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排序方式: 共有641条查询结果,搜索用时 15 毫秒
31.
Sarata Kumar Sahoo Yuji Nakamura Kunio Shiraishi Akimasa Masuda 《International journal of environmental analytical chemistry》2013,93(12):919-926
A chemical and mass-spectrometric procedure for uranium isotopic analysis using a thermal ionisation mass spectrometer equipped with a Wide Aperture Retardation Potential energy filter has been developed and applied to uranium isotopic measurements for various soil samples. Soil samples were digested using a microwave digestor. Uranium was isolated from soil samples by the chemical separation procedure based on the use of anion-exchange resin and UTEVA extraction chromatography column. The isotope ratios were measured for two certified reference materials by using a VG Sector 54-30 thermal ionisation mass spectrometer in dynamic mode with Faraday cup and Daly ion counting system. Replicates of standard reference materials showed excellent analytical agreement with established values supporting the reliability and accuracy of the method. Precision of the 235U/238U ratio was achieved by a correction factor of 0.22% amu as a function of ion-beam intensity with sample loads of around 250?ng of U. The resulting reproducibility for standards and soil samples was better than 0.2% at two standard deviations (SD). Uranium isotopic compositions have been determined in several reference soil samples such as Buffalo river sediment, NIST 2704, river sediment SRM 4350b and ocean sediment NIST-4357 and a Chernobyl soil sample. There was a significant deviation from the natural uranium in comparison with Chernobyl soil samples. 相似文献
32.
Katsuyuki Ogura Kunio Sanada Kazumasa Takahashi Hirotada Iida 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):83-87
Abstract An efficient preparation of a 3-methylthio-2-alkanone (1) has been realized by the reaction of a 3-alkyl-2,4-pentanedione (8) with one mol-equiv of S-methyl methanethiosulfonate (4) in the presence of excess EtONa in EtOH. Furthermore, treatment of 8 with 4 and K2CO3 in refluxing acetone, followed by addition of MeOH and heating the resulting mixture, gave 1 in a high yield. These methods were applied to synthesis of pseudoionone. 相似文献
33.
Koichiro Yonetake Kunio Maruyama Jun-Ichi Sugiyama Toru Masuko Mitsuru Ueda 《Journal of polymer science. Part A, Polymer chemistry》1994,32(8):1415-1421
Poly[4-(4-hydroxyphenoxy) benzoic acid] was prepared by the bulk polycondensation of 4-(4-acetoxyphenoxy) benzoic acid. Polycondensation was conducted at 350°C for 3 h under a reduced pressure of 0.1 mmHg and gave a polymer with X?n of 255. The polymer was characterized by elemental analysis, IR spectroscopy, differential scanning calorimetry, and wide-angle X-ray measurement. The crystal/nematic and nematic/isotropic phase transition temperatures of polymer, which depend on the molecular weight, were observed at about 300°C and 410°C, respectively. The polymers with low molecular weights showed nematic textures above 300°C. This nematic/isotropic phase transition temperature is lower than that of poly (4-hydroxybenzoic acid). This thermal behavior of polymer comes from ether units, which increase the flexibility (the rotation or torsion of skeletal bonds) of the polymer chain. © 1994 John Wiley & Sons, Inc. 相似文献
34.
Comparison of PAMAM-Au and PPI-Au nanocomposites and their catalytic activity for reduction of 4-nitrophenol 总被引:4,自引:0,他引:4
Dendrimer-Au nanocomposites are prepared in aqueous solutions using poly(amidoammine)dendrimers (PAMAM) (generation 2, 3, and 5) and poly(propyleneimine)dendrimers (PPI)(generation 2, 3, and 4) by wet chemical NaBH(4) method. The Au nanoparticles thus obtained are 2-4 nm in diameter for both dendrimers and no generation dependence on the particle size is observed, whereas the generations of the dendrimers are increased as stabilization of Au-nanoparticles is achieved with lower dendrimer concentrations. Studies of the reduction reaction of 4-nitrophenol using these nanocomposites show that the rate constants for the PAMAM dendrimers (generations 2 and 3) are higher than those for the PPI dendrimers (generations 2 and 3), while a distinct difference in the rate constants is not seen for the PAMAM dendrimer (generation 5) or the PPI dendrimer (generation 4). In addition, the rate constants for the reduction of 4-nitrophenol involving all the dendrimers decrease with increases in dendrimer concentrations. 相似文献
35.
