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331.
Mieczys?aw M?kosza Krystyna Kamieńska-Trela Maciej Paszewski Ma?gorzata Bechcicka 《Tetrahedron》2005,61(50):11952-11964
Oxidative nucleophilic substitution of hydrogen (ONSH) in nitroarenes with carbanion of isopropyl phenyl acetate gives various products depending on the conditions and oxidant. The reaction carried out in liquid ammonia and KMnO4 oxidant gives iso-propyl α-hydroxy-α-nitroarylphenylacetates formed via hydroxylation of the initial ONSH products. In some cases additionally dimeric, trimeric and tetrameric products are formed. In THF and Bu4N+MnO4− or DDQ oxidants simple ONSH products are formed whereas oxidation by dimethyl dioxirane (DMD) gave iso-propyl hydroxyaryl phenyl acetates. The dimeric and trimeric products are apparently formed via coupling of nitrobenzylic radicals generated in course of oxidation with nitrobenzylic carbanions of the ONSH products. 相似文献
332.
Krystyna Bugajska 《International Journal of Theoretical Physics》1979,18(2):95-106
Geometrical properties of elements of the unique representation of the Clifford algebra of quadratic form (+, –, –, –) are investigated. A connection between horospheres on the positive Lobatschevsky space of timelike directions and spinors is established.Partly supported by the Polish Government under the Research Program MR I.7. 相似文献
333.
Microparticles of poly(1,8-diaminonapthalene) (PDAN) were prepared by chemically oxidative polymerization by (NH4)2S2O8. The effect of pH on the sorption of Cd(II), Cu(II), Ni(II), Mn(II), Zn(II) and Pb(II) on PDAN was examined by the batch procedure. PDAN showed good sorption capacity and high selectivity towards Cu(II) in comparison with the very popular chelating sorbent Chelex 100 containing iminodiacetic functional groups. The on-line preconcentration system containing the knotted reactor with the obtained polymer was examined for the sorption and desorption processes of copper ions. The applicability of this system was checked by analysis of Cu(II) content in standard reference material (NIST 1643e) and some natural water samples. 相似文献
334.
Isocyanate-terminated six armed star shaped macromers with a statistical copolymer backbone consisting of 80% EO and 20% PO have previously demonstrated excellent protein and cell repellence as nano-layered surfaces. In this study, various macromers are mixed with water and provide a spectrum of materials that range from particles to uniform hydrogels. Due to hydrophobic end groups, 3 kDa molecular weight macromers result in micro and nano-particles, while 18 kDa macromers completely dissolve and consequently uniform, transparent, high water content hydrogels are formed. Oriented channels may be induced into these hydrogels through the controlled freezing of water in the preformed hydrogel. 相似文献
335.
Krystyna R. Brzezinska Regina Schitter Kenneth B. Wagener 《Journal of polymer science. Part A, Polymer chemistry》2000,38(9):1544-1550
Reactive methoxy‐functionalized carbosilane and carbosiloxane dienes can be either homopolymerized or copolymerized via acyclic diene metathesis (ADMET) polycondensation chemistry to produce reactive materials with mechanical behavior dependent on the molar ratios of the comonomers. The methoxy‐functional group within the polycarbosilane repeat unit remains inert during the metathesis polymerization and can be triggered subsequently with water to generate crosslinks between polymer chains. In this way, linear, thermoplastic copolymers can be prepared with ADMET chemistry and converted into crosslinked, thermoset copolymers upon exposure to moisture. Crosslinked films containing 5–10% of the crosslinked hard segment are soft and flexible materials. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1544–1550, 2000 相似文献
336.
Valeriy Demchenko Yevgen Mamunya Serhii Kobylinskyi Sergii Riabov Krystyna Naumenko Svitlana Zahorodnia Olga Povnitsa Nataliya Rybalchenko Maksym Iurzhenko Grazyna Adamus Marek Kowalczuk 《Molecules (Basel, Switzerland)》2022,27(12)
Green synthesis of silver-containing nanocomposites based on polylactide (PLA) was carried out in two ways. With the use of green tea extract, Ag+ ions were reduced to silver nanoparticles with their subsequent introduction into the PLA (mechanical method) and Ag+ ions were reduced in the polymer matrix of PLA-AgPalmitate (PLA-AgPalm) (in situ method). Structure, morphology and thermophysical properties of nanocomposites PLA-Ag were studied by FTIR spectroscopy, wide-angle X-ray scattering (WAXS), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) methods. The antimicrobial, antiviral, and cytotoxic properties were studied as well. It was found that the mechanical method provides the average size of silver nanoparticles in the PLA of about 16 nm, while in the formation of samples by the in situ method their average size was 3.7 nm. The strong influence of smaller silver nanoparticles (3.7 nm) on the properties of nanocomposites was revealed, as with increasing nanosilver concentration the heat resistance and glass transition temperature of the samples decreases, while the influence of larger particles (16 nm) on these parameters was not detected. It was shown that silver-containing nanocomposites formed in situ demonstrate antimicrobial activity against gram-positive bacterium S. aureus, gram-negative bacteria E. coli, P. aeruginosa, and the fungal pathogen of C. albicans, and the activity of the samples increases with increasing nanoparticle concentration. Silver-containing nanocomposites formed by the mechanical method have not shown antimicrobial activity. The relative antiviral activity of nanocomposites obtained by two methods against influenza A virus, and adenovirus serotype 2 was also revealed. The obtained nanocomposites were not-cytotoxic, and they did not inhibit the viability of MDCK or Hep-2 cell cultures. 相似文献
337.
