Click chemistry for the synthesis of 5-substituted 1H-tetrazoles from boron-azides and nitriles

A novel and metal free catalysis of synthesizing 5-substituted 1H-tetrazoles through 1,3-dipolar cycloaddition of boron-azides and nitriles is reported with broad substrate scope and excellent yields.     

Rapid determination of Pu isotopes for decommission concrete samples by inductively coupled plasma mass spectrometry

Journal of Radioanalytical and Nuclear Chemistry - Plutonium is one of the key radionuclides in nuclear decommission. In this study, a rapid method was developed to analyze Pu for concrete samples...     

基于LIBS及时间分辨特征峰的激光除漆机理研究

激光除漆是一种高效、清洁的新型清洗技术，对激光除漆物理过程和机理的研究是该技术发展的关键。基于LIBS技术，测量得到油漆去除过程中等离子体的发光光谱，计算出油漆样品去除前后等离子体的电子密度和温度，研究了油漆中特征元素对应的光谱特征峰强度随时间的变化情况。结果表明，随着激光作用脉冲数量的增加，油漆去除深度逐渐增加，等离子体电子密度和温度在将漆去除干净的最后几个脉冲作用时呈下降趋势。油漆中Ti元素的所对应的特征峰信号持续时间为2个μs，油漆去除前后信号强度呈现跳跃减少，该现象可用于快速、准确、实时的判断油漆去除情况。     

Calibration of the complex matrix effects on the sampling of polycyclic aromatic hydrocarbons in milk samples using solid phase microextraction

Solid phase microextraction (SPME), a simple, fast and promising sampling technique, has been widely used for complex sample analysis. However, complex matrices could modify the absorption property of coatings as well as the uptake kinetics of analytes, eventually biasing the quantification results. In the current study, we demonstrated the feasibility of a developed calibration method for the analysis of polycyclic aromatic hydrocarbons (PAHs) in complex milk samples. Effects of the complex matrices on the SPME sampling process and the sampling conditions were investigated. Results showed that short exposure time (pre-equilibrium SPME, PE-SPME) could increase the lifetime of coatings, and the complex matrices in milk samples could significantly influence the sampling kinetics of SPME. In addition, the optimized sampling time, temperature and dilution factor for PAHs were 10 min, 85 °C and 20, respectively. The obtained LODs and LOQs of all the PAHs were 0.1–0.8 ng/mL and 1.4–4.7 ng/mL, respectively. Furthermore, the accuracy of the proposed PE-SPME method for milk sampling was validated by the recoveries of the studied compounds in two concentration levels, which ranged from 75% to 110% for all the compounds. Finally, the proposed method was applied to the screening of PAHs in milk samples.