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91.
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Anna Gumieniczek Justyna Galeza Tomasz Mroczek Krzysztof Wojtanowski Katarzyna Lipska Rafał Pietras 《Chromatographia》2018,81(8):1147-1162
Dihydralazine and hydrochlorothiazide were stored at high temperature and humidity, under UV/Vis light and different pH, as individual drugs and the mixture. Then, a sensitive and selective HPLC-UV method was developed for simultaneous determination of dihydralazine and hydrochlorothiazide in presence of their degradation products. Finally, the degradation products were characterized through LC-DAD and LC–MS methods. Dihydralazine was sensitive to high temperature and humidity, UV/Vis light and pH?≥?7. At the same time, it was resistant to acidic conditions. Hydrochlorothiazide was sensitive to high temperature and humidity, UV/Vis light and changes in pH. Its highest level of degradation was observed in 1 M HCl. Degradation of the drugs was higher when they were stressed in the mixture. In the case of dihydralazine, the percentage degradation was 5–15 times higher. What is more, dihydralazine became sensitive to acidic conditions. Hydrochlorothiazide was shown to be more sensitive to UV/Vis light and pH?>?4. Degradation of dihydralazine and hydrochlorothiazide followed first-order kinetics. The quickest degradation of dihydralazine was found to be in 1 M NaOH while of hydrochlorothiazide was in 1 M HCl (individual hydrochlorothiazide) or at pH 7–10 (hydrochlorothiazide in the mixture). A number of new degradation products were detected and some of them were identified by our LC-DAD and LC–MS methods. In the stressed individual samples, (phenylmethyl)hydrazine and 1,2,4-benzothiadiazine-7-sulfonamide 1,1-dioxide were observed for the first time. Interactions between dihydralazine and hydrochlorothiazide in the mixture were confirmed by additional degradation products, e.g., 2H-1,2,4-benzothiadiazine-7-sulfonamide 1,1,4-trioxide. 相似文献
93.
Numerical Algorithms - The paper introduces the analytical modification of the classic boundary integral equation (BIE) for Stokes equation in 3D. The performed modification allows us to obtain... 相似文献
94.
Mathematical Programming - The aim of this paper is to show that every representative function of a maximally monotone operator is the Fitzpatrick transform of a bifunction corresponding to the... 相似文献
95.
In this paper we investigate Stäckel transforms between different classes of parameter‐dependent Stäckel separable systems of the same dimension. We show that the set of all Stäckel systems of the same dimension splits to equivalence classes so that all members within the same class can be connected by a single Stäckel transform. We also give an explicit formula relating solutions of two Stäckel‐related systems. These results show in particular that any two geodesic Stäckel systems are Stäckel equivalent in the sense that it is possible to transform one into another by a single Stäckel transform. We also simplify proofs of some known statements about multiparameter Stäckel transform. 相似文献
96.
The first attempt of finding of optimal shape for bars in presence of body forces with respect to mixed creep rupture is made. For given volume of the bar, distribution of initial cross-section, ensuring the longest life-time to mixed rupture is sought. The finite strain theory and physical law in form of Norton's law generalized for true stresses and logarithmic strains are applied. Using the method of parametric optimization, the best of linear and quadratic functions describing the initial shape of the bar are found. The shape of initial strength is corrected in a way leading to longer life-time. Results of both approaches are compared. 相似文献
97.
Dr. Łukasz Mąkolski Vadim Szejko Dr. Karolina Zelga Dr. Adam Tulewicz Dr. Piotr Bernatowicz Dr. Iwona Justyniak Prof. Janusz Lewiński 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(18):5666-5674
Simple RZnOR’ alkoxides are among the first known organozinc compounds, and widespread interest in their multifaced chemistry has been driven by their fundamental significance and potential applications including various catalytic reactions. Nevertheless, their chemistry in solution and in the solid state remains both relatively poorly understood and a subject of constant debate. Herein, the synthesis and structural characterization of long-sought structural forms, a roof-like trimer [(tBuZn)3(μ-OC(H)Ph2)2(μ3-OC(H)Ph2)] and a ladder-type tetramer [(PhZn)4(μ-OC(H)Ph2)2(μ3-OC(H)Ph2)2], incorporating diphenylmethanolate as a model alkoxide ligand, are reported. Both novel aggregates are robust in the solid state and resistant towards mechanical force. By using 1H NMR and diffusion-order spectroscopy, it is demonstrated that new RZnOR’ alkoxides are kinetically labile in solution and readily undergo ligand scrambling, such as in the case of Schlenk equilibrium. The elucidated key structural issues, which have remained undiscovered for decades, significantly advance the chemistry of RZnOR’ alkoxides and should support the rational design of zinc alkoxide-based applications. 相似文献
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99.
The significance of the electron–phonon interaction for optically stimulated luminescence (OSL) process in quartz is demonstrated. OSL variation with temperature has been investigated for four samples of natural quartz. Changes of the OSL decay rate have been observed for all components of the OSL signal. The scale and tendency of these changes are comparable with outcomes of computer simulations carried out for the model composed of two deep electron traps, one shallow trap and one recombination centre, taking into account the electron–phonon interactions. 相似文献
100.