Exploration of Mesoporous Stationary Phases Prepared Using Deep Eutectic Solvents Combining Choline Chloride with 1,2-Butanediol or Glycerol for Use in Size-Exclusion Chromatography

Mesoporous siliceous particles were prepared using deep eutectic solvents (DESs)—either choline chloride and 1,2-butanediol in a 1:2 molar ratio (ChCl-B) or choline chloride and glycerol in a 1:2 molar ratio (ChCl-G)—and then tested as column packing materials in size-exclusion chromatography (SEC). When they were tested as column packing materials in SEC of a mixture of two dextrans with different molecular weights using a methanol mobile phase, the ChCl-G-based particles were not able to separate the dextrans, whereas the ChCl-B-based particles provided good separation (considerably better than that afforded by traditional sorbents) at a flow rate of 0.3 mL min⁻¹. This high separating power of the ChCl-B-based particles can be attributed to the utilization of the DES ChCl-B during their preparation.

     

GS-221高速摄影机的驱动与控制系统

GS—221高速摄影测量仪是用于测量大型火箭(导弹)起飞段的姿态及其横向漂移量的专用超小型高速电影经纬仪,其主机为一台间歇式同步高速电影摄影机。本文简要介绍其驱动控制和点阵数据记录系统。     

Synthesis,Structure, and Spectroscopic and Electrochemical Properties of Heteroleptic Bis(phthalocyaninato) Rare Earth Complexes with a C4 Symmetry

A series of eleven heteroleptic bis(phthalocyaninato) rare earth double‐deckers [M^III(pc){pc(α‐OC₅H₁₁)₄}] 1 – 11 (M=Y, Sm? Lu; pc=phthalocyaninato; pc(α‐OC₅H₁₁)₄=1,8,15,22‐tetrakis(1‐ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [M^III(pc)(acac)]‐induced (acac=acetylacetonato) cyclic tetramerization of 3‐(1‐ethylpropoxy)phthalonitrile in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in refluxing pentanol. These compounds could also be prepared by treating [M^III(pc)(acac)] with the metal‐free phthalocyanine H₂{pc(α‐OC₅H₁₁)₄} in refluxing octanol. The whole series of double‐decker complexes 1 – 11 were characterized by elemental analysis and various spectroscopic methods. The molecular structures of the Sm, Eu, and Er complexes 1, 2 , and 8 , respectively, were also determined by single‐crystal X‐ray diffraction analysis. The effects of the rare earth ion size on the reaction yield, molecular structure, and spectroscopic and electrochemical properties of these complexes were systematically examined.     

Biodegradable electrospun mat: Novel block copolymer of poly (p‐dioxanone‐co‐L‐lactide)‐block‐poly(ethylene glycol)

Ultrafine fibers of a laboratory‐synthesized new biodegradable poly(p‐dioxanone‐co‐L ‐lactide)‐block‐poly(ethylene glycol) copolymer were electrospun from solution and collected as a nonwoven mat. The structure and morphology of the electrospun membrane were investigated by scanning electron microscopy, differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD), and a mercury porosimeter. Solutions of the copolymer, ranging in the lactide fraction from 60 to 80 mol % in copolymer composition, were readily electrospun at room temperature from solutions up to 20 wt % in methylene chloride. We demonstrate the ability to control the fiber diameter of the copolymer as a function of solution concentration with dimethylformamide as a cosolvent. DSC and WAXD results showed the relatively poor crystallinity of the electrospun copolymer fiber. Electrospun copolymer membrane was applied for the hydrolytic degradation in phosphate buffer solution (pH = 7.5) at 37 °C. Preliminary results of the hydrolytic degradation demonstrated the degradation rate of the electrospun membrane was slower than that of the corresponding copolymers of cast film. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1955–1964, 2003     

A study on heat transfer during thermoplastic composite tape lay-up process

A study on heat transfer during thermoplastic composite tape lay-up process was done. To investigate the relation between major process variables, experiments as well as numerical simulations were performed. A small-scale tape lay-up system was built. A hot nitrogen torch was used to heat the prepreg tape. Right after the torch, a compaction roller was located to bond the prepreg plies. Temperatures inside the composite at four different locations through the thickness were measured, using thermocouples. Experiments were done for different process conditions. Numerical simulations also were performed, using the finite element code developed in this study. A numerical code was run for the same conditions as the experiment. Close agreement was observed between the numerical results and the experimental data.     

Mössbauer study of the NingQiang carbonaceous meteorites

The NingQiang carbonaceous meteorites from the Shan Xi(China) was falling in 1983. In this report, the Mössbauer spectra has been measured for the NingQiang meteorites and the spectra were analysed with computer. The experimental results indentify it as a carbonaceous meteorite of type III. The spectrum shows the principal iron components to be of olivine, magnetite, troilite and phyllosilicate or goethite material. For comparation the Mössbauer spectra of the Allende and Leoville carbonaceous meteorites have been also measured.     

E.CCD和微型机在高速相机控制系统中的应用

CCD器件及微处理机的普遍应用,使高速摄影机的电控制系统有了新的发展。本文将介绍第19届国际高速摄影与光子学会议上出现的一些新型系统。     

人胰岛素半合成方法的改进

本文对森原等人合成人胰岛素的方法进行了改进。用羧肽酶A和胰酶成功地实施了人胰岛素的半合成。精品的总收率为70％,高于1986年森原等报道的水平(50％)。 苏氨酸叔丁酯是半合成人胰岛素的主要原料之一。我们改进了它的合成方法。采用N端未加保护的苏氨酸一步法合成了     

Fibred knots and twisted Alexander invariants

We study the twisted Alexander invariants of fibred knots. We establish necessary conditions on the twisted Alexander invariants for a knot to be fibred, and develop a practical method to compute the twisted Alexander invariants from the homotopy type of a monodromy. It is illustrated that the twisted Alexander invariants carry more information on fibredness than the classical Alexander invariants, even for knots with trivial Alexander polynomials.

     

Test of the jellium model: Photoelectron spectra of small copper clusters

Copper cluster anions in the size range of 1-18 atoms are studied by photoelectron spectroscopy. Using photons of 5.0 eV energy the electronic level structure built from the delocalized s-orbitals of the atoms is revealed. An attempt is made to assign the observed bands to the electronic shells predicted by the jellium model. Even though the general behavior resembles the predictions of this model, the spectra are much more complicated reflecting the discrete atomic geometry of these particles.