全文获取类型
收费全文 | 424篇 |
免费 | 53篇 |
国内免费 | 42篇 |
专业分类
化学 | 365篇 |
晶体学 | 5篇 |
力学 | 16篇 |
综合类 | 1篇 |
数学 | 22篇 |
物理学 | 110篇 |
出版年
2023年 | 7篇 |
2022年 | 13篇 |
2021年 | 11篇 |
2020年 | 16篇 |
2019年 | 16篇 |
2018年 | 14篇 |
2017年 | 13篇 |
2016年 | 33篇 |
2015年 | 17篇 |
2014年 | 27篇 |
2013年 | 26篇 |
2012年 | 36篇 |
2011年 | 25篇 |
2010年 | 28篇 |
2009年 | 18篇 |
2008年 | 31篇 |
2007年 | 16篇 |
2006年 | 25篇 |
2005年 | 21篇 |
2004年 | 16篇 |
2003年 | 14篇 |
2002年 | 15篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 4篇 |
1997年 | 7篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1966年 | 3篇 |
1951年 | 1篇 |
排序方式: 共有519条查询结果,搜索用时 15 毫秒
51.
52.
Crystal engineering, as a burgeoning technology, has been widely used to construct metalloporphyrins biomimetic catalysts. Herein, a bimetallic metal-organic framework (MOF) was constructed by 4-(4-carboxyphenyl)-1,2,4-triazole ligand, Co2+ and Zr4+ metal ions by solvothermal reaction(named PFC-88). A N,N-chelation site was found between the two adjacent ligands in PFC-88, consequently a porphyrin-like structure was obtained through chelating Fe3+ in this site by post-modification, named PFC-88-Fe. The result of a single crystal X-ray technology verified that Fe ions were successfully metalated in the N,N-chelation site of PFC-88, which is assisted by the X-ray absorption near-edge structure(XANES) spectra. An o-phenylenediamine oxidation reaction was applied to assessing the catalytic activity of PFC-88-Fe, in which the absorbance increases of phenazine-2,3-diamine at λ=418 nm were recorded by absorption spectroscopy in kinetic mode, exhibiting the application potential as a biomimetic catalyst. 相似文献
53.
Yaqin Wang Xibo Zhang Kuan Chang Zhiying Zhao Jiayu Huang Prof. Qin Kuang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(16):e202104514
Exploring new catalytic strategies for achieving efficient CO2 hydrogenation under mild conditions is of great significance for environmental remediation. Herein, a composite photocatalyst Zr-based MOF encapsulated plasmonic AuPt alloy nanoparticles (AuPt@UiO-66-NH2) was successfully constructed for the efficient photothermal catalysis of CO2 hydrogenation. Under light irradiation at 150 °C, AuPt@UiO-66-NH2 achieved a CO production rate of 1451 μmol gmetal−1 h−1 with 91 % selectivity, which far exceeded those obtained by Au@Pt@UiO-66-NH2 with Pt shell on Au (599 μmol gmetal−1 h−1) and Au@UiO-66-NH2 (218 μmol gmetal−1 h−1). The outstanding performances of AuPt@UiO-66-NH2 were attributed to the synergetic effect originating from the plasmonic metal Au, doped active metal Pt, and encapsulation structure of UiO-66-NH2 shell. This work provides a new way for photothermal catalysis of CO2 and a reference for the design of high-performance plasmonic catalysts. 相似文献
54.
Flame retardance and thermal stability of carbon nanotube epoxy composite prepared from sol-gel method 总被引:1,自引:0,他引:1
Chen-Feng Kuan Yi-Luen Li Hsu-Chiang Kuan 《Journal of Physics and Chemistry of Solids》2010,71(4):539-13298
Carbon nanotubes (CNTs) are functionalized by vinyltriethoxysilane (VTES) to incorporate the -O-C2H5 functional group and become VTES—CNT. The VTES—CNTs are added to the modified DGEBA epoxy resin that contains silicon to induce the sol-gel reaction. The final products are organic/inorganic nanocomposites. Thermogravimetric analysis (TGA) and differential scanning calorimeter (DSC) are used to study the thermal property of nanocomposites. The Tg was increased from 118 to 160 °C and char yield of composites that contained 9 wt% CNT at 750 °C was increased by 46.94%. The integral procedural decomposition temperature (IPDT) was increased from 890 to 1571 °C. The limiting oxygen index (LOI) and UL-94 tests were classified as the flame retardance. The LOI of composites was increased from 22 to 27 and the UL-94 changed from V-1 to V-0 when the contents were increased to 9 wt%. The nanocomposites had a higher char yield and were highly flame retardant. The products can meet to the requirements of halogen-free and phosphorus-free ecological flame retardant. 相似文献
55.
56.
