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排序方式: 共有2936条查询结果,搜索用时 10 毫秒
91.
Eunchan Jeong Joon Heo Dr. Sehoon Park Prof. Dr. Sukbok Chang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(25):6320-6325
While numerous organo(metallic)catalyst systems were documented for dearomative hydroboration of N-aromatics, alkoxide base catalysts have not been disclosed thus far. Described herein is the first example of alkoxide-catalyzed hydroboration of N-heteroaromatics including pyridines, providing a broad range of reduced N-heterocycles with high efficiency and selectivity. Mechanistic studies revealed an unprecedented counterintuitive dearomatization pathway, in which 1) pyridine-BH3 adducts undergo a hydride attack by alkoxyborohydrides, 2) in situ generated BH3 serves as a catalytic promoter, and 3) 1,4-dihydropyridyl borohydride is in a predominant resting state. 相似文献
92.
Dileep K. Singh Suzi Kim Jeong Hwa Lee Na Keum Lee Jinwoo Kim Jeeyeon Lee Ikyon Kim 《Journal of heterocyclic chemistry》2020,57(8):3018-3028
A highly fluorescent indolizino[1,2-c]quinoline with a substituent at the C6 position was designed and synthesized as a new indolizine-quinoline hybrid structure via a tetracyclic lactam. Various (hetero)aryl groups were introduced at the C6 site of this basic skeleton to display intriguing photophysical properties. 相似文献
93.
Seon Yu Lee Ji Hyun Jeong Bo Na Kim So Jung Park Yang-Chun Park Guk Yeo Lee 《Biomedical chromatography : BMC》2020,34(4):e4774
The aim of this study was to confirm pharmacokinetic screening of multiple components in healthy Korean subjects after oral administration of Samso-eum and perform quantitation of active components in the human plasma. Thirteen potential bioactive components [puerarin (PRR), daidzin, nodakenin, ginsenoside Rb1, 18β-glycyrrhetinic acid (18β-GTA), 6-shogaol, naringin, glycyrrhizin, hesperidin, platycodin D, naringenin, hesperetin, and 6-gingerol] were screened based on literature. The results showed that three analytes (daidzin, naringenin, and hesperetin) were detected in trace amounts. In addition, PRR and 18β-GTA were detected in human plasma after the oral administration of Samso-eum. In this study, a liquid chromatography–electrospray ionization-tandem mass spectrometry method was validated for the simultaneous determination of PRR and 18β-GTA in human plasma. This was the first study to evaluate pharmacokinetics of PRR and 18β-GTA after the usual oral dose of Samso-eum (30 g containing 102.48 mg PRR, 48.18 mg glycyrrhizin) in human subjects. 相似文献
94.
Nonlinear Dynamics - Quantum features of time-dependent molecular interactions are investigated by introducing a time-varying Hamiltonian that involves a generalized non-central potential.... 相似文献
95.
Herein, two unit of β-cyclodextrin linked by thiomethylene bridge was synthesized and employed as a novel efficient supramolecular host for the synthesis of biologically active chromenones templates via three-component single-pot reaction. A possible reaction mechanism through molecular complexation is suggested based on 2D ROESY NMR spectroscopic analysis. Moreover, the catalyst could be easily recycled, while a 94% yield and 89% rate of catalyst recovery could be achieved after four cycles of catalyst recycling. Environmentally benign reaction conditions, excellent yields, and avoidance of organic solvent and conventional isolation as well as purification are the noteworthy credits of this developed protocol. 相似文献
96.
Here, we present physical–chemical properties of Linde type A (LTA) zeolite crystals synthesized via conventional hydrothermal
and microwave heating methods. Both heating methods produced LTA crystals that were sub-micron in size, highly negatively
charged, super-hydrophilic, and stable when dispersed in water. However, microwave heating produced relatively narrow crystal
size distributions, required much shorter heating times, and did not significantly change composition, crystallinity, or surface
chemistry. Moreover, microwave heating allowed systematic variation of crystal size by varying heating temperature and time
during the crystallization reaction, thus producing a continuous gradient of crystal sizes ranging from about 90 to 300 nm.
