全文获取类型
收费全文 | 1724篇 |
免费 | 41篇 |
国内免费 | 17篇 |
专业分类
化学 | 1378篇 |
晶体学 | 20篇 |
力学 | 20篇 |
数学 | 89篇 |
物理学 | 275篇 |
出版年
2022年 | 10篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 10篇 |
2017年 | 14篇 |
2016年 | 31篇 |
2015年 | 26篇 |
2014年 | 17篇 |
2013年 | 66篇 |
2012年 | 59篇 |
2011年 | 80篇 |
2010年 | 41篇 |
2009年 | 38篇 |
2008年 | 79篇 |
2007年 | 89篇 |
2006年 | 66篇 |
2005年 | 79篇 |
2004年 | 95篇 |
2003年 | 79篇 |
2002年 | 91篇 |
2001年 | 52篇 |
2000年 | 37篇 |
1999年 | 31篇 |
1998年 | 24篇 |
1997年 | 18篇 |
1996年 | 18篇 |
1995年 | 20篇 |
1994年 | 14篇 |
1993年 | 19篇 |
1992年 | 30篇 |
1991年 | 26篇 |
1990年 | 26篇 |
1989年 | 24篇 |
1988年 | 20篇 |
1987年 | 19篇 |
1986年 | 28篇 |
1985年 | 31篇 |
1984年 | 31篇 |
1983年 | 19篇 |
1982年 | 34篇 |
1981年 | 31篇 |
1980年 | 28篇 |
1979年 | 28篇 |
1978年 | 28篇 |
1977年 | 25篇 |
1975年 | 15篇 |
1974年 | 21篇 |
1973年 | 16篇 |
1972年 | 13篇 |
1968年 | 9篇 |
排序方式: 共有1782条查询结果,搜索用时 31 毫秒
161.
Kunio Yasue 《International Journal of Theoretical Physics》1979,18(12):861-913
The present status of the work on the application of the stochastic quantization procedure is reviewed. A compact mathematical introduction to the basic notions of random processes such as Markov processes, Martingales and Fokker-Planck equations is presented. The stochastic quantization procedure is explained in much detail and it is found to possess remarkable features which can not be achieved within the conventional framework of quantum theory. This admits us to give systematic analyses of irreversible quantum dynamics of dissipative systems and the vacuum tunneling phenomena in non-Abelian gauge theory 相似文献
162.
Photolysis of tris(trimethylsilyl)phenylsilane, in alcohols yielded 1-aikoxy-1-phenyl-2, 2,2-trimethyldisilane, dialkoxyphenylsilane, hexamethyldistlane, and trimethylstlane as major products. The formation of the products was explained by a mechanssm which included the consecutive generatinn of phenyltrimethylsilylsilyleses and alkoxyphenylsilylenes. 相似文献
163.
Tamotsu Kamiya Kuniyuki Goto Isao Shinohara 《Journal of polymer science. Part A, Polymer chemistry》1979,17(2):561-569
The ionene polymers were prepared by the Menshutkin reaction of α,ω-dibromoalkane (n) with triethylenediamine (TDA) or 4,4′-bipyridil (BP). Resistivities (p) and activation energies of conduction (Ea) were measured for the polymeric 7,7,8,8-tetracyanoquinodimethan (TCNQ) salts with these ionenes. The correlation between the chemical structure of the ionenes and the conductivity was discussed. In the TDA,n-TCNQ complex salts and the BP,n-TCNQ simple salts the salts of the ionenes containing even numbers of CH2 groups showed higher conductivities than those of the ionenes containing odd numbers of CH2 groups. The conductivities determined by the narrower interval between the N+ cations of the main chains were measured in the simple salts. In the complex salts the conductivities determined by the larger interval were measured. The conformational change of the matrix ionenes affected the arrangement of the TCNQ molecules. The values of p were 79.7 and 12.5 Ω cm, and the values of Ea were 0.122 and 0.063 eV for TDA,4-TCNQ complex salt and BP,5-TCNQ complex salt, respectively. 相似文献
164.
Summary The influence of secondary minimum for the stability of spherical colloid has been studied using a series of soap-free polystyrene latices from 350 m to 1400 m in diameter.The critical flocculation concentration (c. f. c.) and the zeta-potential at the c. f. c. for each latex were determined with several salts of different ionic valencies. The values of c. f. c. varied with the particle size, reaching a maximum value at 750 m and then decreasing gradually with the diameter.Another phenomenon detected in the experiment was the complete reversibility of coagulation which was observed only in the cases of large size latices, i. e., the coagulates of large size particles were fully redispersed in the solution by stirring. The time-dependence of their sedimentation curves was reproducible.These experimental results could not be explained by the simple theoretical consideration for stability of suspension. The satisfactory explanation is given only using the term of secondary minimum of interaction potential, i. e., the origin of coagulation was shifted from the ordinary primary minimum to the shallow secondary minimum at about 750 m of the particle diameter.