本文研究了形如∑_n~k=o~((α_k)(e~((α_k)x))D~k(a_k≤0)及∑_k~n=o((-1)~k)α_(2k)D~ke~(α_(2k)x)D~k+i/2∑_k~n=o(α_(2k+1))(D~ke~((α_(2k+1))x)D~(k+1)+D~(k+1)e~((α_(2k+1)x)D~k)(α_k≤0)的算式的谱问题,分别得到了它们的本质谱或本质谱所在的范围. 相似文献
57.
The assembly of gold nanorods(GNRs) into different liquid crystalline structures can be controlled by tuning their surface electric potential. After mildly removing excess surfactants in the GNRs solution, the electrostatic interaction between GNRs can be tuned by adjusting counter ion concentration. Specifically, nematic and smectic structures formed after solvent evaporation at low and high bromide concentrations, respectively. These results could be helpful for fabricating anisotropy enabled devices composed of metal and semiconductor nanorods. 相似文献
58.
Xia Wu Yumin Tang Yuxi Wang Xiaoyuan Liu Changmei Liu Xiaonan Zhang Yingguo Yang Xingyu Gao Fei Chen Xugang Guo Zhi‐Kuan Chen 《Journal of polymer science. Part A, Polymer chemistry》2017,55(22):3679-3689
Two novel polymeric acceptors based on naphthalene diimide (NDI) and 2.2′‐bithiophene, named as P(NDI2THD‐T2) and P(NDI2TOD‐T2), were designed and synthesized for all polymer solar cells application. The structural and electronic properties of the two acceptors were modulated through side‐chain engineering of the NDI units. The optoelectronic properties of the polymers and the morphologies of the blend films composed of the polymer acceptors and a donor polymer PTB7‐Th were systemically investigated. With thiophene groups introduced into the side chains of the NDI units, both polymers showed wider absorption from 350 nm to 900 nm, compared with the reference polymer acceptor of N2200. No redshift of absorption spectra from solutions to films indicated reduced aggregation of the polymers due to the steric hindrance effect of thiophene rings in the side chains. The photovoltaic performance were characterized for devices in a configuration of ITO/PEDOT:PSS/PTB7‐Th:acceptors/2,9‐bis(3‐(dimethylamino)propyl)anthra[2,1,9‐def:6,5,10‐def]diisoquinoline‐1,3,8,10(2H,9H)‐tetraone (PDIN)/Al. With the addition of diphenyl ether as an additive, the power conversion efficiencies (PCEs) of 2.73% and 4.75% for P(NDI2THD‐T2) and P(NDI2TOD‐T2) based devices were achieved, respectively. The latter showed improved Jsc, Fill Factor (FF), and PCE compared with N2200 based devices. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3679–3689 相似文献
59.
广义扩展有限元法及其在裂纹扩展分析中的应用 总被引:1,自引:0,他引:1
结合广义有限元法(GFEM)和扩展有限元法(XFEM)的特点,提出了一种新的数值方法——广义扩展有限元法(GXFEM)。阐述了广义扩展有限元法的基本原理,对相关公式进行推导,探讨数值实施中需注意的重要问题,给出利用广义扩展有限元法进行断裂分析时应力强度因子的计算方法,编写了广义扩展有限元法程序。通过算例进行了应力强度因子的计算,模拟了结构裂纹的扩展过程。算例结果表明,利用广义扩展有限元法计算裂纹扩展问题,不需要进行过密的网格划分,且网格在裂纹扩展后无需重新剖分,具有相当高的计算精度。 相似文献
60.
Ying Lin Zhi‐Kuan Chen Teng‐Ling Ye Yan‐Feng Dai Dong‐Ge Ma Zhun Ma Qin‐De Liu Yu Chen 《Journal of polymer science. Part A, Polymer chemistry》2010,48(2):292-301
A series of conjugated blue‐light‐emitting copolymers, PTC‐1 , PTC‐2 , and PTC‐3, comprised different ratios of electron‐withdrawing segments (spirobifluorene substituted with cyanophenyl groups) and electron‐donating segments (tricarbazole‐triphenylamines), has been synthesized. The structures of these polymers were characterized and their thermal, photophysical, electrochemical, and electroluminescence properties were measured. Incorporation of rigid spirobifluorene units into the copolymers led to blue‐shifted absorption peaks in dilute toluene solution. Cyclic voltammetric measurement indicated the bandgaps of the polymers were in the range of 2.77–2.94 eV. It was found that increasing cyanophenyl‐spirobifluorene content in the polymer backbone lowered both the HOMO and LUMO energy levels of the copolymers, which was beneficial for electron injection/transporting in the polymer layer of the device. OLED device evaluation indicated that all the polymers emitted sky blue to deep blue light when the pure polymers were used as the emissive layers in the devices with a configuration of ITO/PEDOT:PSS/polymers/CsF/Ca/Al. The devices have been optimized by doping 30 wt % PBD into the polymer layers. Among the doped devices, PTC‐2 showed the best performance with the turn‐on voltage of 3.0 V, maximum brightness of 7257 cd/m2, maximum current efficiency of 1.76 cd/A, and CIE coordinates of (0.15, 0.14). © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 292–301, 2010 相似文献