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911.
Gel polymer electrolyte (GPE) films comprising of poly(vinylidenefluoride), propylene carbonate, ethylene carbonate and zinc trifluoromethane sulfonate are prepared and characterized. The composition of GPE is optimized to contain minimum liquid components with a maximum specific conductivity of 3.94×10−3 S cm−1 at (25±1) °C. A detailed investigation on the properties such as ionic conductivity, transport number, electrochemical stability window, reversibility of Zn/Zn2+ couple and Zn/gel electrolyte interfacial stability have been carried out. The ionic conductivity follows a VTF behaviour with an activation energy of about 0.0014 eV. Cationic transport number varies from 0.51 at 25 °C to 0.18 at 70 °C. Several cells have been assembled with GPE as the electrolyte, zinc as the anode, γ-MnO2 as the cathode and their charge–discharge behaviour followed. Capacity values of 105, 82, 64 and 37 mAh/g of MnO2 have been achieved at 10, 50, 100 and 200 μA/cm2 discharge current densities, respectively. The discharge capacity values are almost constant for about 55 cycles for all values of current densities. Cyclic voltammetric study of MnO2 electrode in Zn/GPE/MnO2 cell clearly shows intercalation/deintercalation of Zn2+. 相似文献
912.
In a Young–Michelson tandem interferometer a Michelson interferometer is illuminated through a pair of Young slits. The pattern produced by this set-up is analyzed theoretically. The consequences of small misalignments and uncompensated arms in the Michelson interferometer are studied. The effects of the spatial and temporal partial coherence of the source are also explored. Experimental results using a laser source are shown to be in good agreement with the predicted theoretical calculations. 相似文献
913.
A simple and effective technique for calculating the transient signals in three-level spin systems irradiated at one and two
frequencies is described. All possible signals are presented and discussed. The application of the two-frequency excitation
technique for the investigation of the inhomogeneity of the crystalline lattice is suggested. 相似文献
914.
N. Segovia M. A. Armienta C. Valdes M. Mena J. L. Seidel M. Monnin P. Pea M. B. E. Lopez A. V. Reyes 《Radiation measurements》2003,36(1-6):379-383
Soil radon has been monitored at two fixed stations in the northern flank of Popocatepetl Volcano, a high risk volcano located 60 km SE from Mexico City. Water samples from three springs were also studied for radon as well as major and trace elements. Radon in the soil was recorded using track detectors. Radon in the water samples was evaluated using the liquid scintillation method and an Alphaguard. The major elements were determined through conventional chemical methods and trace elements using an ICP-MS equipment. Soil radon levels were low, indicating a moderate diffuse degassing through the flanks of the volcano. Groundwater radon had almost no relation with the eruptive stages. Water chemistry was stable in the reported time (2000–2002). 相似文献
915.
In search of a noncontact underwater acoustic source 总被引:7,自引:0,他引:7
S. V. Egerev 《Acoustical Physics》2003,49(1):51-61
The history of studies of the photoacoustic effect in liquids and its applications to the development of a “virtual” source of underwater acoustic signals is briefly reviewed. The problem of the efficiency of the photoacoustic conversion is considered. The modes of laser generation of sound, i.e., the thermooptical, nonlinear surface, and nonlinear bulk modes of operation, are discussed taking into account the real features of the marine environment, the most important of them being the surface waves. A review of the publications concerned with the problem of a moving photoacoustic source is presented. Advances in the photoacoustic underwater remote sensing technology are described. 相似文献
916.
I. Longo D. Cros N. Tosoratti 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(2):273-277
We present a numerical and experimental characterization of high-Q whispering gallery resonant modes excited in a fused quartz spherical shell operated in the 18-26.5 GHz band; easy coupling
and selection of modes is a most advantageous feature of the proposed structure with respect to ordinary bulk resonators.
The numerical results, based on a finite element algorithm, well match experimental data, which also show the capability of
our device to perform gaseous spectroscopy measurements.
Received 25 October 2002 Published online 4 February 2003 相似文献
917.
Crystal Structure of the Zinc Amide Zn[N(SiMe3)2]2 X‐ray quality crystals of Zn[N(SiMe3)2]2 (monoclinic, P21/c) are obtained by sublimation of the zinc amide Zn[N(SiMe3)2]2 at —30 °C in vacuo (300 torr). According to the result of the X‐ray structural analysis, Zn[N(SiMe3)2]2 contains an almost linear N‐Zn‐N unit with two short N‐Zn bonds. 相似文献
918.
919.
920.
In the paper the asymptotics for Dirichlet polynomials associated to certain cusp forms are obtained.
Partially supported by Lithuanian Foundation of Studies and Science 相似文献