全文获取类型
收费全文 | 1260篇 |
免费 | 36篇 |
国内免费 | 7篇 |
专业分类
化学 | 898篇 |
晶体学 | 13篇 |
力学 | 17篇 |
数学 | 154篇 |
物理学 | 221篇 |
出版年
2022年 | 8篇 |
2021年 | 5篇 |
2020年 | 9篇 |
2019年 | 10篇 |
2018年 | 5篇 |
2017年 | 18篇 |
2016年 | 26篇 |
2015年 | 18篇 |
2014年 | 26篇 |
2013年 | 64篇 |
2012年 | 46篇 |
2011年 | 78篇 |
2010年 | 37篇 |
2009年 | 49篇 |
2008年 | 67篇 |
2007年 | 89篇 |
2006年 | 82篇 |
2005年 | 92篇 |
2004年 | 78篇 |
2003年 | 58篇 |
2002年 | 64篇 |
2001年 | 17篇 |
2000年 | 22篇 |
1999年 | 20篇 |
1998年 | 13篇 |
1997年 | 18篇 |
1996年 | 14篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1992年 | 16篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 10篇 |
1988年 | 10篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 18篇 |
1984年 | 17篇 |
1983年 | 12篇 |
1982年 | 16篇 |
1981年 | 12篇 |
1980年 | 20篇 |
1979年 | 16篇 |
1978年 | 9篇 |
1977年 | 7篇 |
1976年 | 9篇 |
1975年 | 14篇 |
1974年 | 9篇 |
1973年 | 8篇 |
1971年 | 4篇 |
排序方式: 共有1303条查询结果,搜索用时 15 毫秒
81.
Relationship between apparent diffusion coefficient and signal intensity in endometrial and other pelvic cysts 总被引:8,自引:0,他引:8
We evaluated whether apparent diffusion coefficient (ADC) value is more useful than signal intensity for differentiating endometrial cysts from other pelvic cysts. In an in vitro study, signal intensity and diffusion coefficients were measured in whole blood phantoms in which blood oxidation was gradually increased and concentration subsequently diluted. Although both signal intensity and diffusion value were largely affected by blood concentration, diffusion value was almost independent of blood oxidation and red blood cell lysis-related diminution of magnetic nonhomogeneity, both factors greatly affecting signal intensity on T1- and T2-weighted images. In an in vivo study, differentiation between endometrial and other pelvic cysts was attempted by means of ADC values and signal ratios of cysts to muscles on T1- and T2-weighted images (T1- and T2-ratios). Endometrial cysts tended to show lower T2-ratios, higher T1-ratios, and lower ADC values than other pelvic cysts (p < 0.001). However, ADC values were not correlated with T1- and T2-ratios (p < /0.15/). The ability of ADC value to discriminate between these two groups (discriminant rate, 91.4%) was higher than that of T2-ratio (71.4%) or T1-ratio (88.6%). If combined, ADC and T1-ratio (or T2-ratio) showed higher discriminant rate (94.3%) than the combination of T1- and T2 ratios (88.6%). ADC value might be useful for evaluating the blood concentration of a cystic lesion, because diffusion value is more closely related to blood concentration and almost independent of blood oxidation and red blood cell lysis that largely affect signal intensity. 相似文献
82.
In this paper we investigate linear three-term recurrence formulae with sequences of integers (T(n))n?0 and (U(n))n?0, which are ultimately periodic modulo m, e.g.
83.
Prof. Dr. Yasuchika Hasegawa Takafumi Matsui Dr. Yuichi Kitagawa Dr. Takayuki Nakanishi Dr. Tomohiro Seki Prof. Dr. Hajime Ito Prof. Dr. Yuta Nakasaka Prof. Dr. Takao Masuda Prof. Dr. Koji Fushimi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(53):12308-12315
Oxygen-sensitive and near-infrared (NIR) luminescent YbIII coordination polymers incorporating ligands based on pyrene derivatives were synthesized: YbIII–TBAPy and YbIII–TIAPy (TBAPy: 1,3,6,8-tetrakis(p-benzoate)pyrene; TIAPy: 1,3,6,8-tetrakis(3,5-isophthalic acid)pyrene). The coordination structures of these materials have been characterized by means of electrospray ionization mass spectrometry, X-ray diffraction analysis, and thermogravimetric analysis. Moreover, the porous structure of YbIII–TIAPy has been evaluated by measuring its N2 adsorption isotherm. The NIR luminescence properties of YbIII–TBAPy and YbIII–TIAPy have been examined by acquiring emission spectra and determining emission lifetimes under air or argon and in vacuo. YbIII–TIAPy exhibited high thermal stability (with a decomposition temperature of 400 °C), intense luminescence (with an emission quantum yield under argon of 6.6 %), and effective oxygen-sensing characteristics. These results suggest that NIR luminescent YbIII coordination polymers prepared using pyrene derivatives could have applications in novel thermo-stable oxygen sensors. 相似文献
84.
Silhanek AV Ebihara T Harrison N Jaime M Tezuka K Fanelli V Batista CD 《Physical review letters》2006,96(20):206401
We show that antiferromagnetism in lightly (approximately 8%) Sn-doped CeIn3 terminates at a critical field mu0H(c) = 42 +/- 2 T. Electrical transport and thermodynamic measurements reveal the effective mass m* not to diverge, suggesting that cubic CeIn3 is representative of a critical spin-density wave (SDW) scenario, unlike the local quantum critical points reported in anisotropic systems such as CeCu(6-x)Au(x) and YbRh2Si(2-x)Ge(x). The existence of a maximum in m* at a lower field mu0H(x) = 30 +/- 1 T may be interpreted as a field-induced crossover from local moment to SDW behavior as the Néel temperature falls below the Fermi temperature. 相似文献
85.
