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51.
The exciton spin dynamics in a quantum well with a magnetic field applied in its plane is analyzed theoretically. The exchange interaction between the electron and the hole is assumed to be strong. The width of the Hanle effect profile is shown to depend on the hole spin relaxation time. The intensity signal obtained under pulsed exciton generation as a function of time is characterized by two decay times, and the polarization signal, by a third time which is strongly dependent on the applied field. 相似文献
52.
D. A. Loginov D. V. Muratov Z. A. Starikova P. V. Petrovskii A. R. Kudinov 《Russian Chemical Bulletin》2006,55(9):1581-1584
The reaction of the (borole)rhodium iodide complex [(η-C4H4BPh)RhI]4 with Cp*Li afforded the sandwich compound Cp*Rh(η-C4H4BPh) (4). The reactions of compound 4 with the solvated complexes [Cp*M(MeNO2)3]2+(BF
4
−
)2 gave triple-decker cationic complexes with the central borole ligand [Cp*Rh(η-η5:η5-C4H4BPh)MCp*]2+(BF
4
−
)2 (M = Rh (5) or Ir (7)). The structure of complex 4 was established by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1525–1527, September, 2006. 相似文献
53.
Kudinov A. R. Perekalin D. S. Petrovskii P. V. Grintselev-Knyazev G. V. 《Russian Chemical Bulletin》2002,51(10):1928-1930
The ruthenium arene complexes [(-arene)Ru(-9-SMe2-7,8-C2B9H10)]+ (arene = C6H6 (3a); arene = 1,3,5-C6H3Me3 (3b)) with the monoanionic carborane ligand were synthesized by the reactions of the [9-SMe2-7,8-C2B9H10]– anion with [(-arene)RuCl2]2. The structure of the compound [3a]BPh4 was established by single-crystal X-ray diffraction analysis. 相似文献
54.
Maddalena Corsini Piero Zanello Alexander R. Kudinov Vladimir I. Meshcheryakov Dmitry S. Perekalin Konstantin A. Lyssenko 《Journal of Solid State Electrochemistry》2005,9(11):750-757
The redox aptitude of a series of cobalt(III) or cobalt(I) sandwich complexes bearing a charge compensated dicarbollide ligand
([9-L-7,8-C2B9H10]−) as a constant unit and different counterparts (varying from classical [7,8-C2B9H11]2− to charge-compensated [9-L-7,8-C2B9H10]− dicarbollides, from cyclopentadienyl [C5R5]− (R = Me, H) to cyclobutadiene [C4Me4]0 ligands) has been studied. All the Co(III) complexes display the reversible sequence Co(III)/Co(II)/Co(I). In contrast, the
Co(I) complexes (namely, those capped by tetramethylcyclobutadiene) accede reversibly only to the Co(II) oxidation state,
the passage to Co(III) being irreversible. When possible, the Co(II) intermediates have been characterized by EPR spectroscopy.
The molecular structures of the monocation [Co(η-9-SMe2-7,8-C2B9H10)2]+ in its DD/LL and meso diastereomeric forms as well as that of heteroleptic (η-7,8-C2B9H11)Co(η-9-SMe2-7,8-C2B9H10) have been obtained by single-crystal diffraction.
Presented at the 3rd Chianti Electrochemistry Meetings July 3−9, 2004, Certosa di Pontignano, Italy 相似文献
55.
A. S. Vusikhis D. Z. Kudinov L. I. Leont’ev 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(11):1824-1827
A model was suggested that allows the kinetics of bubbling of various reducing gases through an oxide melt to be described by thermodynamic equilibrium calculations without the use of experimental data. An algorithm for calculations was developed. The model is tested for the NiO-FeO-Al2O3-SiO2-CaO-Mg-CO-CO2 system. A comparative analysis of the calculation results and experimental data showed that the suggested technique could be used in a qualitative analysis of interactions between multicomponent oxide melts and gaseous reducing agents of various compositions. Calculations describing the kinetics of reduction of nickel oxide with hydrogen in the NiO-CaO-B2O3 system over the temperature range 1473–1973 K were performed. 相似文献
56.
