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41.
Hyocheon Kweon Kyu Won Lee Cheol Eui Lee S.J. Noh H.S. Kim D.-J. Kim J.-W. Choi 《Solid State Communications》2010,150(13-14):572-575
Electron paramagnetic resonance measurements revealed a ferromagnetic phase transition taking place near room temperature in quasi-two-dimensional dodecylamine-intercalated vanadium pentoxide with a mixed structure of coexisting lamellar and rectangular phases. It is shown that the ferromagnetism can be ascribed to the rectangular phase, whereas the paramagnetic lamellar phase undergoes no magnetic transition. 相似文献
42.
The Navier-Stokes system for a steady-state barotropic nonlinear compressible viscous flow, with an inflow boundary condition, is studied on a polygon D. A unique existence for the solution of the system is established. It is shown that the lowest order corner singularity of the nonlinear system is the same as that of the Laplacian in suitable L q spaces. Let ω be the interior angle of a vertex P of D. If \(\) and \(\), then the velocity u is split into singular and regular parts near the vertex P. If α < 2 and \(\) or if α > 2 and 2 < q < ∞&;, it is shown that u∈ (H 2, q (D))2. 相似文献
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Deok‐Heon Kweon Ho‐Kyun Kim Jeum‐Jong Kim Hyun A. Chung Yong‐Jin Yoon Woo Song Lee Sung‐Kyu Kim 《Journal of heterocyclic chemistry》2002,39(1):203-211
The direct sulfonylation of 4,5‐dichloropyridazin‐3‐ones with some benzenesulfonyl chlorides in the presence of base in tetrahydrofuran gave only the corresponding N‐sulfonylated product. The reaction of 2‐benzenesulfonyl‐4,5‐dichloropyridazin‐3‐ones with some aliphatic amines under neutral conditions afforded 5‐alkylamino‐2‐benzenesulfonyl‐4‐chloropyridazin‐3‐ones and/or the corresponding N‐alkyl‐benzenesulfonamides. 相似文献
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Dae-Hyukkweon Kweon Sung-Gunkim Kim Jin-Hoseo Seo 《Journal of inclusion phenomena and macrocyclic chemistry》2004,50(1-2):37-41
Recombinant DNA technology and protein engineering are currently utilized in the cost-effective production of pharmaceutical and industrial proteins with native conformation. Escherichia coli retains its dominant position as the first choice of host for speed, simplicity and well-established production protocols. However, protein production using recombinant E. coli occasionally encounters complex purification and refolding steps. This paper introduces an efficient scheme for purification andin vitro refolding of industrially important proteins including cyclodextrin glycosyltransferase (CGTase) expressed in recombinant E. coli employing a polycationic amino acid fusion system. Fusion of polycationic amino acids to CGTase allowed purification and refolding of CGTase to be simple and efficient. A novel CGTase production strategy will be discussed by considering recent progress in protein purification and refolding techniques. 相似文献
47.
Byun HS Won M Park KA Kim YR Choi BL Lee H Hong JH Piao L Park J Kim JM Kweon GR Kang SH Han J Hur GM 《Experimental & molecular medicine》2008,40(2):186-195
Previous studies have demonstrated that rottlerin, a specific PKCdelta inhibitor, potentiates death receptor- mediated apoptosis through a cytochrome c-dependent or -independent pathway. However, its ability to regulate necrotic cell death, as well as the underlying mechanism, remains unknown. We found that in murine fibrosarcoma L929 cells, treatment with rottlerin protected the cells against TNF-induced necrosis, whereas it sensitized the cells to apoptosis induced by co-treatment with Hsp90 inhibitor geldanamycin and TNF, in a manner independent of its ability to inhibit PKC-delta. TNF treatment induced rapid accumulation of mitochondrial superoxide (O2-) through the Nox1 NADPH oxidase when cells undergo necrosis. Moreover, pretreatment with rottlerin failed to induce the GTP-bound form of small GTPase Rac1 by TNF treatment, and subsequently suppressed mitochondrial O2- production and poly(ADP-ribose) polymerase activation, thus inhibiting necrotic cell death. Therefore, our study suggests that Nox1 NADPH oxidase is a new molecular target for anti-necrotic activity of rottlerin upon death-receptor ligation. 相似文献
48.
Min Ku Jeon Chang Hwa Lee Chang Je Park Jung Hoon Choi In Hak Cho Kweon Ho Kang Hwan-Seo Park Geun Il Park 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(3):1629-1633
The effect of fuel burn-up on the radioactivation behavior of cladding hull materials was investigated using the ORIGEN-S code for various materials of Zircaloy-4, Zirlo, HANA-4, and HANA-6 and for various fuel burn-ups of 30, 45, 60, and 75 GWD/MTU. The Zircaloy-4 material is the only one that does not contain Nb as an alloy constituent, and it was revealed that 125Sb, 125mTe, and 55Fe are the major sources of radioactivity. On the other hand, 93mNb was identified as the most radioactive nuclide for the other materials although minor radioactive nuclides varied owing to their different initial constituents. The radioactivity of 94Nb was of particular focus owing to its acceptance limit against a Korean intermediate-/low-level waste repository. The radioactivation calculation results revealed that only Zircaloy-4 is acceptable for the Korean repository, while the other materials required at least 4,900 of Nb decontamination factor owing to the high radioactivity of 94Nb regardless of the fuel burn-up. A discussion was also made on the feasibility of Zr recovery methods (chlorination and electrorefining) for selective recovery of Zr so that it can be disposed of in the Korean repository. 相似文献
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In this study we developed simple, coupled algorithms for solving low‐Reynolds‐number flows applicable to micro‐scale flows such as electro‐osmotic flows. The most popular scheme, i.e. the projection method, is not suitable for such flows because of its undesirable slip effect on boundaries at low‐Reynolds‐numbers. In our method, the velocity and pressure are strongly coupled, and the momentum and pressure equations are solved iteratively by using the successive over relaxation (SOR) method while exchanging the unknown variables as soon as they have been updated. The developed methods are applied to a model flow for evaluating their performance. It was found that the coupled schemes are indeed superior to a projection method, i.e. the fractional‐step method, in both numerical accuracy and CPU time. The code is then applied to a dc electro‐osmotic flow within a cavity driven by electrical force acting on the ions spread in the fluid. In this application, the system of equations for the fluid flow and that for the ion transport are solved in a decoupled way, but each system is solved by using fully implicit schemes. From the simulations and by introducing the concept of vorticity source, we can identify two roles of the body force, one contributing to build‐up of the osmotic pressure and the other to the fluid flow. The interesting reverse flow occurring after the external potentials applied on the electrodes have been shut off is also investigated in terms of the vorticity source. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献