In ion-exchange studies, colloidal zeolites exhibited excellent sorption kinetics and capacity for divalent metal ions, suggesting
their potential for use in water softening, scale inhibition, and scavenging of toxic metal ions from water. 相似文献
97.
Jin-Mun Jeong 《Journal of Applied Mathematics and Computing》2002,9(1):213-230
We deal with the approximate controllability for semilinear systems with time delay in a Hilbert space. First, we show the existence and uniqueness of solutions of the given systems with the more general Lipschitz continuity of nonlinear operator f fromR ×V toH. Thereafter, it is shown that the equivalence between the reachable set of the semilinear system and that of its corresponding linear system. Finally, we make a practical application of the conditions to the system with only discrete delay. 相似文献
98.
Quantum Spheres and Projective Spaces as Graph Algebras 总被引:5,自引:0,他引:5
The C
*
-algebras of continuous functions on quantum spheres, quantum real projective spaces, and quantum complex projective spaces
are realized as Cuntz-Krieger algebras corresponding to suitable directed graphs. Structural results about these quantum spaces,
especially about their ideals and K-theory, are then derived from the general theory of graph algebras. It is shown that the quantum even and odd dimensional
spheres are produced by repeated application of a quantum double suspension to two points and the circle, respectively.
Received: 31 January 2001 / Accepted: 29 July 2002 Published online: 7 November 2002
RID="*"
ID="*" Supported by grant No. R04–2001–000–00117–0 from the Korea Science & Engineering Foundation.
RID="**"
ID="**" Partially supported by the Research Management Committee of the University of Newcastle. 相似文献
99.
Sun Hong Lee Sang Youn Chae Yun Jeong Hwang Kee-Kahb Koo Oh-Shim Joo 《Applied Physics A: Materials Science & Processing》2013,112(3):733-737
Dye-sensitized solar cells (DSSCs) were fabricated using TiO2 nanoparticles (NPs), TiO2 nanotube arrays (NTAs), and surface-modified NTAs with a TiCl4 treatment. The photovoltaic efficiencies of the DSSCs using TiO2 NP, NTA, and TiCl4-treated NTA electrodes are 4.25, 4.74, and 7.47 %, respectively. The highest performance was observed with a TiCl4-treated TiO2 NTA photoanode, although in the case of the latter two electrodes, the amounts of N719 dye adsorbed were similar and 68 % of that of the NP electrode. Electrochemical impedance measurements show that the overall resistance, including the charge–transfer resistance, was smaller with NTA morphologies than with NP morphologies. We suggest that a different electron transfer mechanism along the one-dimensional nanostructure of the TiO2 NTAs contributes to the smaller charge–transfer resistance, resulting in a higher short circuit current (J sc), even at lower dye adsorption. Furthermore, the TiCl4-treated NTAs showed even smaller charge–transfer resistance, resulting in the highest J sc value, because the downward shift in the conduction band edge improves the electron injection efficiency from the excited dye into the TiCl4-treated TiO2 electrodes. 相似文献
100.
S. H. Kim K. H. Byun I. B. Sohn S. H. Jeong 《Applied physics. B, Lasers and optics》2013,113(3):395-402
In this work, we report the progressive formation of first nanoparticles, next fine ripples, and eventually coarse ripples during the irradiation of single-crystal 6H-SiC surfaces with increasing number of femtosecond laser pulses (λ = 515 nm, τ = 250 fs, repetition rate = 100 kHz). At laser fluences greater than the single-pulse ablation threshold, nanoparticles were produced on the surface by the first few pulses over which fine ripple patterns overlapped at increased pulse numbers. As the pulse number was further increased over ten, the surface was gradually transformed into a coarse ripple–covered one. At laser fluence below the threshold, however, only fine ripples were formed nonuniformly. 相似文献