Bushra Y Ahmed Sridhara Chakravarthy Ruben Eggers Wim TJMC Hermens Jing Ying Zhang Simone P Niclou Christiaan Levelt Fred Sablitzky Patrick N Anderson AR Lieberman Joost Verhaagen 《BMC neuroscience》2004,5(1):1-11
Background
As development proceeds the human embryo attains an ever more complex three dimensional (3D) structure. Analyzing the gene expression patterns that underlie these changes and interpreting their significance depends on identifying the anatomical structures to which they map and following these patterns in developing 3D structures over time. The difficulty of this task greatly increases as more gene expression patterns are added, particularly in organs with complex 3D structures such as the brain. Optical Projection Tomography (OPT) is a new technology which has been developed for rapidly generating digital 3D models of intact specimens. We have assessed the resolution of unstained neuronal structures within a Carnegie Stage (CS)17 OPT model and tested its use as a framework onto which anatomical structures can be defined and gene expression data mapped.Results
Resolution of the OPT models was assessed by comparison of digital sections with physical sections stained, either with haematoxylin and eosin (H&E) or by immunocytochemistry for GAP43 or PAX6, to identify specific anatomical features. Despite the 3D models being of unstained tissue, peripheral nervous system structures from the trigeminal ganglion (~300 μm by ~150 μm) to the rootlets of cranial nerve XII (~20 μm in diameter) were clearly identifiable, as were structures in the developing neural tube such as the zona limitans intrathalamica (core is ~30 μm thick). Fourteen anatomical domains have been identified and visualised within the CS17 model. Two 3D gene expression domains, known to be defined by Pax6 expression in the mouse, were clearly visible when PAX6 data from 2D sections were mapped to the CS17 model. The feasibility of applying the OPT technology to all stages from CS12 to CS23, which encompasses the major period of organogenesis for the human developing central nervous system, was successfully demonstrated.Conclusion
In the CS17 model considerable detail is visible within the developing nervous system at a minimum resolution of ~20 μm and 3D anatomical and gene expression domains can be defined and visualised successfully. The OPT models and accompanying technologies for manipulating them provide a powerful approach to visualising and analysing gene expression and morphology during early human brain development. 相似文献57.
58.
I. S. Rassonskaya N. K. Semendyaeva I. B. Kudinov S. F. Chistov 《Journal of Thermal Analysis and Calorimetry》1969,1(4):459-464
Anhydrous double salts of rubidium sulphate and cesium sulphate with lithium sulphate have been prepared, and polymorphous transformations at+60° and +200° for Rb2SO4 · Li2SO4 and at –75° for Cs2SO4 · Li2SO4 have been disclosed by means of differential thermal analysis. These findings were confirmed by dilatometric measurements and X-ray phase analysis at various temperatures.
Zusammenfassung Mit Hilfe differentialthermoanalytischer Untersuchungen konnten polymorphe Umwandlungen in den wasserfreien Doppelsalzen Rubidiumsulfat-Lithiumsulfat bzw. Cäsiumsulfat-Lithiumsulfat festgestellt werden. Die entsprechenden Temperaturen betragen bei Rb2SO4 · Li2SO4 +60° und +200°, bei Cs2SO4 · Li2SO4 –75°. Diese Befunde wurden durch dilatometrische Messungen und weiterhin durch röntgenographische Phasenanalyse bei verschiedenen Temperaturen bekräftigt.
Résumé On a observé, lors de l'examen par ATD de Rb2SO4 · Li2SO4 et Cs2SO4 · Li2SO4 anhydres, des transformations polymorphiques à + 60° et à + 200° dans le cas de la première combinaison et à –75° dans le cas de la seconde. Ces observations ont été confimées par les résultats dilatométriques et d'analyse de phase par rayons X.
. +60° +200° Rb2SO4. Li2SO4 –75° Cs2SO4. Li2SO4. .相似文献
59.
60.
Visible light irradiation of the [(η-C6H7)Fe(η-C6H6)]+ cation (1) in CH2Cl2 in the presence of alkyl-substituted benzenes results in arene exchange forming the [(η5-C6H7)Fe(η-C6R6)]+ cations (2a–d: C6R6 is toluene, p-xylene, mesitylene, and durene). The mixed bis(arene) [(η-C6H6)Fe(η-C6R6)]2+ iron complexes (3a–d) were synthesized by hydride ion abstraction from 2a–d by [Ph3C]+.
Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1864–1865, September, 2007. 相似文献