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This work deals with the transient analysis of crystal size distribution (CSD) in a continuous sodium chloride crystallizer. The crystallization is assumed to take place under diffusion controlled conditions and the crystal growth models reported by Sen Gupta and Dutta elsewhere have been used. Monte Carlo (MC) scheme has been employed for simulation purposes. The simulation results have been compared with the available experimental data at steady state. 相似文献
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Mani Iyer Prasanth Subramanyam Gayathri James Prabhanand Bhaskar Venkateswaran Krishnan Krishnaswamy Balamurugan 《Photochemistry and photobiology》2020,96(1):139-147
Aging, a universal and unique process, occurs both intrinsically (chronological) and extrinsically (photoaging). Ultraviolet-A (UV-A)-mediated stress is a growing health hazard to mankind as it is the major cause of photoaging, which could lead to much damage of skin cells and tissues ranging from tan, burn, or even cancer. The present study focuses on the role of antioxidants and other natural compounds which have been widely used in oral/topical applications to combat and delay the effects of photoaging using model nematode Caenorhabditis elegans. Compounds like green tea extract, naringenin, and naringin, which are known for their antioxidant properties, were able to extend life span and healthspan of the nematode in normal as well as under UV-A-mediated stress conditions. Regulation of both the stress-responsive genes (skn-1 and sir-2.1) and the aging-regulating genes (daf-2 and age-1) was attributable for these conditions. Interestingly, it was observed that these compounds when combined in equal ratios by weight worked synergistically to combat the aging process. Pronounced synergistic effects were observed during UV-A-mediated stress conditions, suggesting that these could be used as potential antiphotoaging compounds which will be of greater significance for health-based research. 相似文献
416.
Bimetallic palladium(II) complexes containing classical NHC donor ligands are becoming increasingly popular owing to their various catalytic applications. However, examples of the aforementioned complexes with mixed NHC/PPh3 ligands are still rare. Bimetallic palladium(II) complexes possessing these mixed ligands are described starting from a C2-symmetric bis-imidazolium salt containing 4,4′-substituted central biphenyl ring. All the palladium(II) complexes have been tested as precatalysts in α-arylation of oxindole and Suzuki–Miyaura coupling reactions. The complex composed of mixed NHC/PPh3 donor ligands shows superior catalytic activity compared with the corresponding PEPPSI type complexes when applied in α-arylation of oxindole. The dinuclear complexes display better activity compared with the mononuclear complexes. The preliminary electrochemical measurements show the facile oxidation of PdII in the presence of combined NHC/PPh3 ligands compared with a combination of NHC/Py ligands. 相似文献
417.
Bhaskar Jyoti Sarmah 《Journal of organometallic chemistry》2010,695(6):781-785
The complex [Ru(CO)2(triphos-κ2P)Cl2] (1) underwent decarbonylation in dichloromethane solution under air over a period of about two weeks to afford the chelated monocarbonyl complex [Ru(CO)(triphos-κ3P)Cl2] (2). The Single Crystal X-ray structure of 2 showed a slightly distorted metal centred complex. The catalytic activity of one of the complexes [Ru(CO)(triphos-κ3P)Cl2] (2) was examined in the transfer hydrogenation of aromatic carbonyl compounds and was found to be efficient with conversion up to 100% in the presence of isopropanol/NaOH. 相似文献
418.
We developed a procedure to synthesize pinacolyl boronate containing stilbene derivatives and used this procedure to synthesize boron-containing combretastatin analogues. The key step involves the Wittig reaction of the ylide 4-(4,4,5,5-tetramethyl-1,3,2-dioxaboratophenyl)-methyl triphenylphosphonium bromide 11 with 3,4,5-trimethoxy benzaldehyde in the presence of tBuONa in DMF, providing 88% yield. We are now in a position to evaluate the biological activity of these derivatives as modulators of TGF-beta signaling pathways. 相似文献
419.
Bhaskar C. Das Sakkarapalayam M. Mahalingam Pranoy Mohapatra 《Tetrahedron letters》2009,50(42):5860-5863
Guanidine-containing new retinoids 1–4 were synthesized through the addition of guanidine to the activated carboxylic acids (retinoids) promoted by carbonyldiimidazole (CDI). A set of structurally and functionally diverse guanidine derivatives of retinoids were obtained in high yields (78–82%). We are in the process of studying the biological effect of these molecules on retinoic acid signaling pathways. 相似文献
420.
Carl J. Carrano Xiaoping Wang Bhaskar Poola Cynthia B. Powell Michael G. Richmond 《Journal of chemical crystallography》2009,39(11):820-826