全文获取类型
收费全文 | 3991篇 |
免费 | 537篇 |
国内免费 | 393篇 |
专业分类
化学 | 2842篇 |
晶体学 | 33篇 |
力学 | 174篇 |
综合类 | 45篇 |
数学 | 594篇 |
物理学 | 1233篇 |
出版年
2024年 | 8篇 |
2023年 | 75篇 |
2022年 | 130篇 |
2021年 | 124篇 |
2020年 | 140篇 |
2019年 | 153篇 |
2018年 | 149篇 |
2017年 | 125篇 |
2016年 | 191篇 |
2015年 | 176篇 |
2014年 | 252篇 |
2013年 | 282篇 |
2012年 | 324篇 |
2011年 | 315篇 |
2010年 | 231篇 |
2009年 | 214篇 |
2008年 | 256篇 |
2007年 | 208篇 |
2006年 | 205篇 |
2005年 | 168篇 |
2004年 | 140篇 |
2003年 | 122篇 |
2002年 | 145篇 |
2001年 | 125篇 |
2000年 | 71篇 |
1999年 | 68篇 |
1998年 | 61篇 |
1997年 | 41篇 |
1996年 | 38篇 |
1995年 | 43篇 |
1994年 | 48篇 |
1993年 | 35篇 |
1992年 | 34篇 |
1991年 | 41篇 |
1990年 | 30篇 |
1989年 | 16篇 |
1988年 | 15篇 |
1987年 | 14篇 |
1986年 | 9篇 |
1985年 | 16篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1971年 | 5篇 |
1962年 | 3篇 |
排序方式: 共有4921条查询结果,搜索用时 31 毫秒
141.
A novel three-dimensional metal selenite [Fe2(H2O)4(SeO3)2] (1) has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum, TG analysis and the single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, with a=6.5283(13) Å, b=8.8754(18) Å, c=7.6798(15) Å, (=98.82(3)β, V=439.71(15) Å3, and Z=2. Compounds 1 exhibits interesting three-dimensional structure constructed from {FeO6} octahedra and {SeO3} pyramids linked via the corner- and/or edge-sharing mode. The most interesting structural feature of compound 1 is that the existence of multidirectional intersecting double helical chains in one compound. 相似文献
142.
A novel near infrared (NIR) modeling method—Laplacian regularized least squares regression (LapRLSR) was presented, which can take the advantage of many unlabeled spectra to promote the prediction performance of the model even if there are only few calibration samples. Using LapRLSR modeling, NIR spectral analysis was applied to the online monitoring of the concentration of salvia acid B in the column separation of Salvianolate. The results demonstrated that LapRLSR outperformed partial least squares (PLS) significantly, and NIR online analysis was applicable. 相似文献
143.
Yu-Dong Shen Hai-Qiang Wu Xian-Zhang Bu Lin-Kun An Pei-Qing Liu Yue-Ming Li 《Tetrahedron》2005,61(38):9097-9101
A novel procedure to construct o-naphthothiophenequinones has been achieved from readily available o-benzothiophenquinones and N-dienes via Diels-Alder reaction-aromatization sequence as key steps. The absolute regioselectivity was established via Diels-Alder reaction of o-benzothiophenquinones with rich electron N-dienes. 相似文献
144.
Optical Review - Based on the planar optical theory, compact beam expanders are proposed to miniaturize the dimension of an optical system. Both simulated and experimental results have demonstrated... 相似文献
145.
146.
147.
Wenyu Zhao Shengli An Bin Fan Songbo Li 《Applied Physics A: Materials Science & Processing》2014,116(3):987-991
Tm3+ and In3+ co-doped LaAlO3 phosphors were prepared by a Pechini sol–gel method and characterized by X-ray diffraction, scanning electron microscope, and cathodoluminescence spectrum. The phosphor is composed of slightly aggregated particles with approximately spherical shape and a narrow size range of 1.0–1.5 μm. Under voltage electron beam excitation, the phosphor shows the characteristic emissions of Tm3+. All the color purity, radiant efficiency, luminous efficiency, and stability of the optimum LaAlO3:0.01Tm3+, 0.04In3+ phosphor are superior to these of commercial ZnS:Ag,Cl phosphor. These tests suggest that it could be a potential candidate as a blue phosphor for field emission displays. 相似文献
148.
149.
Damla Durak Anıl Delikanlı Cahit Demetgül İbrahim Kani Selahattin Serin 《Transition Metal Chemistry》2013,38(2):199-206
An unsymmetrical tetradentate Schiff base (H2L) was synthesized by the reaction of 3-methoxysalicylaldehyde, o-phenylenediamine, and salicylaldehyde in EtOH. H2L was characterized by single-crystallographic X-ray analysis. Its Co(II) and Mn(III) complexes ([CoL] and [MnLCl]) were prepared and immobilized on 3-aminopropyltriethoxysilane functionalized silica gel. The immobilized materials were found to be efficient catalysts for epoxidation of styrene in the presence of tert-BuOOH in acetonitrile at 40 °C. The catalysts can be reused several times without significant loss of performance. 相似文献
150.
Montmorillonite K10 was found to catalyze the Michael addition of indoles or pyrrole with nitroalkenes efficiently under solventless condition. The short reaction time, simple workup, and excellent yields were noteworthy. The green catalyst could be reused for three runs without considerable variation in yield. 相似文献