全文获取类型
收费全文 | 715292篇 |
免费 | 8555篇 |
国内免费 | 2997篇 |
专业分类
化学 | 387142篇 |
晶体学 | 11136篇 |
力学 | 31717篇 |
综合类 | 74篇 |
数学 | 84491篇 |
物理学 | 212284篇 |
出版年
2020年 | 5788篇 |
2019年 | 6275篇 |
2018年 | 8121篇 |
2017年 | 8228篇 |
2016年 | 12222篇 |
2015年 | 7735篇 |
2014年 | 11929篇 |
2013年 | 31152篇 |
2012年 | 23230篇 |
2011年 | 28297篇 |
2010年 | 20193篇 |
2009年 | 19838篇 |
2008年 | 25833篇 |
2007年 | 25987篇 |
2006年 | 24316篇 |
2005年 | 21935篇 |
2004年 | 19979篇 |
2003年 | 17786篇 |
2002年 | 17645篇 |
2001年 | 19975篇 |
2000年 | 15354篇 |
1999年 | 12036篇 |
1998年 | 10119篇 |
1997年 | 9974篇 |
1996年 | 9740篇 |
1995年 | 8738篇 |
1994年 | 8555篇 |
1993年 | 8244篇 |
1992年 | 9332篇 |
1991年 | 9323篇 |
1990年 | 8941篇 |
1989年 | 8912篇 |
1988年 | 8669篇 |
1987年 | 8741篇 |
1986年 | 8296篇 |
1985年 | 11033篇 |
1984年 | 11198篇 |
1983年 | 9286篇 |
1982年 | 9950篇 |
1981年 | 9380篇 |
1980年 | 9290篇 |
1979年 | 9715篇 |
1978年 | 10558篇 |
1977年 | 10278篇 |
1976年 | 9972篇 |
1975年 | 9308篇 |
1974年 | 9268篇 |
1973年 | 9528篇 |
1972年 | 6797篇 |
1967年 | 5798篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
971.
G. Hinze R. Böhmer G. Diezemann H. Sillescu 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,131(2):218-223
Four-time stimulated echo experiments have been used to monitor the temporal evolution of the reorientation rates of deuterated molecules or colloidal suspensions. We present extended phase cycles for this seven-pulse experiment. In order to test its performance three vastly different materials are chosen. These include a crystal in which the molecules carry out well-defined 180° flips and a supercooled liquid characterized by a distribution of jump angles centered around 10°. As an example for rotational diffusion, data on a concentrated suspension of polystyrene spheres in a viscous medium are presented. 相似文献
972.
E. Hatta H. Hosoi H. Akiyama T. Ishii K. Mukasa 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(3):347-349
We have observed a remarkable two-armed spiral in the collapse process of a floating monolayer at the air-water interface
by phase contrast microscopy. This demonstrates that the floating monolayer as a form of soft condensed matter reorganizes
itself due to a certain kind of macroscopic or collective behavior of molecules as it collapses. This pattern formation is
caused by the breakdown of a critical dynamical balance between the deformation of solid domain and the applied surface pressure.
The fragility as well as the flexibility of the floating monolayer can be associated with the observed pattern growth. There
are also observed interesting, periodically arranged collections of molecules in numerous collapsed regions.
Received: 8 July 1997 / Accepted: 4 November 1997 相似文献
973.
An assignment of the near-infrared bands in the 600–800 nm spectral region observed in magnetic circular dichroism (MCD)
spectra of high-spin ferrous haemoproteins is presented. The assignment is based on a relative energy level scheme for iron
d-electrons, a comparison of predicted and measured temperature dependences of MCD intensity, a sign of MCD bands and a group
theoretical analysis of allowed transitions. The proposed assignment is consistent with the ∼15-nm red shift of the ∼760 nm
band on breakage of the Fe-His bond in deoxy-myoglobin at low pH, with low-temperature photolysis experiments available for
CO complexes of several haemoproteins. In accordance with the observations, the intensity of the MCD bands for proteins with
a sulphur anion of cysteine as proximal haemligand (cytochrome P450 and chloroperoxidase) is predicted to be diminished by
at least one order of magnitude compared to that for proteins with an imidazole of a histidine as a protein-derived haemligand
(i.e. myoglobin, haemoglobin and horseradish peroxidase).
Received: 4 February 1997 / Accepted: 1 May 1997 相似文献
974.
