Five unique compounds: xyloketals from mangrove fungus Xylaria sp. from the South China Sea coast

Five unique metabolites, xyloketals A (1), B (2), C (3), D (4), and E (5), and the known 6 were isolated from mangrove fungus Xylaria sp. (no. 2508), obtained from the South China Sea. The structures of these compounds were elucidated by spectroscopic and X-ray diffraction experiments. Xyloketal A is a ketal compound with a C(3) symmetry and xyloketals B-E are its analogues. It was found that xytoketal C slowly rearranged to xytoketal B in DMSO-d(6)() solution at room temperature. Xyloketal A exhibited the activity of inhibiting acetylcholine esterase.     

GA/GV measured in the decay of polarized neutrons

A measurement of [G_A/G_V] in the decay of polarized neutrons, basically quite similar to our 1968 one, gives a value of 1.258±0.015. The asymmetry coefficient, A, is ?0.113±0.006. These results include the 1968 data.     

The ν2 + ν4 band of 12CF4

From a high-resolution diode laser spectrum of cooled ¹²CF₄, line assignments in ν₂ + ν₄ at 1066.4 cm^?1 have been made for tetrahedral subspecies to J = 20, and in many cases to higher J. Spectroscopic constants have been obtained from a least-squares fit of the Hamiltonian, and the relative intensities of the assigned lines have been calculated. The ground- and excited-state rotational constants, Coriolis constant, and splitting of the F₁ and F₂ vibrational substates have the values a.The CF bond length in the ground vibrational state is thus $\text{r}{}_0\text{= 1.31752 ± 0.00007}\text{A}\text{?}$. The analysis of a combination band such as this provides a method of obtaining ground-state spectroscopic constants of spherical-top molecules directly from the infrared spectrum, without the necessity of measuring weak “forbidden” transitions. The assignments allow accurate predictions of the frequencies emitted by the CO₂-pumped CF₄ laser.     

The perturbations of line frequencies in high-J manifolds of the ν3 band of SF6

In the diode laser spectra of several P- and R-branches of high-J manifolds in the ν₃ band of SF₆ it has been observed that the lines are shifted away from the positions predicted by the diagonal F_A1pp^(4,R,R) approximation of Moret-Bailly. The shifts form a smooth function of the line positions across each manifold; this function can be represented empirically by a parabola, to which the measured wavenumbers fit within experimental accuracy. This phenomenon is explained here by model calculations for P-, Q-, and R-branch excited state levels that perturb each other through higher-order vibration-rotation interactions. In the analysis, eigenvalues calculated by second-order perturbation theory are compared with those obtained by diagonalization of the Hamiltonian.