The flocculation behavior of anionic and cationic latex dispersions induced by addition of ionic surfactants with different polarities (SDS and cetyltrimethylammonium bromide (CTAB)) have been evaluated by rheological measurements. It was found that in identical polar surfactant systems with particle surfaces of SDS + anionic lattices and CTAB + cationic lattices, a weak and reversible flocculation has been observed in a limited concentration region of surfactant, which was analyzed as a repletion flocculation induced by the volume-restriction effect of the surfactant micelles. On the other hand, in oppositely charged surfactant systems (SDS + cationic lattices and CTAB + anionic lattices), the particles were flocculated strongly in a low surfactant concentration region, which will be based on the charge neutralization and hydrophobic effects from the adsorbed surfactant molecules. After the particles stabilized by the electrostatic repulsion of adsorbed surfactant layers, the system viscosity shows a weak maximum again in a limited concentration region. This weak maximum was influenced by the shear rate and has a complete reversible character, which means that this weak flocculation will be due to the depletion effect from the free micelles after saturated adsorption. 相似文献
36.
Kunio Urushido Akira Matsumoto Masayoshi Oiwa 《Journal of polymer science. Part A, Polymer chemistry》1981,19(2):245-256
Radical copolymerizations of methyl allyl maleate (MAM) and methyl allyl fumarate (MAF) with styrene (St) are carried out in bulk using AIBN as an initiator at 60°C, and their copolymerization behaviors are compared in detail. The different rate features are observed with each other; thus in the MAF-St copolymerization the rate was quite enhanced and, also, the maximum rate was found at the molar ratio of 1:1 in the monomer feed, whereas no maximum phenomenon of the rate was apparent for the MAM—St copolymerization. The copolymerizability of MAF with St was quite high, whereas that of MAM was very poor. The cyclization of MAM or MAF was hindered by the highly reactive St monomer. These results are discussed in terms of the formation of the charge—transfer complex between MAF and St and, furthermore, the cyclocopolymerization kinetics involving the 17 elementary reactions as the propagation reactions. 相似文献
37.
Samuel A. Delp Colleen Munro-Leighton Chetna Khosla Joseph L. Templeton Nikki M. Alsop T. Brent Gunnoe Thomas R. Cundari 《Journal of organometallic chemistry》2009,694(9-10):1549-1556
Using 2D proton-coupled gHSQC pulse sequences in addition to 1D 15N NMR experiments of 15N labeled systems, 15N NMR chemical shifts of a range of transition metal amido and amine complexes were determined. Tungsten(II), ruthenium(II), platinum(IV) and copper(I) complexes with aniline and their anilido variants were studied and compared to free aniline, lithium anilido and anilinium tetrafluoroborate. Upon coordination of aniline to transition metals, upfield chemical shifts of 20–60 ppm were observed. Deprotonation of the amine complexes to form amido complexes resulted in downfield chemical shifts of 40–60 ppm for all of the complexes except for the tungsten d4 system. For the tungsten(II) complexes, the cationic aniline complex displayed a downfield shift of approximately 56 ppm relative to the neutral anilido complex. The change in chemical shift for amine to amido conversion is proposed to depend on the ability of the amido ligand to π-bond with the metal center, which influences the magnitude of the paramagnetic screening term. 相似文献
38.
Hyoe Hatakeyama Shigeo Hirose Tatsuko Hatakeyama Kunio Nakamura Ken Kobashigawa Noriyuki Morohoshi 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(4):743-750
Abstract Polyurethane (PU) sheets and foams having plant components in their network were prepared by using the following procedure. Polyethylene glycol (PEG) was mixed with one of the following; molasses, lignin, woodmeal, or coffee grounds. The mixture obtained was reacted with diphenylmethane diisocyanate (MDI) at room temperature, and precured PUs were prepared. The precured PUs were heat-pressed and PU sheets were obtained. In order to make PU foam, the above mixture was reacted with MDI after the addition of plasticizer, surfactant (silicone oil), catalyst (di-n-butyltin dilaurate), and droplets of water under vigorous stirring. The glass transition temperature, tensile and compression strengths, and Young's modulus of the PU sheets and foams increased with an increasing amount of plant components. This suggests that saccharide and lignin residues act as hard segments in PUs. It was found that the PUs obtained were biodegradable in soil. The rate of biodegradation of the PUs derived from molasses and coffee grounds was between that of cryptomeria (Cryptomeria japonica) and beech (Fagus sieboldi). 相似文献
39.
Makoto Hatakeyama Takako Mashiko Hisanao Hazama Kunio Awazu Masanori Tachikawa 《International journal of quantum chemistry》2013,113(2):125-129
To investigate the correlation between the wavelength dependence of ionization threshold fluence of target molecule in matrix‐assisted laser desorption/ionization by infrared (IR) laser and the IR absorption spectrum of matrix molecule, we have analyzed the IR absorption spectra of four matrix molecules using density functional theory and correlated ab initio molecular orbital method. The calculated IR absorption spectra of the isolated molecules showed more qualitative correlation with the wavelength dependence of ionization threshold fluence than those of the solid state structures. We can consider that a portion of matrix molecules lost the ordered crystal structure and that the transition to the diluted or isolated state occurred at the early process of IR laser irradiation. © 2012 Wiley Periodicals, Inc. 相似文献
40.