Anna Nowak Wiktoria Duchnik Edyta Makuch ukasz Kucharski Paula Ossowicz-Rupniewska Krystyna Cybulska Tadeusz Sulikowski Micha Moritz Adam Klimowicz 《Molecules (Basel, Switzerland)》2021,26(23)
Epilobium angustifolium L. is a popular medicinal plant found in many regions of the world. This plant contains small amounts of essential oil whose composition and properties have not been extensively investigated. There are few reports in the literature on the antioxidant and antifungal properties of this essential oil and the possibility of applying it as a potential promoter of the skin penetration of drugs. The essential oil was obtained by distillation using a Clavenger type apparatus. The chemical composition was analyzed by the GC-MS method. The major active compounds of E. angustifolium L. essential oil (EOEa) were terpenes, including α-caryophyllene oxide, eucalyptol, β-linalool, camphor, (S)-carvone, and β-caryophyllene. The analyzed essential oil was also characterized by antioxidant activity amounting to 78% RSA (Radical Scavenging Activity). Antifungal activity against the strains Aspergillus niger, A. ochraceus, A. parasiticum, and Penicillium cyclopium was also determined. The largest inhibition zone was observed for strains from the Aspergillus group. The EOEa enhanced the percutaneous penetration of ibuprofen and lidocaine. After a 24 h test, the content of terpene in the skin and the acceptor fluid was examined. It has been shown that the main compounds contained in the essential oil do not penetrate through the skin, but accumulate in it. Additionally, FTIR-ATR analysis showed a disturbance of the stratum corneum (SC) lipids caused by the essential oil application. Due to its rich composition and high biological activity, EOEa may be a potential candidate to be applied, for example, in the pharmaceutical or cosmetic industries. Moreover, due to the reaction of the essential oil components with SC lipids, the EOEa could be an effective permeation enhancer of topically applied hydrophilic and lipophilic drugs. 相似文献
338.
339.
Irina Macovei Simon Vlad Luca Krystyna Skalicka-Wo
niak Liviu Sacarescu Petronela Pascariu Alina Ghilan Florica Doroftei Elena-Laura Ursu Cristina Mihaela Rimbu Cristina Elena Horhogea Cristina Lungu Gabriela Vochita Alina Diana Panainte Constantin Nechita Maria Andreia Corciova Anca Miron 《Molecules (Basel, Switzerland)》2022,27(1)
Silver nanoparticles synthesized using plant extracts as reducing and capping agents showed various biological activities. In the present study, colloidal silver nanoparticle solutions were produced from the aqueous extracts of Picea abies and Pinus nigra bark. The phenolic profile of bark extracts was analyzed by liquid chromatography coupled to mass spectrometry. The synthesis of silver nanoparticles was monitored using UV-Vis spectroscopy by measuring the Surface Plasmon Resonance band. Silver nanoparticles were characterized by attenuated total reflection Fourier transform infrared spectroscopy, Raman spectroscopy, dynamic light scattering, scanning electron microscopy, energy dispersive X-ray and transmission electron microscopy analyses. The antimicrobial and cytogenotoxic effects of silver nanoparticles were evaluated by disk diffusion and Allium cepa assays, respectively. Picea abies and Pinus nigra bark extract derived silver nanoparticles were spherical (mean hydrodynamic diameters of 78.48 and 77.66 nm, respectively) and well dispersed, having a narrow particle size distribution (polydispersity index values of 0.334 and 0.224, respectively) and good stability (zeta potential values of −10.8 and −14.6 mV, respectively). Silver nanoparticles showed stronger antibacterial, antifungal, and antimitotic effects than the bark extracts used for their synthesis. Silver nanoparticles obtained in the present study are promising candidates for the development of novel formulations with various therapeutic applications. 相似文献
340.
Dominik Niewe Marta Huculak-Mczka Magdalena Braun-Giwerska Kinga Marecka Aleksandra Tyc Marcin Biegun Krystyna Hoffmann Jzef Hoffmann 《Molecules (Basel, Switzerland)》2022,27(11)
Results of efficiency of obtaining humic substances (HSs) from peat in traditional alkaline extraction (TAE) and ultrasound-assisted alkaline extraction (UAAE) are presented. The influence of the duration of the process and ultrasound intensity on the efficiency of extraction of humic acids (HAs) and fulvic acids (FAs) extraction was determined. The composition of the fulvic acid fraction was examined depending on the type of eluent used. Fulvic acids were divided into fractions using columns packed with DAX-8 resin. For this process, 0.1 M NaOH and 0.5 M NH3∙H2O were used as eluents. For the quality assessment of specific fulvic acids fractions, spectroscopic methods (UV-Vis and FTIR) were used. Ultrasound had a positive effect on HS extraction efficiency, especially in increasing the amount of a desired hydrophobic fraction of fulvic acids (HPO). However, a negative effect of the excessive prolongation and ultrasound intensity (approximately 400 mW∙cm−2) on the extraction efficiency of HPO eluted with 0.1 M NaOH solution was observed. Using peat as a raw carbon material for the HS extraction process can be used as an alternative industrial application of peat. UAAE may be considered as an alternative method to TAE, which provides a higher efficiency in HS isolation from peat. 相似文献