全文获取类型
收费全文 | 1423篇 |
免费 | 133篇 |
国内免费 | 2篇 |
专业分类
化学 | 974篇 |
晶体学 | 12篇 |
力学 | 22篇 |
数学 | 345篇 |
物理学 | 205篇 |
出版年
2024年 | 5篇 |
2023年 | 19篇 |
2022年 | 24篇 |
2021年 | 38篇 |
2020年 | 44篇 |
2019年 | 64篇 |
2018年 | 52篇 |
2017年 | 38篇 |
2016年 | 92篇 |
2015年 | 99篇 |
2014年 | 83篇 |
2013年 | 237篇 |
2012年 | 141篇 |
2011年 | 133篇 |
2010年 | 73篇 |
2009年 | 52篇 |
2008年 | 46篇 |
2007年 | 24篇 |
2006年 | 45篇 |
2005年 | 22篇 |
2004年 | 10篇 |
2003年 | 12篇 |
2002年 | 21篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 11篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1986年 | 3篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1958年 | 2篇 |
1955年 | 2篇 |
1922年 | 1篇 |
排序方式: 共有1558条查询结果,搜索用时 93 毫秒
11.
Raquel F. P. Nogueira Ronaldo A. Pilli Nelson durÁn 《Applied biochemistry and biotechnology》1992,33(3):169-176
Growth of the ascomyceteChrysonilia sitophila during degradation of lignin model dimers and monomers was compared to a glucose control. An inhibition of growth by Cα-carbonyl
monomers and stimulation by β-O-4 lignin model and vanillyl alcohol were observed. A comparison of the degradation by this
ascomycete with the basidiomycetePhanerochaete chrysosoporium showed similarities in relation to the type of degradation caused. 相似文献
12.
Kótai László Horváth Tibor Szentmihályi Klára Keszler Ágnes 《Transition Metal Chemistry》2000,25(3):293-294
We have investigated the effect of temperature on the postulated quasi-intramolecular acid-base reactions in aqueous solutions of Cu(NH3)4(MnO4)2 and Ag(NH3)2ClO4. Pure ammonium permanganate and perchlorate were obtained above 5 C and at room temperature, respectively, due to quasi-intramolecular acid-base reactions. 相似文献
13.
14.
The B—A transition has been detected in the emission spectra of ArBr, KrBr, Krl and XeI at low pressure. Comparison with the well-known /ldB–X” continua implies that, in many cases, the latter is heavily overlapped by C—A emission. 相似文献
15.
The Ramanujan Journal - This paper provides elementary proofs for several types of congruences involving multipartitions and self-convolutions of the divisor function. Our computations use... 相似文献
16.
Nazarov Anatoly Sztrik János Kvach Anna Tóth Ádám 《Methodology and Computing in Applied Probability》2022,24(3):1503-1518
Methodology and Computing in Applied Probability - This paper deals with a retrial queuing system with a finite number of sources and collision of the customers, where the server is subject to... 相似文献
17.
Klaus Rose Vlastimil MatĚjec Milos Hayer Marie PospiŠilovÁ 《Journal of Sol-Gel Science and Technology》1998,13(1-3):729-733
Various types of UV-curable organically modified siloxanes have been synthesized by the sol-gel method with the aim of fabricating chemically sensitive coatings for silica optical fibers. The refractive index of the coating material can be tailored in the range from 1.46 to 1.56 and sensitivity towards CO2 is achieved by incorporation of amino groups. The interaction of the cured layers with CO2 or with hydrocarbons has been studied in immersion experiments. Both the reaction of CO2 with incorporated amino groups and the penetration of hydrocarbons into the layer induce changes of the light absorption coefficient and the refractive index of the coating which are detected by measuring the output light intensity from the fiber. 相似文献
18.
The stereochemistry of the cyclodehydration of (±)- and meso-2,5-hexanediol on the action of various dehydrating agents was investigated. The earlier assumed and confirmed intramolecular SN2 mechanism for acid-catalysed ring-closure was found to hold in most cases. Various extents of racemisation can be observed on the action of certain Lewis acids, and the solvents concentrated H2SO4 and HMPT (hexamethyl phosporic acid triamide) under previously unexamined reaction conditions. 相似文献
19.
Arnason I Kvaran A Jonsdottir S Gudnason PI Oberhammer H 《The Journal of organic chemistry》2002,67(11):3827-3831
The molecular structure of 1-methyl-1-silacyclohexane 3 has been determined by gas electron diffraction (GED). The conformational preference of the methyl group was studied experimentally in the gas phase (GED) and in solution (low-temperature (13)C NMR) and by quantum chemical calculations (HF, MP2, and B3LYP with 6-31G basis sets and mPW1PW91/6-311G(2df,p)). Both experimental methods result in a preference of the equatorial position of the methyl group, 68(7)% in the gas phase at 298 K and 74(1)% in solution at 110 K. The calculations predict 68-73% equatorial conformer at room temperature. From coalescence temperatures, Gibbs free energies of activation for ring inversion DeltaG++ (eq --> ax) = 5.81(18) and DeltaG++ (ax --> eq) = 5.56(18) kcal mol(-1) were derived. The calculated values for DeltaG++ (eq --> ax) are 5.92 (B3LYP) and 5.84 kcal mol(-1) (mPW1PW91). 相似文献
20.
Manuel Cano Beatriz Palenzuela J. Luis Ávila Rafael Rodríguez‐Amaro 《Electroanalysis》2007,19(9):973-977
A PVC/TTF‐TCNQ composite electrode has been employed as detector in a flow injection system. The proposed method allows the simultaneous detection of ascorbic acid (AA) and uric acid (UA) in mixtures by using a FIA system in a simple manner, without pre‐treatment or modified electrode. This method is based on the amperometric determination of (a) ascorbic acid at 0.15 V and (b) both analytes at 0.35 V, being the response linear in the range 1×10?2–4×10?4 M for both analytes with detection limits (S/N=3) of 1.2×10?4 M and 8.1×10?5 M for AA and UA, respectively. 相似文献