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91.
Kulkarni NV Budagumpi S Kurdekar GS Revankar VK Didagi S 《Chemical & pharmaceutical bulletin》2010,58(12):1569-1575
A novel Cu(II) and Zn(II) complexes of triazolo-quinoline derivatives were synthesized by in situ method and were characterized by the spectro-analytical methods and their pharmacological properties were evaluated. The compound C3 has exhibited promising anticonvulsant activity towards the electroshock induced seizures in Wistar rats and possesses low toxicity, providing a high safety profile. 相似文献
92.
M.?Prabu S.?SelvasekarapandianEmail author A.?R.?Kulkarni S.?Karthikeyan G.?Hirankumar C.?Sanjeeviraja 《Ionics》2011,17(3):201-207
Olivine-structured pure LiNiPO4 and yttrium-doped LiNiPO4 have been synthesized by a Pechini-type polymerizable precursor method. Compound formation temperature is confirmed from
thermogravimetry to differential thermal analysis. Powder X-ray diffraction pattern confirmed the formation of phase pure
LiNiPO4 compound with an orthorhombic structure with fine crystallite size. Presence of preferred local cation environment is understood
from Fourier transform infrared spectroscopy (FTIR) studies. XRD and FTIR studies show that doped yttrium ion entered in the
lattice of LiNiPO4. It has been found that the ionic conductivity of LiNiPO4 is enhanced by around two orders of magnitude by doping yttrium. Dielectric spectra show the decrease in dielectric constant
with increase in frequency. Dielectric loss spectra reveal that dc conduction contribution predominates in the sample. 相似文献
93.
We consider an appointment system where the patients have preferences about the appointment days. A patient may be scheduled on one of the days that is acceptable to her, or be denied appointment. The patient may or may not show up at the appointed time. The net cost is a convex function of the actual number of patients served on a given day. We study the optimal scheduling policy that minimizes the long-run average cost and study its structural properties. We advocate an index policy, which is easy to implement, performs well in comparison with other heuristic policies, and is close to the optimal policy. 相似文献
94.
95.
S. H. Kulkarni 《International Journal of Mathematical Education in Science & Technology》2013,44(6):919-922
A quantitative version of the Arzela-Ascoli theorem is proved. This version implies that a closed and bounded subset of C(X) is nearly compact, if and only if, it is nearly equicontinuous. 相似文献
96.
Stability constants of the ternary complexes [CuAL] whereA = 5-Nitro-1,10-phenanthroline, bis(2-pyridyl) ketone (DPK) orbis(2-pyridyl)amine (DPA) andL is the dianion of catechol, tiron, protocatechic acid, pyrogallol, 1,8-dihydroxynaphthalene, catecholaldehyde, 2,3-dihydroxynaphthalene,
dopamine or adrenaline have been determined by potentiometric titration in dioxane water (1:1 v/v) medium using a SCOGS computer
programme. The observed trend of stability is explained on the basis of the nature of substitution over the ligands, chelate
ring size and also the composition of mixed solvent in case of DPK. Structural changes in DPK have also been discussed as
a function of pH, composition of medium and coordinating mode of the secondary ligand in the ternary complexes. 相似文献
97.
J.M. Cho W.J. Yun J.-K. Lee H.S. Lee W.W. So S.J. Moon Y. Jia H. Kulkarni Y. Wu 《Applied Physics A: Materials Science & Processing》2007,88(4):751-755
Titania nanotubes were prepared using a hydrothermal method. Hydrogen titanate nanotubes (H-TNTs) with an anatase phase changed
to anatase nanocrystals at about 500 °C, and then a rutile structure at ∼800 °C. A sharp and symmetrical electron spin resonance
(ESR) signal (g=2.003), attributed to a single-electron-trapped oxygen-vacancy (SETOV), was obtained at the annealed H-TNTs
(T<500 °C). The SETOV signal increased and maximized remarkably at about 400–500 °C. Then, the nanotube structure appeared
to be demolished. Yet, when the vacuum-heated H-TNTs were sealed in N2 or Ar ambient, some additional ESR signals appeared besides the SETOV signal. The broad asymmetric ESR signal (g=1.98) was
attributed to a surface oxygen vacancy related to the Ti3+ sites in a reduced TiO2 matrix. The vacuum-heated sodium titanate nanotubes (Na-TNTs) showed only the SETOV signal (T<500 °C).
PACS 61.46.Fg; 61.72.Ji; 76.30.-v 相似文献
98.
99.
This paper reports on the spectral (response) characteristics of fiber Bragg grating sensor to various methanol concentrations. A complete experimental analysis on the use of Ge-B co-doped fiber Bragg grating sensor for a concentration and refractive index measurement is presented. The spectral changes in the grating response due to variation of concentration have been investigated in relation to new sensing configurations. The results also highlight the possibilities of using the sensor for medical and biological applications. 相似文献
100.
Milind V Kulkarni 《European Polymer Journal》2004,40(2):379-384
Polyaniline and poly(o-toluidine) doped with p-toluene sulphonic acid (p-TSA) were synthesized by in situ chemical polymerization method using ammonium per sulphate as an oxidizing agent. This is a novel polymerization process for the direct synthesis of emeraldine salt phase of the polymer. The polymers were characterized by using UV-Vis and FT-IR spectroscopy, SEM, elemental analyzer, TGA/DSC and conductivity measurements. Thermal analysis shows that poly(o-toluidine) is less thermally stable compared to polyaniline. The less conductivity in poly(o-toluidine) is due to the cumulative steric as well as electronic effect of the bulky methyl substituent present on the benzene ring. High temperature conductivity measurements show ‘thermal activated behavior’. 相似文献