimental pulsatile flow profile for mechanical aortic valve flow simulations. Transitional laminar and turbulent flow characteristics in an alternating manner within the pulsatile flow fields were studied numerically. It was observed that fluid accelerations tend to suppress the development of flow disturbances. All the instantaneous maximum values of turbulent kinetic energy, turbulent viscosity and turbulent shear stress are smaller during the acceleration phase than during the deceleration period. Various parametric equations have been formulated through numerical experimentation to better describe the relationships between the instantaneous flow rate (Q), the pressure loss (ΔP), the maximum velocity (Vmax), the maximum vorticity (ζmax), the maximum wall vorticity (ζw,max), the maximum shear stress (τmax) and the maximum wall shear stress (τw,max) for turbulent pulsatile flow in the vicinity of constrictions in the vascular tube. An elliptic relationship has been found to exist between the instantaneous flow rate and the instantaneous pressure gradient. Other linear and quadratic relations between various flow parameters were also obtained. 相似文献
69.
T. S. LEE LIAO WEI H. T. LOW 《International Journal of Computational Fluid Dynamics》2013,27(3):197-208
A numerical method has been developed to solve the steady and unsteady incompressible Navier-Stokes equations in a two-dimensional, curvilinear coordinate system. The solution procedure is based on the method of artificial compressibility and uses a third-order flux-difference splitting upwind differencing scheme for convective terms and second-order center difference for viscous terms. A time-accurate scheme for unsteady incompressible flows is achieved by using an implicit real time discretization and a dual-time approach, which introduces pseudo-unsteady terms into both the mass conservation equation and momentum equations. An efficient fully implicit algorithm LU-SGS, which was originally derived for the compressible Eulur and Navier-Stokes equations by Jameson and Toon [1], is developed for the pseudo-compressibility formulation of the two dimensional incompressible Navier-Stokes equations for both steady and unsteady flows. A variety of computed results are presented to validate the present scheme. Numerical solutions for steady flow in a square lid-driven cavity and over a backward facing step and for unsteady flow in a square driven cavity with an oscillating lid and in a circular tube with a smooth expansion are respectively presented and compared with experimental data or other numerical results. 相似文献
70.
WANG Yan-hua LI Li CHEN Chia-hung CHENG Shuenn-ren LEE Mu-sheng YU Pu-ping CHANG-CHIEN Guo-ping 《高等学校化学研究》2012,28(2):195-199
Sulfonamide residue in honey existed in a form bonded to sugar via the N-glycosidic bond.It would result in the possible underestimation of concentration of sulfonamide if it is not decomposed by chemi... 相似文献