Conductivity‐Dependent Completion of Oxygen Reduction on Oxide Catalysts

The electric conductivity‐dependence of the number of electrons transferred during the oxygen reduction reaction is presented. Intensive properties, such as the number of electrons transferred, are difficult to be considered conductivity‐dependent. Four different perovskite oxide catalysts of different conductivities were investigated with varying carbon contents. More conductive environments surrounding active sites, achieved by more conductive catalysts (providing internal electric pathways) or higher carbon content (providing external electric pathways), resulted in higher number of electrons transferred toward more complete 4e reduction of oxygen, and also changed the rate‐determining steps from two‐step 2e process to a single‐step 1e process. Experimental evidence of the conductivity dependency was described by a microscopic ohmic polarization model based on effective potential localized nearby the active sites.     

Liquid-phase dehydration of sorbitol under microwave irradiation in the presence of acidic resin catalysts

Liquid-phase dehydration of sorbitol has been investigated in wide reaction conditions especially under microwave irradiation in the presence of acidic resin catalysts. From the selectivity for sorbitan and isosorbide, it can be understood that the dehydration is a consecutive reaction (sorbitol to sorbitan, and finally to isosorbide) and that the sorbitan is an intermediate of the dehydration. By using microwave irradiation, the dehydration can be accelerated by around 20?C34 times compared with the rate by conventional electric heating at the same temperature, or the reaction temperature can be decreased by around 40 °C for the comparable conversion in a similar reaction time. However, the microwaves do not have noticeable effects on the selectivity for isosorbide or sorbitan. The accelerated dehydration under microwaves is mainly due to decreased activation energy.     

Optimal investment and consumption decision of a family with life insurance

We study an optimal portfolio and consumption choice problem of a family that combines life insurance for parents who receive deterministic labor income until the fixed time T. We consider utility functions of parents and children separately and assume that parents have an uncertain lifetime. If parents die before time T, children have no labor income and they choose the optimal consumption and portfolio with remaining wealth and life insurance benefit. The object of the family is to maximize the weighted average of utility of parents and that of children. We obtain analytic solutions for the value function and the optimal policies, and then analyze how the changes of the weight of the parents’ utility function and other factors affect the optimal policies.     

Piezochromic fluorescence in liquid crystalline conjugated polymers

Liquid crystalline diphenylacetylene polymer derivatives showed piezochromic fluorescence via order-to-disorder phase transition.     

Circulant Double Coverings of a Circulant Graph of Valency Four

Several isomorphism classes of graph coverings of a graph G have been enumerated by many authors (see [3], [8]–[15]). A covering of G is called circulant if its covering graph is circulant. Recently, the authors [4] enumerated the isomorphism classes of circulant double coverings of a certain kind, called typical, and showed that no double covering of a circulant graph of valency 3 is circulant. In this paper, the isomorphism classes of connected circulant double coverings of a circulant graph of valency 4 are enumerated. As a consequence, it is shown that no double covering of a non-circulant graph G of valency 4 can be circulant if G is vertex-transitive or G has a prime power of vertices. The first author is supported by NSF of China (No. 60473019) and by NKBRPC (2004CB318000), and the second author is supported by Com²MaC-KOSEF (R11-1999-054) in Korea.     

γ-照射银纳米粒子及其抗生特性(英文)

Silvernanoparticleshaveprovidedconsider ableinterestbecauseoftheirpotentialapplications inareassuchasforfightingagainstalltypesof diseases,whethercausedbygerms,viruses,bac teria,allergensorpathogens.Atthesametime, silvernanoparticleshaveattractedconside…     

Synthesis and characterization of polyimides from bis(3‐aminophenyl)‐4‐(1‐adamantyl)phenoxyphenyl phosphine oxide

A novel diamine, bis(3‐aminophenyl)‐4‐(1‐adamantyl)phenoxyphenyl phosphine oxide (mDAATPPO), was synthesized via the Williamson ether reaction of 4‐(1‐adamantyl)phenol and bis(3‐nitrophenyl)‐4‐fluorophenyl phosphine oxide, followed by reduction. The phenol group was prepared by the Friedel–Crafts reaction of 1‐bromoadamantane and phenol, whereas the phosphine oxide group was synthesized by the Grignard reaction of 1‐bromo‐4‐fluorobezene and diphenyl phosphinic chloride, followed by nitration. The monomer and its intermediate compounds were characterized with Fourier transform infrared, NMR, and melting‐point apparatus. The monomer was then used to prepare polyimides with 2,2‐bis(3,4‐dicarboxyphenyl)hexafluoropropane dianhydride, 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride, 4,4′‐oxydiphthalic dianhydride, and pyromellitic dianhydride by the conventional two‐step synthesis: the preparation of poly(amic acid) followed by solution imidization. The molecular weights of the polyimides were controlled to 20,000 g/mol by off‐stoichiometry, and the synthesized polyimides were characterized with Fourier transform infrared, NMR, gel permeation chromatography, thermogravimetric analysis, and differential scanning calorimetry. In addition, the solubility, intrinsic viscosity, dielectric constant, and birefringence of the polyimides were evaluated. Novel polyimides with mDAATPPO exhibited good solubility, high glass‐transition temperatures (290–330 °C), excellent thermal stability (>500 °C), low dielectric constants (2.77–3.01), low refractive indices, and low birefringence values (0.0019–0.0030). © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2567–2578, 2006     

Transport properties of heavily AsF5 doped polyacetylene

We report measurements of the temperature dependence of the thermoelectric power and electrical conductivity for polyacetylene heavily doped (more than 10%) with arsenic pentafluoride. The thermopower is small, positive and linear with temperature. The conductivity is very large for a polymeric system, about 1000 (Ω cm)^-1 at room temperature, and as temperature is decreased drops in value by less than a factor of two, becoming essentially temperature independent below 4 K. The samples exhibited ohmic behavior at the current densities used and did not show any frequency dependence up to 1000 Hz. No evidence for superconductivity was found down to 30 mK. The results are interpreted as the first conclusive evidence for the existence of a metallic state at all temperatures in this material.