Fast preparation of hydroxyapatite/superhydrophilic vertically aligned multiwalled carbon nanotube composites for bioactive application

A method for the electrodeposition of hydroxyapatite films on superhydrophilic vertically aligned multiwalled carbon nanotubes is presented. The formation of a thin homogeneous film with high crystallinity was observed without any thermal treatment and with bioactivity properties that accelerate the in vitro biomineralization process and osteoblast adhesion.     

Identification of archaeal proteins that affect the exosome function in vitro

Background  

The archaeal exosome is formed by a hexameric RNase PH ring and three RNA binding subunits and has been shown to bind and degrade RNA in vitro. Despite extensive studies on the eukaryotic exosome and on the proteins interacting with this complex, little information is yet available on the identification and function of archaeal exosome regulatory factors.     

Preparation and Characterization of Graphite‐Epoxy Composite Modified with Zinc Hexacyanoferrate and Their Electrochemical Behaviour in Presence of Substituted Anilines

The growth of zinc hexacyanoferrate (ZnHCF) hybrid film on the surface of graphite‐epoxy composite (GEC) electrodes was demonstrated by cyclic voltammetry. Surface morphology of the hybrid film was investigated by using scanning electron microscopy. The effect of the type of monovalent cations on the redox behaviour of hybrid film was also studied. This effect indicated that the radius of the hydrated cation mainly determines the ion permeability of the film.     

A theoretical study of dihydrogen bonds in small protonated rings: Aziridine and azetidine cations

B3LYP/6-311++G(d,p) calculations were used to predict some molecular properties of the C₂H₆N⁺?BeH₂, C₂H₆N⁺?MgH₂, C₃H₈N⁺?BeH₂ and C₃H₈N⁺?MgH₂ dihydrogen-bonded complexes. In these systems, it was demonstrated that the C₂H₆N⁺ and C₃H₈N⁺ protonated rings are potential candidates to bind with protonic hydrogens derived from alkaline earth metal compounds, BeH₂ and MgH₂. In terms of structural parameters and quantification of the dihydrogen bond energies, we should mention that the C₂H₆N⁺ three-membered ring provides the formation of stronger bound systems, which are 4.0 kJ mol^?1 more stables than C₃H₈N⁺ four-membered ones. As complement, the analysis of the infrared spectrum indicated that red-shifts and blue-shifts are occurring in the N–H bonds of both C₂H₆N⁺ and C₃H₈N⁺ cationic rings. However, these two vibrational shifts were also verified on BeH₂ and MgH₂, what lead us to affirm that cationic compounds derived from small nitrogen rings and earth alkaline molecules are able to form unusual dihydrogen-bonded complexes by means of distinct spectroscopic phenomena, the red-shits and blue-shifts.     

Thermodynamics of a quasi-two-dimensional electron gas: Effects of magnetic fields, temperature and finite width

The effects of nonzero temperature, finite thickness and magnetic fields on an electron gas confined in a quasi-two-dimensional (Q2DEG) region are studied. Finite values of the thickness allow the existence of energy bands and give new characteristics to the system. Here we study some thermodynamic and transport properties to get a better understanding of these effects. For electronic densities of the order of 10¹² electrons per cm², and temperatures lower than 4 K, it is found that the chemical potential, free energy, magnetization, magnetic susceptibility and the inverse of Hall conductivity are independent of the thickness up to it reaches a threshold value. Systems with thicknesses a little above of the critical value lose the two-dimensional character, but they do not have the properties of a three-dimensional electron gas.     

Conductance peaks in open quantum dots

We present a simple measure of the conductance fluctuations in open ballistic chaotic quantum dots, extending the number of maxima method originally proposed for the statistical analysis of compound nuclear reactions. The average number of extreme points (maxima and minima) in the dimensionless conductance T as a function of an arbitrary external parameter Z is directly related to the autocorrelation function of T(Z). The parameter Z can be associated with an applied gate voltage causing shape deformation in quantum dot, an external magnetic field, the Fermi energy, etc. The average density of maxima is found to be <ρ(Z)>=α(Z)/Z(c), where α(Z) is a universal constant and Z(c) is the conductance autocorrelation length, which is system specific. The analysis of <ρ(Z)> does not require large statistic samples, providing a quite amenable way to access information about parametric correlations, such as Z(c).     

Kneading Theory: A Functorial Approach

We study the homology theory of ? - modal maps of the interval. We give another proof of the Milnor and Thurston results about zeta-functions and we give a functorial approach to kneading theory. Our results give explicit methods for computing the sequences of lap numbers ? (f ^k ) and the sequences of numbers of periodic points in an arbitrary interval [x,y]. Received: 25 February 1998 / Accepted: 15 January 1999     

Study of zinc hexacyanoferrate—modified platinum electrodes using electrochemical quartz crystal microbalance

In this work, the electrochemical quartz crystal microbalance has been employed to monitor directly the in situ growth of the zinc hexacyanoferrate film during the electrodeposition. Mass changes of the platinum|crystal working electrode were correlated with cyclic voltammetry data. Effects of the sorption of counter-cations (K⁺, Na⁺, and NH₄⁺ {\hbox{NH}}_4^{+} and anions (Cl⁻ and SO₄^{2 -} {\hbox{SO}}_4^{2 - } ) during redox reactions were studied. The electrocatalytic oxidation properties of procaine by the zinc hexacyanoferrate films were performed.