Relation between electrooptical constants and polar tensors of CH3F,CD3F,CH3Cl,CD3Cl,CH3Br,CD3Br,CD3I,and CD3I

Infrared intensity analysis was done in two ways. In one approach, formulas connecting electrooptical parameters (eop's) and intensities were derived and, using the intensities, the former were obtained. In evaluating the eop's the intensity sum equations were used directly so that the sign ambiguity of $\text{δP}\text{δQ}$ is avoided. In the other method, polar tensors were obtained directly from intensities. The two methods have now been connected, and polar tensors have been obtained in terms of electrooptical parameters so that the former were also free from sign ambiguity of $\text{δP}\text{δQ}$. They compare well with those obtained directly from intensities. In similar connecting formulas by other authors [see, for example, P. L. Prasad, J. Chem. Phys., 69, 4403, (1978)], both polar tensors and eop's were affected by the sign ambiguity.     

Reactions of uranyl(VI) complexes of acid dihydrazides with β-diketones

Summary Uranyl(VI) complexes of malonic acid dihydrazide (MDH₂) and phthalic acid dihydrazide (PDH₂) and the products of their reactions with four -diketones have been characterised by elemental analysis and by electrical conductance, and spectral (i.r. and electronic) measurements. The MDH₂ and PDH₂ complexes UO₂(L)₂(H₂O)₂ are eight coordinate whereas the macrocyclic UO₂(L)(H₂O)₂ complexes are six coordinate. In each complex MDH₂ and PDH₂ act as bidentate liglands having the coordination sites at secondary amide-nitrogen atoms.     

Ternary Cu(II) complexes involving N-(1-naphthyl)ethylenediamine, ethylenediamine (N-N donors) and a series of amino acids (N-O? donors)

The dissociation constants for N-(l-naphthyl)ethylenediamine (NEN) and the formation constants for binary (ML) and ternary metal complexes (MLA), where M = Cu(II), L = alanine, phenylalanine, tryptophan, lysine, arginine, serine, threonine, aspartic acid or histidine and A = NEN or ethylenediamine (EN) have been determined by pH titrations and are reported at 35°C (gm = 0.2 M KNO₃). The relative stability of the ternary complexes are discussed in terms of statistical effects and the nature of ligands in the coordination sphere of the metal ion.     

Complexes of Pt(II) and Pt(IV) with disubstituted purines

Mixed-ligand complexes of Pt(II) and Pt(IV) with 2,6-diaminopurine and 6-thioguanine were synthesized and characterised. The complexes were prepared in acidic and basic media. The binding of the ligands to the metal ion varies according to the pH of the medium. Thus, in the complexes of 6-thioguanine, the ligand acts as a monodentate ligand coordinating through the neutral C₆-SH group in the acidic medium and in the basic medium as a bidentate ligand binding to the metal ion through C₆S^? and N₇, forming a five-membered chelate ring. In an acidic medium 2,6-diaminopurine forms mononuclear complexes with Pt(II) and Pt(IV) binding through N₇. In a basic medium binuclear hydroxobridged complexes are formed with Pt(IV) and the ligand is monodentate, coordinating through N₇.     

Mixed convection in non-Newtonian fluids along a vertical plate with variable surface heat flux in a porous medium

A nonsimilar boundary layer analysis is presented for the problem of mixed convection in power-law type non-Newtonian fluids along a vertical plate with power-law surface heat flux distribution. The mixed convection regime is divided into two regions, namely, the forced convection dominated regime and the free convection dominated regime. The two solutions are matched. Numerical results are presented for the details of the velocity and temperature fields. A discussion is provided for the effect of viscosity index on the surface heat transfer rate. Received on 13 October 1998     

Simultaneous heat and mass transfer under unsteady mixed convection along a vertical slender cylinder embedded in a porous medium

Unsteady laminar mixed convection flow (combined free and forced convection flow) along a vertical slender cylinder embedded in a porous medium under the combined buoyancy effect of thermal and species diffusion has been studied. The effect of the permeability of the medium as well as the magnetic field has been included in the analysis. The partial differential equations with three independent variables governing the flow have been solved numerically using a implicit finite difference scheme in combination with the quasilinearization technique. Computations have been carried out for accelerating, decelerating and oscillatory free stream velocity distributions. The effects of the permeability of the medium, buoyancy forces, transverse curvature and magnetic field on skin friction, heat transfer and mass transfer have been studied. It is found that the effect of free stream velocity distribution is more pronounced on the skin friction than on the heat and mass transfer. The permeability and magnetic parameters increase the skin friction, but reduce the heat and mass transfer. The skin friction, heat transfer and mass transfer are enhanced due to the buoyancy forces and curvature parameter. The heat transfer is strongly dependent on the viscous dissipation parameter and the Prandtl number, and the mass transfer on the Schmidt number.     

Unsteady free convection flow under the influence of a magnetic field

Summary The unsteady free convection boundary layer at the stagnation point of a two-dimensional body and an axisymmetric body with prescribed surface heat flux or temperature has been studied. The magnetic field is applied parallel to the surface and the effect of induced magnetic field has been considered. It is found that for certain powerlaw distribution of surface heat flux or temperature and magnetic field with time, the governing boundary layer equations admit a self-similar solution locally. The resulting nonlinear ordinary differential equations have been solved using a finite element method and a shooting method with Newton's corrections for missing initial conditions. The results show that the skin friction and heat transfer coefficients, andx-component of the induced magnetic field on the surface increase with the applied magnetic field. In general, the skin friction, heat transfer andx-component of the induced magnetic field for axisymmetric case are more than those of the two-dimensional case. Also they change more when the surface heat flux or temperature decreases with time than when it increases with time. The skin friction, heat transfer andx-component of the induced magnetic field are significantly affected by the magnetic Prandtl number and they increase as the magnetic Prandtl number decreases. The skin friction andx-component of the magnetic field increase with the dissipation parameter, but heat transfer decreases.

