Coordinate transform invariance

A four-dimensional operator is shown to contain the operator-generators for rotation, scale, reflections, and boosts. The hypothesis is advanced that a physical system changes under this operator by at most a complex phase factor due to invariance against the choice of menial frame. A canonical transform gives a simple relation between space-time and energy-momentum. The basic conserved quantity is a four-dimensional angular momentum and/or coupling constant. The differential of this function contains a second-order differential product which is constrained as a power series in the independent variable. The analysis explores the consequences of the model and shows its degree of correspondence to the standard models.     

Conversion estimates for gas-solid reactions: Improved estimates for irreversible systems

Solid conversion has been of much interest to research workers and the Cumulative Gas Concentration Method (CGCM) has been developed to provide bounds for the reactant solid in irreversible systems having power-law type kinetics. This CGCM is used in conjunction with the Pseudo-Steady-State (PSS) assumption and these bounds appear to be good under certain conditions and for long times.

In this work, the PSS condition is not assumed when deriving the bounds on the cumulative gas concentration and the effect of the inclusion of the transient part is analysed. A technique, based on an iterative scheme incorporating the CGCM, is developed to provide improved estimates for the reactant solid.     

Application of129Xe 2D-EXSY NMR to intra- and interparticle exchange in zeolites

2D-EXSY NMR methods were used to explore diffusion between different domains in zeolites on two very different length scales. Measurements were made on xenon-containing samples consisting of a mixture of NaX and NaY zeolite particles which give distinct resonance lines. The cross peaks observed were interpreted in terms of interparticle exchange, and exchange rates were measured as a function of particle size. This kind of experiment with a length scale of microns to mm should be useful in model studies of diffusion in packed catalyst beds. Measurements also were made to study exchange on a much smaller length scale between the main-channel and side-pocket sites in samples of microcrystalline Na-mordenite. Exchange rates and site occupancies were measured as a function of temperature, yielding activation energies for xenon desorption and intersite diffusion. Also, information was obtained on the distribution of inequivalent side-pocket sites which leads to the large xenon NMR linewidths for this type of site.     

Measurement of the spin and temperature dependence of ddµ molecule formation rate in solid and liquid deuterium

The ddµ molecule formation rate is experimentally measured for the two hyperfine states of the dµ-atom in the temperature range of 5–30 K. Results are consistent with a preliminary measurement by the TRIUMF group and contradict theoretical predictions. The work has been performed on the JINR phasotron (Dubna).     

Electron transfer at lanthanum endohedral fullerenes

The aim of this contribution is to study lanthanum containing fullerenes produced and treated under different conditions. The work was done using solid soot extract giving poorly resolved ESR spectra or separated lanthanofullerenes in solution showing well resolved ESR spectra. ESR experiments in connection with the mass spectrometry give information on the electronic states due to the electron transfer from the endohedral metal to the fullerene cage and the influence of oxygen on endohedral lanthanofullerene. The analysis of ESR spectra indicates the presence of up to nine octets of lanthanum containing fullerenes. These species have different stabilities. Furthermore, a very narrow single ESR line in the lanthanofullerene spectrum was detected having a linewidth ΔB=0.008 mT and ag-factor 2.0025. The electron transfer to the endohedral La@C₈₂ molecule studied by voltammetry and electrochemicalin situ ESR experiments is described. The interaction of the lanthanofullerene with oxygen in solution is also studied. In different solvents the influence of oxygen on line broadening in the ESR spectra of La@C₈₂ was observed.     

Communication Roles, Perceived Effectiveness, and Satisfaction in an Environmental Management Program

Earlier research has shown a relationship between various forms of structural centrality and perceived leadership and role satisfaction in small experimental groups. The limited amount of research on this topic in naturally occurring social networks has yielded results that often conflict with one another. Different results have generally been attributed to possible differences in task environments. This paper examines the relationship between two types of structural centrality and perceived influence, role satisfaction, and perceived effectiveness in an environmental resource management program. Findings in this paper suggest that the observed differences in relationships between the network and other variables is partly a function of global network properties (e.g., marginality of subgroups) and related task environments. This revised version was published online in August 2006 with corrections to the Cover Date.     

New applications of atomic physics to the study of nuclear properties

The hyperfine interaction couples the atomic electrons and the nucleus, and because of this interaction, there is a fundamental link between the fields of atomic physics and nuclear physics. Of course, information flows in both directions through this link. This paper reviews in broad terms the previous applications of atomic physics methods to the study of nuclear properties and fundamental interactions, and then focuses on the possible applications of atom trapping methods to nuclear physics problems.Supported in part by the National Science Foundation.