A New Rearrangement Reaction of 2-Phenyl Substituted Benzothiazepine with Ethoxycarbonyl Carbene─Mechanism of the Reaction and Structure of the Product

Intheprevi0usaFticlesl-2wehavereportedthatthereacti0n0fbenz0diazepinewithethoxycarbonylcarbenemayobtainnormal[2 l]cycIoadditi0npr0ductsregardlessthe2-substitUentismethyl0rphenyl.Howeverunderthesamec0nditi0nsthereaction0fbenzothiazepinewithethoxycarbonylcarbeneunderwentrearrangementreacti0n.Forexample,whenthe2-substituentismethyl,thereacti0nofbenzothiazepinewithethoxycarbonylcarbenegivearing-openingproductIIatroomorhightemperature'.Whenthe2-substituentisphenyl,weunexpectedlyfoundan0thernewrea…     

可瓷化硅橡胶材料的研究

研究了一种可瓷化硅橡胶,其特点是在火灾发生时可在金属线外形成瓷化绝缘保护层,600℃的成瓷温度大幅度低于目前文献报道的成瓷温度。实验得到的优化瓷化填料配方为:相对于100份混炼胶,氧化铝10份、硅灰石15份、结构控制剂9份、碳酸锂3份。在此配方条件下,未瓷化硅橡胶的断裂伸长率316%、拉伸强度10.79MPa、体积电阻率134×10~(12)Ω·cm,其在600℃、800℃瓷化后的抗压强度分别为3.47MPa、10.13MPa、体积电阻率≥28×10~(12)Ω·cm,满足电缆用硅橡胶的力学和绝缘要求。经热重分析及SEM分析可知加入瓷化填料后,试样烧蚀重量减少了39.4%,烧蚀残留率大大提高,且成瓷试样结构致密。     

A general solution for static piezothermoelastic problems of crystal class 6mm solids

In this paper, a general solution for three-dimensional static piezothermoelastic problems of crystal class 6mm solids is presented. The general solution involves four piezoelastic potential functions and a piezothermoelastic potential function, of which four piezoelastic potential functions are governed by weighted harmonic differential equations. Compared with the general solution given by Ashida et al., in which seven potential functions are introduced, the general solution proposed in the present paper is more rigorously derived. Moreover, it has a simple form and is convenient for application. As an illustrative example, the problem of a pyroelectric half-space subjected to axisymmetric heating is studied. Numerical results of displacements stresses, electric potential and electric displacements are obtained for a cadmium selenide half-space. Thermally induced displacements and stress distribution are compared with those obtained for the same material without piezoelectric and pyroelectric effects. Project supported by the National Natural Science Foundation of China (19872060).     

基于核心矩阵的线性规划块转轴算法研究

本文在线性规划问题核心矩阵概念的基础之上,对单纯形算法的块转轴规则进行了深入的研究.在线性规划的Kuhn-Tucker条件基础之上,证明了单纯性算法块转轴规则的理论可行性,并在文章中给出了块转轴规则的理论算法,为转轴规则的研究提出了一个新的方向.     

对格上Erceg式p．q．（p．）度量的注记

本文的主要结果是大幅度地简化了Ｅｒｃｅｇ引入的不分明度量的无点化定义，建立了相应的点式刻画．     

国有企业人力资本与所有权安排的实证分析

本首先对中国国有企业人力资本与所有权安排制度作一简要考察，然后对中国国有企业人力资本与所有权安排问题进行实证分析，在此基础上进一步对国有企业人力资本与所有权安排的制度进行分析。     

区间数可能度的二维定义

利用二维空间的面积,提出了一个新的区间数可能度的定义,并给出了简单实用的计算公式和证明了相关的性质,最后,通过实例说明了该定义的实用性.     

基于高聚物光诱导激子漂白的无腔光学双稳态

基于已建立的高聚物光诱导激子漂白动力学理论，模拟计算了一类基态非简并高聚物在光激发和弛豫过程中的瞬态无腔光学双稳态．结果表明，基于高聚物的超快激发和弛豫，可获得瞬态饱和吸收型和增强吸收型无腔光学双稳态，其开关时间均在ps和fs量级．随着入射探测光脉冲相对入射泵浦光脉冲延迟时间的增加，无腔光学双稳态可由饱和吸收型向增强吸收型转变，转变的快慢与高聚物光诱导漂白的弛豫的快慢成正比 关键词：     

分数次积分在加权Herz型Hardy空间的有界性

讨论了具有齐性核的分数次积分算子TΩ,μ在加权Herz型Hardy空间的有界性,证明TΩ,μ是从HKq1α,p1(w1,w2q1)到Kq2 α,p2(w1,w2 q2)或HKq1α,p1(1,w2q2)到HKq2α,p2(1,w2q2)有界的.     

具有θ型Calderón-Zygmund核的多线性奇异积分算子的端点估计

研究了一类具有θ型Calderon-Zygmund核的多线性奇异积分算子的有界性,得到它们是从L1(Rn)到弱L1(Rn)有界的．