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Instationäre freie Konvektionsströmung unter dem Einfluß eines magnetischen Feldes

Übersicht Untersucht wurde die instationäre freie Konvektionsgrenzschicht am Ruhepunkt eines zweidimensionalen und achsensymmetrischen umströmten Körpers bei vorgegebenem Wärmefluß bzw. bei vorgegebener Temperatur an der Oberfläche. Das magnetische Feld wird parallel zur Oberfläche angelegt, und der Einfluß des induzierten magnetischen Feldes wurde berücksichtigt. Es stellt sich heraus, daß bei bestimmter, zeitlicher Potenzgesetzverteilung des Wärmeflusses bzw. der Temperatur und des magnetischen Feldes an der Oberfläche die geltenden Grenzschichtgleichungen örtlich eine selbstähnliche Lösung erlauben. Die sich ergebenden nichtlinearen gewöhnlichen Differentialgleichungen wurden mittels einer Finite-Element-Methode und einer Shooting-Methode mit Newtonschen Korrekturen für fehlende Anfangsbedingungen gelöst. Die Ergebnisse zeigen, daß die Oberflächenreibung und die Wärmeübergangskoeffizienten sowie diex-Komponente des induzierten magnetischen Feldes an der Oberfläche mit dem angelegten magnetischen Feld zunehmen. Im allgemeinen sind die Oberflächenreibung, der Wärmeübergang und diex-Komponente des induzierten magnetischen Feldes im achsensymmetrischen Fall größer als die entsprechenden Werte im zweidimensionalen Fall. Außerdem verändern sich diese Werte beim zeitlichen Abfallen des Wärmeflusses an der Oberfläche bzw. der Temperatur in höherem Maße als bei der zeitlichen Zunahme dieser Werte. Die Oberflächenreibung, der Wärmeübergang und diex-Komponente des induzierten magnetischen Feldes werden durch die magnetische Prandtl-Zahl erheblich beeinflußt; sie nehmen mit abfallender magnetischer Prandtl-Zahl zu. Die Oberflächenreibung und diex-Komponente des magnetischen Feldes nehmen mit dem Wärmeableitungsparameter zu, der Wärmeübergang jedoch fällt ab.

     

Synthesis and characterization of hyperbranched polyesters and polyurethane coatings

Polyurethane (PU) coatings are widely used for variety of high‐performance applications in today's coating technology. The emerging hyperbranched polymers having three‐dimensional morphology have opened a new avenue to tailor the architecture of PU coatings. The methodology followed here is based on preparation of PU coatings from hyperbranched polyester. Initially, different hyperbranched polyester polyols (HPs) were synthesized by varying the hydroxyl‐terminated precursors that is, pentaerythritol, trimethylol propane or glycerol and keeping the diacid that is, adipic acid quantity constant at various mole ratios of 1:0.6, 1:0.8, 1:0.9, and 1:1, respectively. The obtained HPs were characterized by nuclear magnetic resonance (NMR) spectroscopy, matrix‐assisted laser desorption/ionization time‐of‐flight (MALDI‐TOF)‐mass spectrometry, and Fourier transform‐infrared (FTIR) spectroscopy. The degree of branching and the quantity of different structural units present in the various HPs were calculated by integrating the quaternary carbon and carbonyl zone in ¹³C NMR spectroscopy. The extent of condensation in different HPs was also calculated from ¹H NMR spectra. Later on, NCO‐terminated PU prepolymers (NCO‐PU) were synthesized by reacting HPs with isophorone diisocyanate (IPDI) at NCO/OH ratio of 1.6:1. In the third step, the excess NCO content in the NCO‐capped PU prepolymers were reacted with atmospheric moisture and hyperbranched polyurethane (HPU) coatings were formed. The coating films were analyzed by FTIR and dynamic mechanical thermal analysis instruments. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2673–2688, 2007     

Processes developed for the separation of europium (Eu) from various resources

Europium (Eu), one of the most significant rare earth (RE) elements, has wide applications as functional material in phosphor production, majorly used in fluorescent lamps, computer monitors, televisions etc. Eu is one of the three divalent lanthanides (along with Yb and Sm) having a reduction potential higher than ?2 V. This possibility of Eu reduction is attributed to a relatively stable half-filled 4f⁷ electronic configuration, thus providing a high stabilization energy and selective recovery. But the Eu recuperation from natural minerals is either accompanied with other REs or Eu is recovered as a group of light REs. Selective recovery of Eu has sparked the progress for its reutilization through recycling of secondary resources. The perspectives of reclaiming Eu as a value added product from various sources using different pyro-hydro or hybrid techniques are discussed. The systematic research and salient findings on methods, viz., reduction, leaching, solvent extraction, as well as combined methods scaled-up to commercial scale to recover Eu, are also reported with recommendations. Thus, this comparative as well as summarized review hopes to help researchers to develop feasible processes for Eu recovery.