Koji Takagi Tsuyoshi Nakagawa Hidenobu Takao 《Journal of polymer science. Part A, Polymer chemistry》2010,48(1):91-98
Two arylenevinylene compounds bearing the cyano group at α‐position ( 6 ) and β‐position ( 9 ) from the dialkoxylphenylene unit were synthesized, in which the molecular termini were functionalized with 3‐bromocarbazole. The Suzuki coupling copolymerization of these compounds with 1,4‐bis[(3′‐bromocarbazole‐9′‐yl)methylene]‐2,5‐didecyloxybenzene and 9,9‐dihexylfluorene‐2,7‐bis(boronic acid) was carried out to obtain copolymers ( cp67 and cp97 ) containing the cyano‐substituted arylenevinylene fluorophore of 7 mol %. Model compounds ( 6 ′ and 9 ′) corresponding to the arylenevinylene fluorophore were also prepared. The UV spectra of copolymers resembled that of homopolymer hp with no arylenevinylene segment in both CHCl3 solution and thin film. The emission maxima of copolymers in CHCl3 (394 nm) agreed with that of homopolymer indicating that the emission bands originated from the carbazole‐fluorene‐carbazole segment. The emission maximum wavelength of copolymer cp67 in thin film (477 nm) indicated fluorescence from the cyano‐substituted arylenevinylene fluorophore because of the occurrence of fluorescence resonance electron transfer. In contrast, copolymer cp97 showed fluorescence at 528 nm to suggest the formation of a new emissive species such as a charge‐transfer complex (exciplex). © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 91–98, 2010 相似文献
86.
Nine new secoiridoid glucosides from Jasminum nudiflorum 总被引:2,自引:0,他引:2
Takenaka Y Tanahashi T Taguchi H Nagakura N Nish T 《Chemical & pharmaceutical bulletin》2002,50(3):384-389
Phytochemical study of the leaves of Jasminum nudiflorum has led to the isolation of nine new secoiridoid glucosides, jasnudiflosides F-L (1-7), nudifloside D (8) and isooleoacteoside (9). The structures of these compounds were elucidated on the basis of chemical and spectroscopic evidence. 相似文献
87.
Sato S Komoto T Kanamaru Y Kawamoto N Okada T Kaiho T Mogi K Morimoto S Umehara N Koda T Miyashita A Sakamoto T Niino Y Oka T 《Chemical & pharmaceutical bulletin》2002,50(2):292-297
New muq-opioid receptor (MOR) agonists containing 4-hydroxypiperidine, piperidine and piperazine moieties were synthesized and evaluated to find a peripheral opioid analgesic. Among the synthesized compounds, 12-[1-[3-(N,N-dimethylcarbamoyl)-3,3-diphenylpropyl]-4-hydroxypiperidin-4-yl]phenoxy]acetic acid (8: SS620) having phenoxyacetic acid and 4-hydroxypiperidine moieties showed the highest agonist potency on the MOR in an isolated guinea-pig ileum preparation, and it also had selectivity to the human MOR expressed in Chinese hamster ovary (CHO)-K1 cells compared with the same types of delta- and kappa-opioid receptors (DOR and KOR). In addition, compound 8 showed a 10 times more potent MOR agonist activity than loperamide. Furthermore, compound 8 showed a peripheral analgesic activity in vivo screening on rat. 相似文献
88.
Homogeneous ZnO Nanoparticles by Flame Spray Pyrolysis 总被引:2,自引:0,他引:2
Zinc oxide (ZnO) nanoparticles were made by flame spray pyrolysis (FSP) of zinc acrylate–methanol–acetic acid solution. The effect of solution feed rate on particle specific surface area (SSA) and crystalline size was examined. The average primary particle diameter can be controlled from 10 to 20nm by the solution feed rate. All powders were crystalline zincite. The primary particle diameter observed by transmission electron microscopy (TEM) was in agreement with the equivalent average primary particle diameter calculated from the SSA as well as with the crystalline size calculated from the X-ray diffraction (XRD) patterns for all powders, indicating that the primary particles were rather uniform in diameter and single crystals. Increasing the solution feed rate increases the flame height, and therefore coalescence and/or surface growth was enhanced, resulting in larger primary particles. Compared with ZnO nanoparticles made by other processes, the FSP-made powder exhibits some of the smallest and most homogeneous primary particles. Furthermore, the FSP-made powder has comparable BET equivalent primary particle diameter with but higher crystallinity than sol–gel derived ZnO powders. 相似文献
89.
The relationship between cosmological solutionsof five-dimensional Space-Time-Matter (STM) theory anda Generalized Scalar-Tensor (GST) theory is investigatedin which the cosmological term Lambda depends not only on a scalar field but also onits time derivative
.Identification of these solutions allows us to solve forthe functional form of the cosmological term, and mayhave relevance for the early Universe. 相似文献
90.
Takao Yamazaki 《Proceedings of the American Mathematical Society》1999,127(5):1269-1274
For an element of the Brauer group of a curve over a local field, we define the ``Swan conductor' of , which measures the wildness of the ramification of . We give a relation between and Swan conductors for Brauer groups of henselian discrete valuation fields defined by Kato.