Analysis of Cu segregation to oxide–metal interface of Ni‐based alloy in a metal‐dusting environment

Hard X‐ray photoelectron spectroscopy (HX‐PES) has been realized using high‐brilliance synchrotron radiation. High‐energy photon excitation enables us to probe photoelectrons with larger escape depth compared to conventional PES. This allows us to conduct, without destruction, a study of the embedded interface of materials as the oxide‐ metal interface. We apply HX‐PES to investigate for Cu segregation in the oxide–metal interface during metal‐dusting corrosion. The effective concentration of Cu in the segregation was estimated a few times higher than the bulk concentration. These results on the interface layer can explain the variation in the corrosion resistance. Copyright © 2008 John Wiley & Sons, Ltd.     

Diamagnetic muon yields of metal acetylacetonates

Diamagnetic muon yields /P_D/ in various metal acetylacetonates were measured at room temperature by the muon spin rotation technique. We have found a clear difference in P_D between complexes of typical elements and those of transition elements. We suggest that partially filled inner orbitals play some important role in determining the diamagnetic yield in these complexes.     

Compounds having thiourea moiety as derivatization reagents in liquid chromatography/electrospray ionization–tandem mass spectrometry (LC/ESI‐MS/MS): synthesis of derivatization reagents for carboxylic acids

The derivatization reagents for carboxylic acids, N‐(Pyridin‐3‐yl)hydrazinecarbothioamide, N‐[4‐(dimethylamino)phenyl]hydrazinecarbothioamide, 1‐(2‐aminoethyl)‐3‐(pyridin‐3‐yl)thiourea, 1‐(2‐aminoethyl)‐3‐[4‐(dimethylamino)phenyl]thiourea and 4‐(2‐aminoethyl)‐N‐phenylpiperazine‐1‐carbothioamide were synthesized. These reagents reacted with carboxylic acids at 60°C for 45 min in the presence of the condensation reagents. The generated derivatives were favorably separated on the reversed‐phase column and sensitively detected by electrospray ionization tandem mass spectrometry. These reagents enhanced the electrospray ionization response of the analyte and generated a particular product ion efficiently by collision‐induced dissociation, and thus they were suitable for MS/MS detection. Copyright © 2010 John Wiley & Sons, Ltd.     

Spin dynamics in crystalline and amorphous DyAg

Crystalline (cr-) Dyag [CsC] structure] orders antiferro-magnetically with T_N≅60K; amorphous (am-) DyAg ferro-magnetically with T_C≈-18K. We measured the longitudinal field (LF) μ⁺SR relaxation functions G_ZZ(t) for 5K<T<300K using surface muons. In the paramagnetic state. cr-DyAg gives an exponential G_ZZ (t) in the relaxation rate rising first slowly then more rapidlynear T_N; no decoupling is observed in LF up to 0.4T. In the ordered state we see a Lorentzian Kubo-Toyabe G_ZZ(t), becoming nearly static at the lowest temperatures. Its static width is very narrow (Δ≈-7 MHz), and full dceoupling is achieved here in 0.1 T. On approaching T_N, the fluctuation rate and the static width increase mootonically bt the field distribution remains Loratzian. A LF of 0.4T is then insufficient to quench the fast exponential relaxation. In paramagnetic am-DyAg, the μ⁺ depolarization is always much faster then in cr-DyAg. At lower temperatures it is better described by a root-exponential than an exponential G_ZZ(t). Below T_C an exponentially relaxing signal with 1/3 amplitude is seen. The decoupling effect of LF up to 0.4T was negligible at all temperatures.     

Muon spin relaxation in diluted triangular‐lattice antiferromagnet

Zero and longitudinal field μSR measurements on diluted triangular‐lattice antiferromagnet LuFeMgO₄ have revealed gradual and highly anisotropic slowing‐down of spin fluctuation. Relaxation rate \lambda in the condition with initial muon spins perpendicular to the hexagonal c‐plane shows divergent behavior while that in the parallel configuration remains finite. At certain temperature range the fluctuation of spins is suppressed by a small external magnetic field. Monte Carlo calculation suggests that the correlation time for z(c)‐component of spins diverges first on cooling. This revised version was published online in July 2006 with corrections to the Cover Date.