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941.
E. L. Belokoneva A. G. Ivanova S. Yu. Stefanovich O. V. Dimitrova V. S. Kurazhkovskaya 《Crystallography Reports》2004,49(4):603-613
Crystals of new rare earth borates of the composition Ln[B6O9 (OH)3] (Ln = Sm-Lu), sp. gr. R3c are synthesized under hydrothermal conditions. Their crystal structures are determined on single crystals with Ln = Ho, Gd without preliminary determination of their chemical formulas. The polar anionic framework of the crystals consists
of BO3 triangles and BO4 tetrahedra and has wide channels along the threefold axis of the structure, which are similar to the channels along the a, b, and c axes in cubic Li4[B7O12]Cl boracite with Li conductivity. Rare earth atoms are arranged in the structure over the cubic F pseudolattice, whereas
the analogous positions in Li boracites are filled with Cl anions. The squared optical nonlinearity of the new crystals is
comparable with the nonlinearity of quartz, whereas the electrical conductivity in borates at 300°C exceeds 10−6 S/cm.
__________
Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 681–691.
Original Russian Text Copyright ? 2004 by Belokoneva, Ivanova, Stefanovich, Dimitrova, Kurazhkovskaya. 相似文献
942.
943.
944.
Applied Biochemistry and Biotechnology - In summary, it appears that the microbial reduction process is clearly not competitive with conventional SO2-reduction techniques when glucose (DE95 corn... 相似文献
945.
L. P. Smol'skaya S. P. Panova S. G. Kuznetsova V. P. Il'kin L. S. Danyushkin 《Journal of Applied Spectroscopy》1992,56(2):170-173
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 56, No. 2, pp. 259–263, February, 1992. 相似文献
946.
Aït Hmaïdouch L. Mançour Billah S. El Hadek M. 《Journal of Thermal Analysis and Calorimetry》2002,69(2):659-667
The solid—liquid equilibria of the ternary system H2O—Al(NO3)3—Mg(NO3)2 were studied at –30, –20, –10 and 0°C by using a synthetic method which allows to detemine all the characteristic points of isothermal sections. The stable solid phases which appear are respectively: ice, Al(NO3)3·9H2O, Mg(NO3)2·9H2O and Mg(NO3)2·6H2O. Neither double salts nor mixed crystals are observed in the temperature and composition field studied. Polytherm diagram layout show two invariant transformations correspond with an eutectic point and a peritectic point.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
947.
E. Sh. Finkel'shtein N. V. Ushakov N. A. Pritula E. A. Andreev N. A. Platé 《Russian Chemical Bulletin》1992,41(1):185-187
The thermally initiated and platinum-catalyzed polymerization of 1-silacyclobutanes with substitutents containing a trimethylsilyl group was carried out. Soluble, high-molecular-weight, heterochain siltrimethylene polymers were obtained, containing trimethylsilyl groups removed from the main chain by various bridges.A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 223–225, January, 1992. 相似文献
948.
949.
Several extraction procedures are described allowing arsenic speciation in sediments. The extraction of organometallic compounds
such as dimethylarsinic acid or monomethylarsonic acid is quite simple since these compounds are stable in the different extraction
media (HCl/ HNO3, H3PO4, ammonium oxalate) and are easily released independent of the extraction mode (magnetic stirring or microwave solubilization).
Extraction yields are higher than 96% for these two arsenic forms. An HCl/HNO3 microwave solubilization procedure allows the quantitative solubilization of mineral arsenic, but the differentiation between
the two oxidation states is not possible owing to the oxidation of As(III) to As(V). Extractions with orthophosphoric acid
or ammonium oxalate allow the solubilization of mineral arsenic with extraction yields ranging from 90 to 95% and the differentiation
between As(III) and As(V). Nevertheless, the amount of As(III) is underestimated owing to its partial oxidation. The usefulness
and advantages of microwave solubilization compared with conventional extraction procedures are discussed.
Received: 17 May 1996 / Revised: 19 September 1996 / Accepted: 25 September 1996 相似文献
950.