With 7 figures in 10 details and 2 tables 相似文献
Zusammenfassung Der Einfluß des Sekundär-Minimum auf die Stabilität von Kolloiden wurde an seifenfreien Polystyrol-Latex-Suspensionen mit einem Durchmesser von 350 m bis 1400 m untersucht. Die kritische Flockungskonzentration (c. f. c.) und das Zeta-Potential bei c. f. c. wurde mit verschiedenen Salzen bestimmt.Der Wert von c. f. c. ändert sich mit der Teilchengröße.Ein weiterer wichtiger experimenteller Befund ist die vollständige Reversibilität der Flockung bei größeren Latices.Derartige Versuchsergebnisse können durch das Sekundär-Minimum befriedigend erklärt werden.
With 7 figures in 10 details and 2 tables 相似文献
165.
Calorimetric measurements at 25°C were made to determine the thermodynamic quantities for the intercalation of pyridine with α- and γ-zirconium phosphates. These phosphates showed exothermic reactions with ΔH0 = ?59.3 and ?21.9 kJ mole?1, respectively. The large difference between the depyridination temperatures for both intercalates is rediscussed with the aid of the ΔG0 data obtained. 相似文献
166.
Hamao Watanabe Kazuaki Higuchi Tomoko Goto Tsutomu Muraoka Jun Inose Masaaki Kageyama Yasuko Iizuka Masakatsu Nozaki Yoichiro Nagai 《Journal of organometallic chemistry》1981,218(1):27-39
In the presence of a catalytic amount of sodium methoxide, sym-dimethoxytetramethyldisilane was converted into α,ω-dimethoxypermethylpolysilanes, MeO(SiMe2)nOMe where n ? 3, at room temperature. On the other hand, similar treatment of the disilane in THF solution gave cyclic polysilanes, (Me2Si)n where n = 5–7. Decomposition of the disilane in the presence of diphenylacetylene afforded a trisilacyclopentene derivative under similar conditions. This compound was obtained also by the reaction between α,ω-dimethoxypermethylpolysilanes and diphenylacetylene in the presence of sodium methoxide. These cyclic products most likely were formed via permethyl polysilyl anion intermediates derived from α,ω-dimethoxypermethylpolysilanes. Also, the formation of α,ω-dimethoxypermethylpolysilanes could be elucidated in terms of the mechanism involving the base-assisted, concerted nucleophilic substitution or stepwise substitution by silyl anions, rather than the successive dimethylsilylene (Me2Si:) insertion reaction. 相似文献
167.
We have measured luminescence spectra of 2H-PbI2 at different temperatures between 77 and 180 K. The lower energy tail of the luminescence band due to free exciton annihilation decreases exponentially with decreasing the photon energy over an order of magnitude, which corresponds to the Urbach tail in the absorption spectrum. This fact suggests that the exciton state corresponding to the exponential tail is in the thermal equilibrium and the steepness coefficient δ0 = 1.67 in Urbach rule is obtained also from the luminescence spectra. 相似文献
168.
Nakayama M Goto S Uchimoto Y Wakihara M Kitajima Y Miyanaga T Watanabe I 《The journal of physical chemistry. B》2005,109(22):11197-11203
Changes in the electronic structure of olivine Li(1-x)CoPO(4), 4.8 V positive electrode material for lithium ion batteries, were investigated using the X-ray absorption spectroscopy (XAS) technique. The threshold energy in the Co K-edge increased with electrochemical Li removal, indicating the oxidation of cobalt ions due to charge compensation. Moreover, P and O K-edge XAS showed a slight shift in threshold energy with Li removal. Although it is generally believed that the electrons of PO(4) polyanion do not contribute to the oxidation process, present experimental results indicate changes in the electronic structure around PO(4) units. Such results would be interpreted by the idea of the hybridization effect between the Co 3d and O 2p orbitals and of the polarization effect introduced by Li ions. 相似文献
169.
Savici AT Fukaya A Gat-Malureanu IM Ito T Russo PL Uemura YJ Wiebe CR Kyriakou PP MacDougall GJ Rovers MT Luke GM Kojima KM Goto M Uchida S Kadono R Yamada K Tajima S Masui T Eisaki H Kaneko N Greven M Gu GD 《Physical review letters》2005,95(15):157001
Muon spin relaxation measurements in high transverse magnetic fields [FORMULA: SEE TEXT] revealed strong field-induced quasistatic magnetism in the underdoped and Eu-doped (La,Sr)2CuO4 and La1.875Ba0.125CuO4, existing well above Tc and TN. The susceptibility counterpart of Cu spin polarization, derived from the muon spin relaxation rate, exhibits a divergent behavior towards T approximately 25 K. No field-induced magnetism was detected in overdoped La1.81Sr0.19CuO4, optimally doped Bi2212, and Zn-doped YBa2Cu3O7. 相似文献
170.
Inner shell ionization cross sections by low-energy positron impact have been measured. Development of an x-ray detector with thin Si(Li) crystals has enabled the first measurements of the absolute cross sections for the positron impacts in the energy range below 30 keV. Threshold behavior of the measured cross sections for the Cu K shell and Ag L shell are compared with the theoretical results of Gryzinski and Kowalski [Phys. Lett. A 183, 196 (1993)]] and Khare and Wadehra [Can. J. Phys. 74, 376 (1996)]]. Good agreement has been found for the Cu K shell, while the experimental values for the Ag L shell were found to be smaller than the corresponding theoretical results. 相似文献