Summary. We present a simple proof, based on modified logarithmic Sobolev inequalities, of Talagrand’s concentration inequality for
the exponential distribution. We actually observe that every measure satisfying a Poincaré inequality shares the same concentration
phenomenon. We also discuss exponential integrability under Poincaré inequalities and its consequence to sharp diameter upper
bounds on spectral gaps.
Received: 10 June 1996 / In revised form: 9 August 1996 相似文献
975.
Magnetic Properties of the Cobaltates Na6CoS4, Na6CoSe4, and K6CoS4 The alkali metal cobalt chalcogenides Na6CoS4, Na6CoSe4, and K6CoS4 crystallize in the space group P63mc with Z = 4. The structure is characterized by isolated [CoX4]-tetrahedra. The magnetic susceptibilities show Curie-Weiss behaviour. The deviations at low temperatures are caused by antiferromagnetic interactions. The magnetic moments are discussed with regard to ligand-field parameters. 相似文献
976.
Benjamin S. Hsiao Rong-Ming Ho Stephen Z. D. Cheng 《Journal of Polymer Science.Polymer Physics》1995,33(17):2439-2447
Unique crystallization and melting behavior in poly(aryl ether ketone ketone) containing alternated terephthalic and isophthalic moieties were studied by time-resolved synchrotron x-ray methods. Recently, this material has been shown to exhibit three polymorphs (forms I, II, and III). In this work, we further investigated their distinctive thermal properties and found that form I is the dominating and the most thermally stable phase while form II is favored by fast nucleation conditions and is the least stable phase. On the other hand, form III represents a minor intermediate phase that usually coexists with form I and can be transferred from form II and to form I. Structural and morphological changes in form I have been followed by simultaneous wide-angle x-ray diffraction (WAXD)/small-angle x-ray scattering (SAXS) measurements during cold- or melt-crystallization and subsequent melting. In all cases, a larger dimensional change was found in the crystallographic a-axis than the b-axis during heating and cooling. This may be due to the greater lateral stress variation with respect to temperature along the a direction of the primary lamellae which is induced by either the formation of secondary lamellae or the preferential chain-folding direction in poly(aryl ether ketone ketone)s. During the phase transitions of form II ← III in the cold-crystallized specimen and form III ← I in the melt-crystallized samples, lamellar variables (long period, lamellar thickness, and invariant) obtained from SAXS remain almost constant. This indicates that the density distribution in the long spacing is independent of the melting in form II or III. For melt-crystallization, the corresponding changes in unit-cell dimensions and lamellar morphology during the annealing-induced low endotherm are most consistent with the argument that these changes are due to the melting of thin lamellar population. © 1995 John Wiley & Sons, Inc. 相似文献
977.
Barium ferrite particulates prepared by a salt-melt method 总被引:1,自引:0,他引:1
Tsung-Shune Chin S.L. Hsu M.C. Deng 《Journal of magnetism and magnetic materials》1993,120(1-3):64-68
Barium ferrite particulates have been prepared by coprecipitation and calcination in a flux of NaCl-KCl. It was found that a flux containing more than 30 wt% KCl tends to seriously deteriorate the magnetic properties of resultant perticulates. The flux with 10 wt% KCl or less showed promising results. A Ba(CoZr)0.75Fe10.5O19 particulate showed the best properties, i.e., a saturation magnetization of 68.5, a squareness ratio of 0.49, and a coercivity of 1280 Oe, when calcined in NaCl at 900°C for 4 h. 相似文献
978.
On the basis of the general class of solutions of 6D vacuum Einstein equations and using well-known results of the 6D geometric model of electroweak and gravitational interactions, the variations of fundamental physical constants and their influence on the observed red-shift of galaxies are investigated. By considering the interpretation of extra components of the 6D metric as reproducing the properties of matter in the 4D curved space-time, the effective quantities of matter are obtained. In particular, the states of dust and radiation are shown. The corresponding 5D models were also investigated. 相似文献
979.
980.
G. S. Kupriyanova 《Applied magnetic resonance》1996,11(1):87-97
A calculation of the complex signals in homonuclear correlation spectra (HOMCOR) of strongly coupled ABX three-spin systems is presented. It is shown that the presence of strong coupling causes the behavior of the cross-peaks to differ significantly from that found in the case of weak coupling. Two classes of connectivity patterns, namely weak and strong connectivity pairs of transitions are distinguished. Closed expressions for the real amplitudes are given. The dependence of the real amplitude on the flip angle of the mixing pulse and on the coupling strength is analyzed. 相似文献