新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质

用L-氨基酸和5-[邻-(2-溴乙氧基)苯基]-10,15,20-三苯基卟啉为原料合成了三种新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物,通过元素分析、红外光谱、紫外光谱、化学分析和质谱等对其进行了结构表征。测试并研究了它们在4 000～400 cm-1范围内的傅里叶变换红外光谱,对主要谱带进行了经验归属。     

Nonchaotic random behaviour in the second order autonomous system

Evidence is presented for the nonchaotic random behaviour in a second-order autonomous deterministic system. This behaviour is different from chaos and strange nonchaotic attractor. The nonchaotic random behaviour is very sensitive to the initial conditions. Slight difference of the initial conditions will generate wholly different phase trajectories. This random behaviour has a transient random nature and is very similar to the coin-throwing case in the classical theory of probability. The existence of the nonchaotic random behaviour not only can be derived from the theoretical analysis, but also is proved by the results of the simulated experiments in this paper.     

Exchange coupled magnetic nanocomposites of Sm(Co1−xFex)5 / Fe3O4 with core/shell structure

Magnetic nanocomposites of Sm(Co_1−xFe_x)₅/Fe₃O₄ (x≈0.1) with the core/shell type structure were successfully fabricated using a two-step polyol process, where as-prepared SmCo_5(1−x) nanoparticles were used as seeds for the ferrite coating. The core/shell composites are quite stable in air and show a typical hysteric behavior of single component, yielding an enhanced coercivity of 2.2 kOe with a saturated magnetization of 130 emu/g at 5 T. The magnetization data clearly reveal the presence of effective exchange coupling between the hard-magnetic Sm(Co_1−xFe_x)₅ core and soft-magnetic Fe₃O₄ shell, suggestive of a single-phase structure rather than a distinctive two-phase one.     

寄生传输线对PFN-Marx输出波形的影响

紧凑型PFN-Marx脉冲发生器中,级与级之间存在着较大的寄生电容,该电容和PFN节电感构成了寄生传输线。对两种排布方式下的寄生传输线的放电过程进行了简单分析,重点开展了双列排布方式下全电路仿真模拟,对负载类型、寄生电容、负载电感等参数对输出波形的影响进行了计算,得到了二极管负载会在波形前沿上造成下降、寄生电容大小决定振荡频率、负载电感放大振荡幅值等结论。开展的PFN-Marx实验研究也进一步验证了上述分析结果。根据分析,提出了一种有效抑制输出波形振荡的方法,从电路上进行了仿真验证,进一步实验证实了该方法的有效性。     

面向低强度无线网络信号接收谱参数估计研究

针对以北斗卫星导航信号为代表的亚纳秒级的低强度无线网络信号在定位中难以获取精确时间估计及角度估计,且易受环境噪声影响,使其定位精度不高等难题,本文提出了基于亚纳秒级的低强度无线网络信号接收谱参数估计方法。首先通过抽样方式,将发射信号抽样为多维独立子信号并独立建模,通过构造噪声空间与子信号空间在对应列向量正交化的基础上精确获取TOA估计;随后利用复数域映射,在获取TOA估计基础上采取比对方式精确地获取DOA估计。最后对本文参数估计方法进行了精度分析。测试数据显示：与 PM算法、ESPRIT算法相比,本文技术在TOA及DOA估计上更为精确;同时在信号强度低且背景噪声干扰严重的情况下,本文方法仍可有效的维持参数估计精度。     

PGNAA系统中D-T中子管的慢化装置优化设计

为了提高PGNAA系统中D-T中子管的中子慢化效率,获得更高的热中子产额,借助蒙特卡罗模拟,确定了以铅为中子反射层、5个聚乙烯层和铅层相互交替作为中子慢化层、碳化硼含量为3%的含硼聚乙烯作为中子吸收层以及铅作为γ屏蔽层的中子慢化装置模型。针对中子产额为3×107 n/s 的D-T中子管,该慢化装置输出面低于5 eV中子通量可达5.28×106 n/s,占总中子通量的30.8%,有效提高了中子慢化效率。经过验证模拟结果能够满足实验要求。To improve the moderating efficiency of D-T Neutron Generator in PGNAA system, and get higher thermal neutron yield, the Monte Carlo code MCNP was used to optimize the moderation setup. The lead was selected as neutron reflector and gamma absorber, 5 polyethylene layers and 4 lead layers constituted the neutron moderator and 3% boron-doping polyethylene was selected as neutron absorber. For the yield of 3107 n/s D-T Neutron Generator, this moderation setup can provide a yield of lower than 5 eV of 5.28106 n/s, accounting for 30.8% of total neutron yield, dramatically improves the moderating efficiency. It is proved that the simulation results can satisfy the requirement of PGNAA system by preliminary experimental verification.     

Influence of the weakly interacting light U boson on the properties of massive protoneutron stars

Considering the octet baryons in relativistic mean field theory and selecting entropy per baryon S=l,we calculate and discuss the influence of U bosons on the equation of state,mass-radius,moment of inertia and gravitational redshift of massive protoneutron stars(PNSs).The effective coupling constant gu of U bosons and nucleons is selected from 0 to 70 GeV~(-2).The results indicate that U bosons will stiffen the equation of state(EOS).The influence of U bosons on the pressure is more obvious at low density than high density,while the influence of U bosons on the energy density is more obvious at high density than low density.The U bosons play a significant role in increasing the maximum mass and radius of PNS.When the value of gu changes from 0 to 70 GeV~(-2),the maximum mass of a massive PNS increases from 2.11M_⊙ to 2.58M_⊙,and the radius of a PNS corresponding to PSR J0348+0432 increases from 13.71 km to 24.35 km.The U bosons will increase the moment of inertia and decrease the gravitational redshift of a PNS.For the PNS of the massive PSR J0348+0432,the radius and moment of inertia vary directly with gu,and the gravitational redshift varies approximately inversely with gu.     

Spin-Dependent Transport and Densities of States in Non-collinear Magnetic Barriers

The spin-dependent transport properties in the non-collinear pattern of series of δ-magnetic barriers are studied by using scattering theory and Green＇s function methods. The Green＇s function is obtained by using distorted wave approach and the scattering matrix is related by Fisher-Lee relationship. In addition to reproducing the results of Papp＇s and Xu＇s in parallel and antiparallel configurations, we also obtain further results, where arbitrary orientations of the magnetic barriers and arbitrary number of barriers are included. The main finding of our results is that the signs of polarizations can be switched around some ＂geometric unpolarized windows＂. The well-known antiparallel configuration has no such characteristics. Furthermore, we discuss spin-related partial densities of states in both polarized and unpolarized structures.     

各向异性浮力紊流的显式代数应力模型及其验证

在Wallin & Johansson的显式代数雷诺应力模型(EARSM)基础上,引入浮力的紊动效应,使该模型能够反映浮力对紊流运动的影响.利用同位网格上的SIMPLEC算法,模拟了T-型连接管内的温度混合流动.与实验资料和DNS计算结果比较表明,提出的模型能够反映各向异性的浮力紊流特征,而且模型在计算进程中显示出良好的数值收敛性能,与涡粘性两方程模型的计算花费相当.