全文获取类型
收费全文 | 252篇 |
免费 | 5篇 |
专业分类
化学 | 106篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 32篇 |
物理学 | 114篇 |
出版年
2022年 | 3篇 |
2021年 | 4篇 |
2019年 | 3篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 4篇 |
2013年 | 7篇 |
2012年 | 3篇 |
2011年 | 7篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 14篇 |
2007年 | 7篇 |
2006年 | 12篇 |
2005年 | 6篇 |
2004年 | 6篇 |
2003年 | 8篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 8篇 |
1999年 | 8篇 |
1998年 | 3篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 8篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1978年 | 3篇 |
1972年 | 4篇 |
1970年 | 5篇 |
1968年 | 3篇 |
1967年 | 2篇 |
1966年 | 4篇 |
1959年 | 1篇 |
1957年 | 2篇 |
1956年 | 1篇 |
1930年 | 1篇 |
1924年 | 2篇 |
1919年 | 1篇 |
1875年 | 1篇 |
排序方式: 共有257条查询结果,搜索用时 15 毫秒
1.
Effect of nickel coating on electrochemical performance of graphite anodes for lithium ion batteries
Among the different materials often studied and proposed as negative electrodes for lithium-ion batteries, graphite anodes
are the most used in commercial batteries. For this study, synthetic graphite was tested. During the first discharge 0.2 Li
ions were consumed for the formation of the SEI film and the capacity reaches about 387 mAh/g. But at the end of the first
charge only 72% of the initial charge was recovered (the reversible capacity is about 279 mAh/g). In order to improve this
performance we have deposited metallic nickel on graphite with the intention to obtain a homogeneous thin layer able to modify
the nature of the SEI film, to allow the diffusion of lithium ions through the protective layer, and also to increase the
performance of graphite electrodes. The results show a decrease of the irreversible capacity loss (16% instead of 28% for
pure graphite electrodes) as well as better cycleability for a nickel-deposited graphite electrode with only 11% weight ratio
of nickel. On the other hand, an increase of the nickel content decreases this performance. 相似文献
2.
Atiya MS Chiang I Frank JS Haggerty JS Ito MM Kycia TF Li KK Littenberg LS Stevens A Strand RC Louis WC Akerib DS Marlow DR Meyers PD Selen MA Shoemaker FC Smith AJ Azuelos G Blackmore EW Bryman DA Felawka L Kitching P Kuno Y Macdonald JA Numao T Padley P Poutissou J Poutissou R Roy J 《Physical review letters》1990,65(1):21-24
3.
Kenji Yokota Hideo Tomioka Teruyuki Ono Fumimasa Kuno 《Journal of polymer science. Part A, Polymer chemistry》1972,10(5):1335-1343
The sensitization effect of tertiary amines on the photopolymerization of methyl methacrylate was studied. N,N-Dimethylbenzylamine, triethylamine, and N,N-dimethylaniline increased the rate of polymerization in this order, but pyridine did not show any effect. A free-radical mechanism was confirmed by the tacticity of polymer, the retarding effect of hydroquinone, and the copolymer composition with styrene. On the basis of the detailed kinetics of the sensitized polymerization and the ultraviolet spectra of the reaction mixtures, a sensitization mechanism is proposed, in which the excited monomer and the amine form a complex and generate an initiating radical. 相似文献
4.
5.
6.
G. Imokawa S. Akasaki O. Kuno M. Zama M. Kawai Y. Minematsu 《Journal of Dispersion Science and Technology》2013,34(4-5):617-641
In order to clarify the roles of lipids in the water-holding property of stratum corneum, the forearm skin of healthy male volunteers was treated with acetone/ether (1/1) or sodium dodecyl sulfate (5%) for 1-30 min. A prolonged treatment period of 5-30 min produced a chapped and scaly appearance of the stratum corneum without any inflammatory reactions. Under these conditions, there was a marked decrease in the water-holding capacity of the stratum corneum accompanied by a selective loss of stratum corneum lipids such as cholesterol, cholesterol esters, and sphingolipids. Two daily applications of the isolated stratum corneum lipids to experimentally induced dry skins caused a significant increase of conductance, accompanied by a marked improvement in the level of scaling. Meanwhile, the isolated sebaceous lipids exhibited no significant recovery in both the conductance value and the scaling. Out of chroma-tographically separated fractions of the stratum corneum lipids, topical applications of ceramide fraction induced the highest increase in the conductance value. Topical applications of synthesized pseudo-ceramides also showed a significant recovery of the water-retaining properties accompanied by an improvement in the scaling only when the polar group has an amide bond in the major linkage. Analysis of the alkyl chain structures has revealed that a structural requirement for the recovery of the water retaining capacity is the presence of saturated-straight alkyl chains, not unsaturated or branched alkyl chains. These structural characteristics required for water-retaining function also paralleled their capacity to form multiconcentric lamellae vesicles in vitro which is also capable of acquiring bound water as shown by DSC thermograms. The present study suggests that ceramides with relatively shorter alkyl chain length serve as a water modulator in the multi-lipid bilayers through the stratum corneum. 相似文献
7.
8.
W. Schleich 《Nachrichten aus der Chemie》1988,36(11):1226-1226
9.
10.
Atiya MS Chiang IH Frank JS Haggerty JS Ito MM Kycia TF Li KK Littenberg LS Sambamurti A Stevens A Strand RC Louis WC Akerib DS Marlow DR Meyers PD Selen MA Shoemaker FC Smith AJ Blackmore EW Bryman DA Felawka L Kitching P Konaka A Kuno Y Macdonald JA Numao T Padley P Poutissou JM Poutissou R Roy J Soluk R Turcot AS 《Physical review letters》1993,70(17):2521-2524