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51.
H. Yoshioka H. Kurosaki H. Yoshioka 《Journal of Radioanalytical and Nuclear Chemistry》1999,239(1):217-220
The aqueous solutions of 5,5-dimethyl-1-pyrroline N-oxide (DMPO) containing various amount of (-)-epigallocatechin gallate
(EGCg) were mixed with tritiated water, then frozen and β-ray irradiatedin situ for 90 days at −80°C. ESR spectra were measured as a function of time after melting the sample at room temperature. The intensity
of the hydroxyl (OH)_ radical adduct, DMPO-OH, was obtained by the extrapolation to zero time. The ratio of the reaction rate
constants of the OH radical with EGCg and DMPO,k
EGCg/k
DMPO, was obtained kinetically. The result was compared with the case of DNA and EGCg in tritiated water, in order to make clear
the mechanism of the protection of DNA from the radiation-induced scission with EGCg. 相似文献
52.
Yuzuru Eguchi 《国际流体数值方法杂志》2003,41(8):881-904
A new regularization method is proposed for the Galerkin approximation of the incompressible Navier–Stokes equations with Q1/P0 element, by newly introducing a square‐type linear form into the variational divergence‐free constraint regularized with the global pressure jump (GPJ) method. The addition of the square‐type linear form is intended to eliminate the hydrostatic pressure mode appearing in confined flows, and to make the discretized matrix positive definite and then non‐singular without the pressure pegging trick. Effects of the free parameters for the regularization on the solutions are numerically examined with a 2‐D driven cavity flow problem. Furthermore, the convergences in the conjugate gradient iteration for the solution of the pressure Poisson equation are compared among the mixed method, the GPJ method and the present method for both leaky and non‐leaky 3‐D driven cavity flows. Finally, the non‐leaky 3‐D cavity flows at different Re numbers are solved to compare with the literature data and to demonstrate the accuracy of the proposed method. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
53.
Yuzuru Eguchi 《国际流体数值方法杂志》2002,39(11):1037-1052
In the present paper, the author shows that the predictor/multi‐corrector (PMC) time integration for the advection–diffusion equations induces numerical diffusivity acting only in the streamline direction, even though the equations are spatially discretized by the conventional Galerkin finite element method (GFEM). The transient 2‐D and 3‐D advection problems are solved with the PMC scheme using both the GFEM and the streamline upwind/Petrov Galerkin (SUPG) as the spatial discretization methods for comparison. The solutions of the SUPG‐PMC turned out to be overly diffusive due to the additional PMC streamline diffusion, while the solutions of the GFEM‐PMC were comparatively accurate without significant damping and phase error. A similar tendency was seen also in the quasi‐steady solutions to the incompressible viscous flow problems: 2‐D driven cavity flow and natural convection in a square cavity. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
54.
Naoto Sugimoto Seiji Fukushima Yasuhiro Suzuki Yoshihisa Sakai Hiromasa Tanobe Takeshi Kurosaki Kazuto Noguchi Kimio Oguchi Hiromu Toba 《光学学报》2003,23(Z1)
A new generation of network interface card for fiber-to-the-desktop has been fabricated. The fabricated card is PC-card size and suitable for notebook PCs. It could become the key element in the coming optical Ethernet age. 相似文献
55.
Akihito Kitajima Takeshi Kashirajima Takao Minamizawa Hiroyasu Sato Kazuo Iwaki Taisuke Ueda Yoshio Kimura Toshimasa Toyo'oka Tamio Maitani Rieko Matsuda Yuzuru Hayashi 《Analytical sciences》2007,23(9):1077-1080
The stochastic properties of baseline noise in HPLC systems with a UV photo-diode array, photo-multiplier and gamma-ray detector were examined by dividing the noise into auto-correlated random process (Markov process) and an independent process (white noise). The present work focused on the effect of the stochastic noise properties on a theoretical estimation of the standard deviation (SD) of area measurements in instrumental analyses. An estimation theory, called FUMI theory (Function of Mutual Information), was taken as an example. A computer simulation of noise was also used. It was shown that the reliability (confidence intervals) of theoretical SD estimates mainly depends on the following factors: the ratio of the white noise and Markov process occurring in the baselines; the number of data points used for the estimation; the width of a target peak for which the SD is estimated. 相似文献
56.
Hiromasa Kurosaki Rakesh K Sharma Masami Otsuka Masafumi Goto 《Analytical sciences》2003,19(4):647-648
The structure of 7,8-dihydroxy-4-methylcoumarin was determined by an X-ray diffraction method. The compound crystallized in the triclinic space group P1, Z = 2, with a = 7.631(2), b = 9.456(5), c = 7.075(3)A, alpha = 103.13(3), beta = 91.84(3), gamma= 68.21(3) degrees, and V= 460.9(3)A3. The X-ray crystal structure was also compared with those of 5,7-dihydroxy-4-methylcoumarin and 7-hydroxy-4-methylcoumarin. 相似文献
57.
Yuzuru Hayashi Rieko Matsuda Katsutoshi Ito Waka Nishimura Kazuhiro Imai Masako Maeda 《Analytical sciences》2005,21(2):167-169
This paper theoretically derives a general rule that while the slope of the semi-logarithmic plot (Y vs. log X) of a calibration curve varies depending on analyte concentration, X, the slope takes a specific value at the detection limit (L(D)). This rule holds good irrespective of the shape of the calibration curve (linear or non-linear) and in this paper, is applied to competitive ELISA (enzyme linked immunosorbent assay). The following relationship is deduced: slope of log-dose B/B0 at L(D) = [relative standard deviation (RSD) of blank responses] / 0.13. The L(D) obtained from the above-mentioned slope corresponds to the dose at which the RSD of dose estimates is 0.3 (= 30%). A commercial kit for 17alpha-hydroxyprogesterone is taken as an example. 相似文献
58.
59.
Summary The previously proposed theory on the critical micelle concentration is extended and revised, considering the effects of coexisting
small ions. Using the theory of the adsorption equilibrium instead of that of the flat electrical double layer, we obtain
an equation for the salt effect on the c. m. c., which is of somewhat different form from the usual experimental formula.
It is pointed out that the activities of ions should be used instead of the stoichiometric concentrations. Comparisons are
made with available experimental works and the agreement is shown to be good.
Zusammenfassung Die früher ver?ffentlichte Theorie (1) über die kritische Mizellkonzentration wurde erweitert und verbessert, indem wir die Wirkung der gleichzeitig anwesenden Ionen in Betracht zogen. Um den Effekt der Salze auf die kritische Mizellkonzentration zu untersuchen, benutzen wir die Theorie des Adsorptionsgleichgewichtes anstatt der Theorie der ebenen elektrischen Doppelschicht, und unsere Theorie führte zu einer von den üblichen experimentellen Formeln etwas verschiedenen Gleichung. Es wurde gezeigt, da? die Aktivit?t der Ionen anstatt der st?chiometrischen Konzentration gebraucht werden mu?. Unsere Theorie steht in guter übereinstimmung mit existierenden experimentellen Resultaten.相似文献
60.
A new ichthyotoxic toxin was isolated from the unialgal culture of the deleterious Florida red tide organism,
Davis (Syn.
), and its structure was elucidated. 相似文献