Novel acrylic macromonomer with amphiphilic character derived from Triton X‐100: Radical copolymerization with methyl methacrylate and thermal properties

This article explores the synthesis of a novel methacrylic macromonomer with an amphiphilic character derived from poly(ethylene glycol) tert‐octylphenyl ether (MT) and its respective homopolymer. To know their reactivity in radical copolymerization reactions with methyl methacrylate (MMA), a model monomer (MTm) was synthesized to determine the reactivity ratios and compare them with the low molar fractions of copolymers of MT with MMA because they were difficult to isolate. They were r_MTm = 0.97 and r_MMA = 0.95. The compositional diagrams when representing the weight fraction of MT and MTm in the feed and the copolymer suggested that a clear correlation exists between the experimental points of the model monomer MTm and the macromonomer MT ones, suggesting that the length of the side poly(ethylene oxide) chain does not affect the reactivity of the methacrylic double bond in the prepared monomers for this type of polymerization reaction. The reactivity ratios of the copolymers have a tendency for the formation of random or Bernoullian copolymers. The glass‐transition temperatures (T_g's) of the prepared copolymers were determined by differential scanning calorimetry, deviated from the Fox equation, and discussed on the basis of treatments that consider the influence of the monomeric units along the copolymer chains, determining the T_g of the corresponding alternating dyads. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1641–1649, 2003     

1,1,3-Trimethyl-3-phenylindan as a Luminescent Additive to a Plastic Scintillator Based on Poly(methyl Methacrylate)

The luminescence and scintillation properties of poly(methyl methacrylate) containing 1,1,3-trimethyl-3-phenylindan were studied.     

Mass‐lumping or not mass‐lumping for eigenvalue problems

In this article we analyze the effect of mass‐lumping in the linear triangular finite element approximation of second‐order elliptic eigenvalue problems. We prove that the eigenvalue obtained by using mass‐lumping is always below the one obtained with exact integration. For singular eigenfunctions, as those arising in non convex polygons, we prove that the eigenvalue obtained with mass‐lumping is above the exact eigenvalue when the mesh size is small enough. So, we conclude that the use of mass‐lumping is convenient in the singular case. When the eigenfunction is smooth several numerical experiments suggest that the eigenvalue computed with mass‐lumping is below the exact one if the mesh is not too coarse. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 653–664, 2003     

Solving of second order nonlinear PDE problems by using artificial controls with controlled error

In this paper, we find the approximate solution of a second order nonlinear partial differential equation on a simple connected region inR ². We transfer this problem to a new problem of second order nonlinear partial differential equation on a rectangle. Then, we transformed the later one to an equivalent optimization problem. Then we consider the optimization problem as a distributed parameter system with artificial controls. Finally, by using the theory of measure, we obtain the approximate solution of the original problem. In this paper also the global error inL ₁ is controlled.     

On p-Extensions of Fields of Characteristic p

It is proved that a Galois extension of a field of characteristic p is completely determined by its Galois group and the endomorphism of the additive group of the group algebra that corresponds to the raising to the power p.     

A Kinematic Formula for Affine Diameters and Affine Medians of a Convex Set

For a planar convex set K with C ²-smooth boundary, the area of the set of the points lying on a given number of affine diameters of K is estimated. As a corollary, it is proved that the area of K is at most pM² /4\pi M^2 /4 , where M is the largest length of a chord of K halving the area of K. Bibliography: 2 titles.     

Multipulse regimes of excitation of optical superradiance due to a two-photon transition

Multimode triggered optical superradiance due to a two-photon transition is theoretically studied. Kinetic equations are derived for the dynamics of cooperative development of coherence and population inversion of optical centers interacting with each other through a common field of emitted photons. Various regimes of triggering of optical superradiance due to a two-photon transition are considered. The possibility of creating a quantum photomultiplier on the basis of the triggered optical superradiance is discussed.     

Focusing of singular beams

The process of focusing of an inhomogeneously polarized beam passed through a system consisting of a uniaxial crystal and a polarization filter is considered. It is shown that the action of this system is equivalent to the action of a phase transparency with a complex relief of the refractive index. In particular, if the angle between the axes of the quarter-wave plate and the polarizer is equal to 45°, this transparency has a helicoidal relief. Simultaneously, two singular beams with different curvatures of their wavefronts arise in the transparency. The action of the lens consists in formation of a combined singular beam having three focal waists. The boundary wave arising upon focusing is able not only to form a new spectrum of toroidal vortices, but also to straighten the focusing region, forming a fairly extended range with a weak divergence.     

Photoluminescence of liquid-crystal azo derivatives in nanopores

Optics and Spectroscopy - The fluorescence of the nematic liquid crystal n-butyl-n′-methoxyazoxybenzene (BMAOB) in the form of a layer and in porous glasses with pores of different diameter...